Effect of Experimental Conditions on Co-Pyrolysis of Pre-Treated Eucalyptus Blended with Plastic Wastes

Eucalyptus has been largely used in the pulp and paper industry in Iberian Peninsula, due to its fast growth and high productivity. This eucalyptus utilisation has generated high amounts of wastes, including leaves, branches and stumps. Hence, these wastes were selected for the co-pyrolysis studies...

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Main Authors: Filomena Pinto, Filipe Paradela, Florbela Carvalheiro, Luis C. Duarte, Paula Costa, Rui Andre
Format: Article
Language:English
Published: AIDIC Servizi S.r.l. 2018-08-01
Series:Chemical Engineering Transactions
Online Access:https://www.cetjournal.it/index.php/cet/article/view/563
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author Filomena Pinto
Filipe Paradela
Florbela Carvalheiro
Luis C. Duarte
Paula Costa
Rui Andre
author_facet Filomena Pinto
Filipe Paradela
Florbela Carvalheiro
Luis C. Duarte
Paula Costa
Rui Andre
author_sort Filomena Pinto
collection DOAJ
description Eucalyptus has been largely used in the pulp and paper industry in Iberian Peninsula, due to its fast growth and high productivity. This eucalyptus utilisation has generated high amounts of wastes, including leaves, branches and stumps. Hence, these wastes were selected for the co-pyrolysis studies to produce liquid fuels or raw materials. As an alternative to the conventional biomass pyrolysis, biomass was pre-treated under mild acidic conditions to obtain valuable sugar-rich stream to be used in fermentation and the solids rich in lignin were mixed with PE (polyethylene) wastes to be used in co-pyrolysis. The pre-treatment process seems to have weakened initial macromolecular structure of eucalyptus wastes and thus might have helped chemical bonds breakdown during co-pyrolysis. The results obtained so far have shown that PE presence seems to have favoured the biomass conversion. The effect of experimental conditions using Response Surface Methodology (RSM) was studied. There was a good agreement between theoretical and experimental data. The highest liquid yield (78 % wt) was obtained at 380 ºC and for the reaction time of 20 min. These conditions led to the lowest gases yield (7 % wt) and also to the lowest solids yield (14 % wt).
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spelling doaj.art-cf1283c2328a4428969d0076378c215f2022-12-21T23:15:18ZengAIDIC Servizi S.r.l.Chemical Engineering Transactions2283-92162018-08-017010.3303/CET1870133Effect of Experimental Conditions on Co-Pyrolysis of Pre-Treated Eucalyptus Blended with Plastic WastesFilomena PintoFilipe ParadelaFlorbela CarvalheiroLuis C. DuartePaula CostaRui AndreEucalyptus has been largely used in the pulp and paper industry in Iberian Peninsula, due to its fast growth and high productivity. This eucalyptus utilisation has generated high amounts of wastes, including leaves, branches and stumps. Hence, these wastes were selected for the co-pyrolysis studies to produce liquid fuels or raw materials. As an alternative to the conventional biomass pyrolysis, biomass was pre-treated under mild acidic conditions to obtain valuable sugar-rich stream to be used in fermentation and the solids rich in lignin were mixed with PE (polyethylene) wastes to be used in co-pyrolysis. The pre-treatment process seems to have weakened initial macromolecular structure of eucalyptus wastes and thus might have helped chemical bonds breakdown during co-pyrolysis. The results obtained so far have shown that PE presence seems to have favoured the biomass conversion. The effect of experimental conditions using Response Surface Methodology (RSM) was studied. There was a good agreement between theoretical and experimental data. The highest liquid yield (78 % wt) was obtained at 380 ºC and for the reaction time of 20 min. These conditions led to the lowest gases yield (7 % wt) and also to the lowest solids yield (14 % wt).https://www.cetjournal.it/index.php/cet/article/view/563
spellingShingle Filomena Pinto
Filipe Paradela
Florbela Carvalheiro
Luis C. Duarte
Paula Costa
Rui Andre
Effect of Experimental Conditions on Co-Pyrolysis of Pre-Treated Eucalyptus Blended with Plastic Wastes
Chemical Engineering Transactions
title Effect of Experimental Conditions on Co-Pyrolysis of Pre-Treated Eucalyptus Blended with Plastic Wastes
title_full Effect of Experimental Conditions on Co-Pyrolysis of Pre-Treated Eucalyptus Blended with Plastic Wastes
title_fullStr Effect of Experimental Conditions on Co-Pyrolysis of Pre-Treated Eucalyptus Blended with Plastic Wastes
title_full_unstemmed Effect of Experimental Conditions on Co-Pyrolysis of Pre-Treated Eucalyptus Blended with Plastic Wastes
title_short Effect of Experimental Conditions on Co-Pyrolysis of Pre-Treated Eucalyptus Blended with Plastic Wastes
title_sort effect of experimental conditions on co pyrolysis of pre treated eucalyptus blended with plastic wastes
url https://www.cetjournal.it/index.php/cet/article/view/563
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