Low-Valent-Tungsten-Catalyzed Aerobic Oxidative Cross-Dehydrogenative Coupling Reaction
A straightforward and convenient protocol was established for the synthesis of thiophosphates and 3-sulfenylated indoles via low-valent-tungsten-catalyzed aerobic oxidative cross-dehydrogenative coupling reactions. These reactions occur under mild conditions and simple operations with commercially a...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
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MDPI AG
2023-12-01
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| Series: | Molecules |
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| Online Access: | https://www.mdpi.com/1420-3049/28/24/8071 |
| _version_ | 1797379943159562240 |
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| author | Chunsheng Li Yaoyang Chen Feihua Ye Junhua Chen Jia Zheng |
| author_facet | Chunsheng Li Yaoyang Chen Feihua Ye Junhua Chen Jia Zheng |
| author_sort | Chunsheng Li |
| collection | DOAJ |
| description | A straightforward and convenient protocol was established for the synthesis of thiophosphates and 3-sulfenylated indoles via low-valent-tungsten-catalyzed aerobic oxidative cross-dehydrogenative coupling reactions. These reactions occur under mild conditions and simple operations with commercially available starting materials, processing the advantage of excellent atom and step economy, broad substrate scope, and good functional groups tolerance. Moreover, this transformation could be practiced on the gram scale, which exhibits great potential in the preparation of drug-derived or bioactive molecules. |
| first_indexed | 2024-03-08T20:30:20Z |
| format | Article |
| id | doaj.art-cf0f12a8432e41b59c890dc2cf01750a |
| institution | Directory Open Access Journal |
| issn | 1420-3049 |
| language | English |
| last_indexed | 2024-03-08T20:30:20Z |
| publishDate | 2023-12-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Molecules |
| spelling | doaj.art-cf0f12a8432e41b59c890dc2cf01750a2023-12-22T14:27:40ZengMDPI AGMolecules1420-30492023-12-012824807110.3390/molecules28248071Low-Valent-Tungsten-Catalyzed Aerobic Oxidative Cross-Dehydrogenative Coupling ReactionChunsheng Li0Yaoyang Chen1Feihua Ye2Junhua Chen3Jia Zheng4School of Environmental and Chemical Engineering, Zhaoqing University, Zhaoqing 526061, ChinaSchool of Environmental and Chemical Engineering, Zhaoqing University, Zhaoqing 526061, ChinaSchool of Environmental and Chemical Engineering, Zhaoqing University, Zhaoqing 526061, ChinaSchool of Environmental and Chemical Engineering, Zhaoqing University, Zhaoqing 526061, ChinaThe Marine Biomedical Research Institute, Guangdong Medical University, Zhanjiang 524023, ChinaA straightforward and convenient protocol was established for the synthesis of thiophosphates and 3-sulfenylated indoles via low-valent-tungsten-catalyzed aerobic oxidative cross-dehydrogenative coupling reactions. These reactions occur under mild conditions and simple operations with commercially available starting materials, processing the advantage of excellent atom and step economy, broad substrate scope, and good functional groups tolerance. Moreover, this transformation could be practiced on the gram scale, which exhibits great potential in the preparation of drug-derived or bioactive molecules.https://www.mdpi.com/1420-3049/28/24/8071cross-dehydrogenative couplingaerobicthiophosphates3-sulfenylated indoles |
| spellingShingle | Chunsheng Li Yaoyang Chen Feihua Ye Junhua Chen Jia Zheng Low-Valent-Tungsten-Catalyzed Aerobic Oxidative Cross-Dehydrogenative Coupling Reaction Molecules cross-dehydrogenative coupling aerobic thiophosphates 3-sulfenylated indoles |
| title | Low-Valent-Tungsten-Catalyzed Aerobic Oxidative Cross-Dehydrogenative Coupling Reaction |
| title_full | Low-Valent-Tungsten-Catalyzed Aerobic Oxidative Cross-Dehydrogenative Coupling Reaction |
| title_fullStr | Low-Valent-Tungsten-Catalyzed Aerobic Oxidative Cross-Dehydrogenative Coupling Reaction |
| title_full_unstemmed | Low-Valent-Tungsten-Catalyzed Aerobic Oxidative Cross-Dehydrogenative Coupling Reaction |
| title_short | Low-Valent-Tungsten-Catalyzed Aerobic Oxidative Cross-Dehydrogenative Coupling Reaction |
| title_sort | low valent tungsten catalyzed aerobic oxidative cross dehydrogenative coupling reaction |
| topic | cross-dehydrogenative coupling aerobic thiophosphates 3-sulfenylated indoles |
| url | https://www.mdpi.com/1420-3049/28/24/8071 |
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