Acid Free Oxidation and Simple Dispersion Method of MWCNT for High-Performance CFRP

Carbon nanotubes (CNT) provide an outstanding property spectrum which can be used to improve a wide range of materials. However, the transfer of properties from the nanoscale to a macroscopic material is a limiting factor. Different approaches of functionalizing the surface of a CNT can improve the...

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Main Authors: Gerald Singer, Philipp Siedlaczek, Gerhard Sinn, Harald Rennhofer, Matej Mičušík, Maria Omastová, Miriam M. Unterlass, Josef Wendrinsky, Valeria Milotti, Filippo Fedi, Thomas Pichler, Helga C. Lichtenegger
Format: Article
Language:English
Published: MDPI AG 2018-11-01
Series:Nanomaterials
Subjects:
Online Access:https://www.mdpi.com/2079-4991/8/11/912
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author Gerald Singer
Philipp Siedlaczek
Gerhard Sinn
Harald Rennhofer
Matej Mičušík
Maria Omastová
Miriam M. Unterlass
Josef Wendrinsky
Valeria Milotti
Filippo Fedi
Thomas Pichler
Helga C. Lichtenegger
author_facet Gerald Singer
Philipp Siedlaczek
Gerhard Sinn
Harald Rennhofer
Matej Mičušík
Maria Omastová
Miriam M. Unterlass
Josef Wendrinsky
Valeria Milotti
Filippo Fedi
Thomas Pichler
Helga C. Lichtenegger
author_sort Gerald Singer
collection DOAJ
description Carbon nanotubes (CNT) provide an outstanding property spectrum which can be used to improve a wide range of materials. However, the transfer of properties from the nanoscale to a macroscopic material is a limiting factor. Different approaches of functionalizing the surface of a CNT can improve the interaction with the surrounding matrix but is connected to difficult and expensive treatments, which are usually inconvenient for industrial applications. Here, a simple and eco-friendly method is presented for the oxidation of CNT, where hydrogen peroxide (H<sub>2</sub>O<sub>2</sub>) is the only chemical needed and no toxic emissions are released. Also, the extensive step of the incorporation of CNT to an epoxy matrix is simplified to an ultrasonic dispersion in the liquid hardener component. The effectiveness is proven by mechanical tests of produced CNT/CFRP and compared to a conventional processing route. The combination of those simple and cost efficient strategies can be utilized to produce multiscale composites with improved mechanical performance in an ecological and economical way.
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spelling doaj.art-cf00abf8533a424fae38cb6c3181a2d52022-12-22T01:59:05ZengMDPI AGNanomaterials2079-49912018-11-0181191210.3390/nano8110912nano8110912Acid Free Oxidation and Simple Dispersion Method of MWCNT for High-Performance CFRPGerald Singer0Philipp Siedlaczek1Gerhard Sinn2Harald Rennhofer3Matej Mičušík4Maria Omastová5Miriam M. Unterlass6Josef Wendrinsky7Valeria Milotti8Filippo Fedi9Thomas Pichler10Helga C. Lichtenegger11Institute of Physics and Materials Science, University of Natural Resources and Life Sciences Vienna, Peter-Jordan-Straße 82, 1190 Vienna, AustriaInstitute of Physics and Materials Science, University of Natural Resources and Life Sciences Vienna, Peter-Jordan-Straße 82, 1190 Vienna, AustriaInstitute of Physics and Materials Science, University of Natural Resources and Life Sciences Vienna, Peter-Jordan-Straße 82, 1190 Vienna, AustriaInstitute of Physics and Materials Science, University of Natural Resources and Life Sciences Vienna, Peter-Jordan-Straße 82, 1190 Vienna, AustriaSlovak Academy of Sciences, Polymer Institute, Dúbravská cesta 9, 845 41 Bratislava 45, Slovak RepublicSlovak Academy of Sciences, Polymer Institute, Dúbravská cesta 9, 845 41 Bratislava 45, Slovak RepublicInstitute of Materials Chemistry, Technische Universität Wien, Getreidemarkt 9/165, 1060 Vienna, AustriaInstitute of Materials Chemistry, Technische Universität Wien, Getreidemarkt 9/165, 1060 Vienna, AustriaElectronic Properties of Materials, Universität Wien, Boltzmanngasse 5, 1090 Vienna, AustriaElectronic Properties of Materials, Universität Wien, Boltzmanngasse 5, 1090 Vienna, AustriaElectronic Properties of Materials, Universität Wien, Boltzmanngasse 5, 1090 Vienna, AustriaInstitute of Physics and Materials Science, University of Natural Resources and Life Sciences Vienna, Peter-Jordan-Straße 82, 1190 Vienna, AustriaCarbon nanotubes (CNT) provide an outstanding property spectrum which can be used to improve a wide range of materials. However, the transfer of properties from the nanoscale to a macroscopic material is a limiting factor. Different approaches of functionalizing the surface of a CNT can improve the interaction with the surrounding matrix but is connected to difficult and expensive treatments, which are usually inconvenient for industrial applications. Here, a simple and eco-friendly method is presented for the oxidation of CNT, where hydrogen peroxide (H<sub>2</sub>O<sub>2</sub>) is the only chemical needed and no toxic emissions are released. Also, the extensive step of the incorporation of CNT to an epoxy matrix is simplified to an ultrasonic dispersion in the liquid hardener component. The effectiveness is proven by mechanical tests of produced CNT/CFRP and compared to a conventional processing route. The combination of those simple and cost efficient strategies can be utilized to produce multiscale composites with improved mechanical performance in an ecological and economical way.https://www.mdpi.com/2079-4991/8/11/912oxidationfunctionalizationeco-friendlydispersioncarbon fiber reinforced polymer (CFRP)mechanical properties
spellingShingle Gerald Singer
Philipp Siedlaczek
Gerhard Sinn
Harald Rennhofer
Matej Mičušík
Maria Omastová
Miriam M. Unterlass
Josef Wendrinsky
Valeria Milotti
Filippo Fedi
Thomas Pichler
Helga C. Lichtenegger
Acid Free Oxidation and Simple Dispersion Method of MWCNT for High-Performance CFRP
Nanomaterials
oxidation
functionalization
eco-friendly
dispersion
carbon fiber reinforced polymer (CFRP)
mechanical properties
title Acid Free Oxidation and Simple Dispersion Method of MWCNT for High-Performance CFRP
title_full Acid Free Oxidation and Simple Dispersion Method of MWCNT for High-Performance CFRP
title_fullStr Acid Free Oxidation and Simple Dispersion Method of MWCNT for High-Performance CFRP
title_full_unstemmed Acid Free Oxidation and Simple Dispersion Method of MWCNT for High-Performance CFRP
title_short Acid Free Oxidation and Simple Dispersion Method of MWCNT for High-Performance CFRP
title_sort acid free oxidation and simple dispersion method of mwcnt for high performance cfrp
topic oxidation
functionalization
eco-friendly
dispersion
carbon fiber reinforced polymer (CFRP)
mechanical properties
url https://www.mdpi.com/2079-4991/8/11/912
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