Synthesis, Characterization, and Photocatalytic Performance of ZnO–Graphene Nanocomposites: A Review

ZnO is an exciting material for photocatalysis applications due to its high activity, easy accessibility of raw materials, low production costs, and nontoxic. Several ZnO nano and microstructures can be obtained, such as nanoparticles, nanorods, micro flowers, microspheres, among others, depending o...

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Main Authors: Elim Albiter, Aura S. Merlano, Elizabeth Rojas, José M. Barrera-Andrade, Ángel Salazar, Miguel A. Valenzuela
Format: Article
Language:English
Published: MDPI AG 2020-12-01
Series:Journal of Composites Science
Subjects:
Online Access:https://www.mdpi.com/2504-477X/5/1/4
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author Elim Albiter
Aura S. Merlano
Elizabeth Rojas
José M. Barrera-Andrade
Ángel Salazar
Miguel A. Valenzuela
author_facet Elim Albiter
Aura S. Merlano
Elizabeth Rojas
José M. Barrera-Andrade
Ángel Salazar
Miguel A. Valenzuela
author_sort Elim Albiter
collection DOAJ
description ZnO is an exciting material for photocatalysis applications due to its high activity, easy accessibility of raw materials, low production costs, and nontoxic. Several ZnO nano and microstructures can be obtained, such as nanoparticles, nanorods, micro flowers, microspheres, among others, depending on the preparation method and conditions. ZnO is a wide bandgap semiconductor presenting massive recombination of the generated charge carriers, limiting its photocatalytic efficiency and stability. It is common to mix it with metal, metal oxide, sulfides, polymers, and nanocarbon-based materials to improve its photocatalytic behavior. Therefore, ZnO–nanocarbon composites formation has been a viable alternative that leads to new, more active, and stable photocatalytic systems. Mainly, graphene is a well-known two-dimensional material, which could be an excellent candidate to hybridize with ZnO due to its excellent physical and chemical properties (e.g., high specific surface area, optical transmittance, and thermal conductivity, among others). This review analyses ZnO–graphene nanocomposites’ recent advances, addressing the synthesis methods and the resulting structural, morphological, optical, and electronic properties. Moreover, we examine the ZnO–graphene composites’ role in the photocatalytic degradation of organic/inorganic pollutants.
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spelling doaj.art-cf233bc9b27b421eaeb608f0f843ffc72023-11-21T02:36:31ZengMDPI AGJournal of Composites Science2504-477X2020-12-0151410.3390/jcs5010004Synthesis, Characterization, and Photocatalytic Performance of ZnO–Graphene Nanocomposites: A ReviewElim Albiter0Aura S. Merlano1Elizabeth Rojas2José M. Barrera-Andrade3Ángel Salazar4Miguel A. Valenzuela5Laboratory de Catálisis y Materiales, ESIQIE-Instituto Politécnico Nacional, Zacatenco, Ciudad de México 07738, MexicoGrupo de Óptica y Espectroscopía (GOE), Centro de Ciencia Básica, Universidad Pontificia Bolivariana, Medellín 050031, ColombiaÁrea de Ingeniería Química, Universidad Autónoma Metropolitana-Iztapalapa, Iztapalapa, Ciudad de México 09340, MexicoLaboratory de Catálisis y Materiales, ESIQIE-Instituto Politécnico Nacional, Zacatenco, Ciudad de México 07738, MexicoGrupo de Óptica y Espectroscopía (GOE), Centro de Ciencia Básica, Universidad Pontificia Bolivariana, Medellín 050031, ColombiaLaboratory de Catálisis y Materiales, ESIQIE-Instituto Politécnico Nacional, Zacatenco, Ciudad de México 07738, MexicoZnO is an exciting material for photocatalysis applications due to its high activity, easy accessibility of raw materials, low production costs, and nontoxic. Several ZnO nano and microstructures can be obtained, such as nanoparticles, nanorods, micro flowers, microspheres, among others, depending on the preparation method and conditions. ZnO is a wide bandgap semiconductor presenting massive recombination of the generated charge carriers, limiting its photocatalytic efficiency and stability. It is common to mix it with metal, metal oxide, sulfides, polymers, and nanocarbon-based materials to improve its photocatalytic behavior. Therefore, ZnO–nanocarbon composites formation has been a viable alternative that leads to new, more active, and stable photocatalytic systems. Mainly, graphene is a well-known two-dimensional material, which could be an excellent candidate to hybridize with ZnO due to its excellent physical and chemical properties (e.g., high specific surface area, optical transmittance, and thermal conductivity, among others). This review analyses ZnO–graphene nanocomposites’ recent advances, addressing the synthesis methods and the resulting structural, morphological, optical, and electronic properties. Moreover, we examine the ZnO–graphene composites’ role in the photocatalytic degradation of organic/inorganic pollutants.https://www.mdpi.com/2504-477X/5/1/4ZnOgraphenecompositesphotocatalysispollutant degradation
spellingShingle Elim Albiter
Aura S. Merlano
Elizabeth Rojas
José M. Barrera-Andrade
Ángel Salazar
Miguel A. Valenzuela
Synthesis, Characterization, and Photocatalytic Performance of ZnO–Graphene Nanocomposites: A Review
Journal of Composites Science
ZnO
graphene
composites
photocatalysis
pollutant degradation
title Synthesis, Characterization, and Photocatalytic Performance of ZnO–Graphene Nanocomposites: A Review
title_full Synthesis, Characterization, and Photocatalytic Performance of ZnO–Graphene Nanocomposites: A Review
title_fullStr Synthesis, Characterization, and Photocatalytic Performance of ZnO–Graphene Nanocomposites: A Review
title_full_unstemmed Synthesis, Characterization, and Photocatalytic Performance of ZnO–Graphene Nanocomposites: A Review
title_short Synthesis, Characterization, and Photocatalytic Performance of ZnO–Graphene Nanocomposites: A Review
title_sort synthesis characterization and photocatalytic performance of zno graphene nanocomposites a review
topic ZnO
graphene
composites
photocatalysis
pollutant degradation
url https://www.mdpi.com/2504-477X/5/1/4
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