Optimization of Furfural Production from Corncobs using p-Toluene Sulphonic Acid

Furfural is a promising renewable platform compound derived from lignocellulosic biomass that can be further converted to bio-based industrial chemicals. About 90% of what is used in Nigeria is imported, translating to hundreds of millions of Dollars in foreign exchange. Hence, this research aim wa...

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Main Authors: F. E. Awe, O. J. Okunola, Z. H. Ibrahim, M. Sule
Format: Article
Language:English
Published: Joint Coordination Centre of the World Bank assisted National Agricultural Research Programme (NARP) 2023-03-01
Series:Journal of Applied Sciences and Environmental Management
Subjects:
Online Access:https://www.ajol.info/index.php/jasem/article/view/244769
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author F. E. Awe
O. J. Okunola
Z. H. Ibrahim
M. Sule
author_facet F. E. Awe
O. J. Okunola
Z. H. Ibrahim
M. Sule
author_sort F. E. Awe
collection DOAJ
description Furfural is a promising renewable platform compound derived from lignocellulosic biomass that can be further converted to bio-based industrial chemicals. About 90% of what is used in Nigeria is imported, translating to hundreds of millions of Dollars in foreign exchange. Hence, this research aim was to optimize the production process of furfural from corncobs, a lignocellulosic biomass using a three steps methods which includes; pretreatment of raw materials, acid hydrolysis and distillation according to standard methods. The corncobs were grind to powdered form and then hydrolysed in a stirred reactor using p-toluene sulphonic acid (p-TsOH) by varying parameters which includes; temperature (60, 65 and 70 oC), reaction time (1, 2 and 3hrs) and concentration (30 ml, 40 ml and 50 ml). Analysis using FTIR was conducted to identify the functional group present in the furfural produced. The results showed yield of furfural increased from 23.66 % to 28 %, and the highest yield of furfural production was obtained using 50 ml p-TsOH at 70 oC for 3 h.
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spelling doaj.art-cf09a503e6624d608c375a71490e526c2024-04-01T15:19:02ZengJoint Coordination Centre of the World Bank assisted National Agricultural Research Programme (NARP)Journal of Applied Sciences and Environmental Management2659-15022659-14992023-03-0127310.4314/jasem.v27i3.23Optimization of Furfural Production from Corncobs using p-Toluene Sulphonic AcidF. E. AweO. J. OkunolaZ. H. IbrahimM. Sule Furfural is a promising renewable platform compound derived from lignocellulosic biomass that can be further converted to bio-based industrial chemicals. About 90% of what is used in Nigeria is imported, translating to hundreds of millions of Dollars in foreign exchange. Hence, this research aim was to optimize the production process of furfural from corncobs, a lignocellulosic biomass using a three steps methods which includes; pretreatment of raw materials, acid hydrolysis and distillation according to standard methods. The corncobs were grind to powdered form and then hydrolysed in a stirred reactor using p-toluene sulphonic acid (p-TsOH) by varying parameters which includes; temperature (60, 65 and 70 oC), reaction time (1, 2 and 3hrs) and concentration (30 ml, 40 ml and 50 ml). Analysis using FTIR was conducted to identify the functional group present in the furfural produced. The results showed yield of furfural increased from 23.66 % to 28 %, and the highest yield of furfural production was obtained using 50 ml p-TsOH at 70 oC for 3 h. https://www.ajol.info/index.php/jasem/article/view/244769Furfural;Corncorb;Optimization;Analysis
spellingShingle F. E. Awe
O. J. Okunola
Z. H. Ibrahim
M. Sule
Optimization of Furfural Production from Corncobs using p-Toluene Sulphonic Acid
Journal of Applied Sciences and Environmental Management
Furfural;
Corncorb;
Optimization;
Analysis
title Optimization of Furfural Production from Corncobs using p-Toluene Sulphonic Acid
title_full Optimization of Furfural Production from Corncobs using p-Toluene Sulphonic Acid
title_fullStr Optimization of Furfural Production from Corncobs using p-Toluene Sulphonic Acid
title_full_unstemmed Optimization of Furfural Production from Corncobs using p-Toluene Sulphonic Acid
title_short Optimization of Furfural Production from Corncobs using p-Toluene Sulphonic Acid
title_sort optimization of furfural production from corncobs using p toluene sulphonic acid
topic Furfural;
Corncorb;
Optimization;
Analysis
url https://www.ajol.info/index.php/jasem/article/view/244769
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AT ojokunola optimizationoffurfuralproductionfromcorncobsusingptoluenesulphonicacid
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AT msule optimizationoffurfuralproductionfromcorncobsusingptoluenesulphonicacid