{4,4′-Dimethyl-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethanylylidene)]diphenolato}copper(II) monohydrate
The asymmetric unit of the title compound, [Cu(C21H24N2O2)]·H2O, comprises half of a Schiff base complex and half of a water molecule. The whole compound is generated by crystallographic twofold rotation symmetry. The geometry around the CuII atom, located on a twofold axis, is distorte...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2012-09-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536812034502 |
| _version_ | 1798017135770861568 |
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| author | Hadi Kargar Reza Kia Fatemeh Ganji Valiollah Mirkhani |
| author_facet | Hadi Kargar Reza Kia Fatemeh Ganji Valiollah Mirkhani |
| author_sort | Hadi Kargar |
| collection | DOAJ |
| description | The asymmetric unit of the title compound, [Cu(C21H24N2O2)]·H2O, comprises half of a Schiff base complex and half of a water molecule. The whole compound is generated by crystallographic twofold rotation symmetry. The geometry around the CuII atom, located on a twofold axis, is distorted square-planar, which is supported by the N2O2 donor atoms of the coordinating Schiff base ligand. The dihedral angle between the symmetry-related benzene rings is 47.5 (4)°. In the crystal, the water molecule that is hydrogen bonded to the coordinated O atoms links the molecules via O—H...O interactions into chains parallel to [001]. The crystal structure is further stabilized by C—H...π interactions, and by π–π interactions involving inversion-related chelate rings [centroid–centroid distance = 3.480 (4) Å]. |
| first_indexed | 2024-04-11T16:00:46Z |
| format | Article |
| id | doaj.art-cf23b22eb04f4982a64a200a7c1e5ba7 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-04-11T16:00:46Z |
| publishDate | 2012-09-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-cf23b22eb04f4982a64a200a7c1e5ba72022-12-22T04:15:01ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-09-01689m1172m117210.1107/S1600536812034502{4,4′-Dimethyl-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethanylylidene)]diphenolato}copper(II) monohydrateHadi KargarReza KiaFatemeh GanjiValiollah MirkhaniThe asymmetric unit of the title compound, [Cu(C21H24N2O2)]·H2O, comprises half of a Schiff base complex and half of a water molecule. The whole compound is generated by crystallographic twofold rotation symmetry. The geometry around the CuII atom, located on a twofold axis, is distorted square-planar, which is supported by the N2O2 donor atoms of the coordinating Schiff base ligand. The dihedral angle between the symmetry-related benzene rings is 47.5 (4)°. In the crystal, the water molecule that is hydrogen bonded to the coordinated O atoms links the molecules via O—H...O interactions into chains parallel to [001]. The crystal structure is further stabilized by C—H...π interactions, and by π–π interactions involving inversion-related chelate rings [centroid–centroid distance = 3.480 (4) Å].http://scripts.iucr.org/cgi-bin/paper?S1600536812034502 |
| spellingShingle | Hadi Kargar Reza Kia Fatemeh Ganji Valiollah Mirkhani {4,4′-Dimethyl-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethanylylidene)]diphenolato}copper(II) monohydrate Acta Crystallographica Section E |
| title | {4,4′-Dimethyl-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethanylylidene)]diphenolato}copper(II) monohydrate |
| title_full | {4,4′-Dimethyl-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethanylylidene)]diphenolato}copper(II) monohydrate |
| title_fullStr | {4,4′-Dimethyl-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethanylylidene)]diphenolato}copper(II) monohydrate |
| title_full_unstemmed | {4,4′-Dimethyl-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethanylylidene)]diphenolato}copper(II) monohydrate |
| title_short | {4,4′-Dimethyl-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethanylylidene)]diphenolato}copper(II) monohydrate |
| title_sort | 4 4 amp 8242 dimethyl 2 2 amp 8242 2 2 dimethylpropane 1 3 diylbis nitrilomethanylylidene diphenolato copper ii monohydrate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536812034502 |
| work_keys_str_mv | AT hadikargar 44amp8242dimethyl22amp824222dimethylpropane13diylbisnitrilomethanylylidenediphenolatocopperiimonohydrate AT rezakia 44amp8242dimethyl22amp824222dimethylpropane13diylbisnitrilomethanylylidenediphenolatocopperiimonohydrate AT fatemehganji 44amp8242dimethyl22amp824222dimethylpropane13diylbisnitrilomethanylylidenediphenolatocopperiimonohydrate AT valiollahmirkhani 44amp8242dimethyl22amp824222dimethylpropane13diylbisnitrilomethanylylidenediphenolatocopperiimonohydrate |