Synthesis and crystal structure of (1,4,7,10-tetraazacyclododecane-κ4N)(tetrasulfido-κ2S1,S4)manganese(II)

Synthesis and crystal structure of (1,4,7,10-tetraazacyclododecane-κ4N)(tetrasulfido-κ2S1,S4)manganese(II)

The title compound, [Mn(S4)(C8H20N4)], was accidentally obtained by the hydrothermal reaction of Mn(ClO4)2·6H2O, cyclen (cyclen = 1,4,7,10-tetraazacyclododecane) and Na3SbS4·9H2O in water at 413 K, indicating that polysulfide anions might represent intermediates in the synthesis of thiometallate com...

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Bibliographic Details
Main Authors:	Felix Danker, Christian Näther, Wolfgang Bensch
Format:	Article
Language:	English
Published:	International Union of Crystallography 2020-03-01
Series:	Acta Crystallographica Section E: Crystallographic Communications
Subjects:	crystal structure polysulfide manganese(ii) discrete complex hydrogen bonding
Online Access:	http://scripts.iucr.org/cgi-bin/paper?S2056989020002492

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