Crystal structure of bis(benzylamine-κN)[5,10,15,20-tetrakis(4-chlorophenyl)porphyrinato-κ4N]iron(II) n-hexane monosolvate
In the title compound, [FeII(C44H24Cl4N4)(C6H5CH2NH2)2]·C6H14 or [FeII(TPP-Cl)(BzNH2)2]·n-hexane [where TPP-Cl and BzNH2 are 5,10,15,20-tetrakis(4-chlorophenyl)porphyrinate and benzylamine ligands, respectively], the FeII cation lies on an inversion centre and is octahedrally coordinated by the four...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2016-01-01
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| Series: | Acta Crystallographica Section E: Crystallographic Communications |
| Subjects: | |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2056989015024135 |
| _version_ | 1798025930684235776 |
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| author | Selma Dhifaoui Wafa Harhouri Anna Bujacz Habib Nasri |
| author_facet | Selma Dhifaoui Wafa Harhouri Anna Bujacz Habib Nasri |
| author_sort | Selma Dhifaoui |
| collection | DOAJ |
| description | In the title compound, [FeII(C44H24Cl4N4)(C6H5CH2NH2)2]·C6H14 or [FeII(TPP-Cl)(BzNH2)2]·n-hexane [where TPP-Cl and BzNH2 are 5,10,15,20-tetrakis(4-chlorophenyl)porphyrinate and benzylamine ligands, respectively], the FeII cation lies on an inversion centre and is octahedrally coordinated by the four pyrrole N atoms of the porphyrin ligand in the equatorial plane and by two amine N atoms of the benzylamine ligand in the axial sites. The crystal structure also contains one inversion-symmetric n-hexane solvent molecule per complex molecule. The average Fe—Npyrrole bond length [1.994 (3) Å] indicates a low-spin complex. The crystal packing is sustained by N—H...Cl and C—H...Cl hydrogen-bonding interactions and by C—H...π intermolecular interactions, leading to a three-dimensional network structure. |
| first_indexed | 2024-04-11T18:26:55Z |
| format | Article |
| id | doaj.art-cefa1294080944c2879d8a85342945f0 |
| institution | Directory Open Access Journal |
| issn | 2056-9890 |
| language | English |
| last_indexed | 2024-04-11T18:26:55Z |
| publishDate | 2016-01-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E: Crystallographic Communications |
| spelling | doaj.art-cefa1294080944c2879d8a85342945f02022-12-22T04:09:35ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902016-01-0172110210510.1107/S2056989015024135wm5253Crystal structure of bis(benzylamine-κN)[5,10,15,20-tetrakis(4-chlorophenyl)porphyrinato-κ4N]iron(II) n-hexane monosolvateSelma Dhifaoui0Wafa Harhouri1Anna Bujacz2Habib Nasri3Laboratoire de Physico-chimie des Matériaux, Faculté des Sciences de Monastir, Avenue de l'environnement, 5019 Monastir, University of Monastir, TunisiaLaboratoire de Physico-chimie des Matériaux, Faculté des Sciences de Monastir, Avenue de l'environnement, 5019 Monastir, University of Monastir, TunisiaX-Ray Analysis Laboratory, Institute of Technical Biochemistry, Lodz University of Technology, Stefanowskiego 4/10, 90-924 Lodz, PolandLaboratoire de Physico-chimie des Matériaux, Faculté des Sciences de Monastir, Avenue de l'environnement, 5019 Monastir, University of Monastir, TunisiaIn the title compound, [FeII(C44H24Cl4N4)(C6H5CH2NH2)2]·C6H14 or [FeII(TPP-Cl)(BzNH2)2]·n-hexane [where TPP-Cl and BzNH2 are 5,10,15,20-tetrakis(4-chlorophenyl)porphyrinate and benzylamine ligands, respectively], the FeII cation lies on an inversion centre and is octahedrally coordinated by the four pyrrole N atoms of the porphyrin ligand in the equatorial plane and by two amine N atoms of the benzylamine ligand in the axial sites. The crystal structure also contains one inversion-symmetric n-hexane solvent molecule per complex molecule. The average Fe—Npyrrole bond length [1.994 (3) Å] indicates a low-spin complex. The crystal packing is sustained by N—H...Cl and C—H...Cl hydrogen-bonding interactions and by C—H...π intermolecular interactions, leading to a three-dimensional network structure.http://scripts.iucr.org/cgi-bin/paper?S2056989015024135crystal structurehydrogen bondingUV–vis spectrairon(II)–porphyrinbenzylamine |
| spellingShingle | Selma Dhifaoui Wafa Harhouri Anna Bujacz Habib Nasri Crystal structure of bis(benzylamine-κN)[5,10,15,20-tetrakis(4-chlorophenyl)porphyrinato-κ4N]iron(II) n-hexane monosolvate Acta Crystallographica Section E: Crystallographic Communications crystal structure hydrogen bonding UV–vis spectra iron(II)–porphyrin benzylamine |
| title | Crystal structure of bis(benzylamine-κN)[5,10,15,20-tetrakis(4-chlorophenyl)porphyrinato-κ4N]iron(II) n-hexane monosolvate |
| title_full | Crystal structure of bis(benzylamine-κN)[5,10,15,20-tetrakis(4-chlorophenyl)porphyrinato-κ4N]iron(II) n-hexane monosolvate |
| title_fullStr | Crystal structure of bis(benzylamine-κN)[5,10,15,20-tetrakis(4-chlorophenyl)porphyrinato-κ4N]iron(II) n-hexane monosolvate |
| title_full_unstemmed | Crystal structure of bis(benzylamine-κN)[5,10,15,20-tetrakis(4-chlorophenyl)porphyrinato-κ4N]iron(II) n-hexane monosolvate |
| title_short | Crystal structure of bis(benzylamine-κN)[5,10,15,20-tetrakis(4-chlorophenyl)porphyrinato-κ4N]iron(II) n-hexane monosolvate |
| title_sort | crystal structure of bis benzylamine κn 5 10 15 20 tetrakis 4 chlorophenyl porphyrinato κ4n iron ii n hexane monosolvate |
| topic | crystal structure hydrogen bonding UV–vis spectra iron(II)–porphyrin benzylamine |
| url | http://scripts.iucr.org/cgi-bin/paper?S2056989015024135 |
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