Post-Functionalization of Organometallic Complexes via Click-Reaction
CuAAC (Cu catalyzed azide-alkyne cycloaddition) click-reaction is a simple and powerful method for the post-synthetic modification of organometallic complexes of transition metals. This approach allows the selective introduction of additional donor sites or functional groups to the periphery of the...
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| Format: | Article |
| Language: | English |
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MDPI AG
2022-10-01
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| Series: | Molecules |
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| Online Access: | https://www.mdpi.com/1420-3049/27/19/6494 |
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| author | Stanislav Petrovskii Viktoria Khistiaeva Aleksandra Paderina Evgenia Abramova Elena Grachova |
| author_facet | Stanislav Petrovskii Viktoria Khistiaeva Aleksandra Paderina Evgenia Abramova Elena Grachova |
| author_sort | Stanislav Petrovskii |
| collection | DOAJ |
| description | CuAAC (Cu catalyzed azide-alkyne cycloaddition) click-reaction is a simple and powerful method for the post-synthetic modification of organometallic complexes of transition metals. This approach allows the selective introduction of additional donor sites or functional groups to the periphery of the ligand environment. This is especially important if a metalloligand with free donor sites, which are of the same nature as the primary site for the coordination of the primary metal, has to be created. The concept of post-synthetic modification of organometallic complexes by click-reaction is relatively recent and the currently available experimental material does not yet allow us to identify trends and formulate recommendations to address specific problems. In the present study, we have applied the CuAAC reaction for the post-synthetic modification of diimine mononuclear complexes Re(I), Pt(II) and Ir(III) with C≡C bonds at the periphery of the ligand environment and demonstrated that click-chemistry is a powerful tool for the tunable chemical post-synthetic modification of coordination compounds. |
| first_indexed | 2024-03-09T21:25:01Z |
| format | Article |
| id | doaj.art-cf39ba036c2b46e5b31016607ef45e2c |
| institution | Directory Open Access Journal |
| issn | 1420-3049 |
| language | English |
| last_indexed | 2024-03-09T21:25:01Z |
| publishDate | 2022-10-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Molecules |
| spelling | doaj.art-cf39ba036c2b46e5b31016607ef45e2c2023-11-23T21:12:19ZengMDPI AGMolecules1420-30492022-10-012719649410.3390/molecules27196494Post-Functionalization of Organometallic Complexes via Click-ReactionStanislav Petrovskii0Viktoria Khistiaeva1Aleksandra Paderina2Evgenia Abramova3Elena Grachova4Institute of Chemistry, St. Petersburg University, 198504 St. Petersburg, RussiaInstitute of Chemistry, St. Petersburg University, 198504 St. Petersburg, RussiaInstitute of Chemistry, St. Petersburg University, 198504 St. Petersburg, RussiaInstitute of Chemistry, St. Petersburg University, 198504 St. Petersburg, RussiaInstitute of Chemistry, St. Petersburg University, 198504 St. Petersburg, RussiaCuAAC (Cu catalyzed azide-alkyne cycloaddition) click-reaction is a simple and powerful method for the post-synthetic modification of organometallic complexes of transition metals. This approach allows the selective introduction of additional donor sites or functional groups to the periphery of the ligand environment. This is especially important if a metalloligand with free donor sites, which are of the same nature as the primary site for the coordination of the primary metal, has to be created. The concept of post-synthetic modification of organometallic complexes by click-reaction is relatively recent and the currently available experimental material does not yet allow us to identify trends and formulate recommendations to address specific problems. In the present study, we have applied the CuAAC reaction for the post-synthetic modification of diimine mononuclear complexes Re(I), Pt(II) and Ir(III) with C≡C bonds at the periphery of the ligand environment and demonstrated that click-chemistry is a powerful tool for the tunable chemical post-synthetic modification of coordination compounds.https://www.mdpi.com/1420-3049/27/19/6494click-reactionCuAACplatinum complexiridium complexrhenium complexpost-synthetic modification |
| spellingShingle | Stanislav Petrovskii Viktoria Khistiaeva Aleksandra Paderina Evgenia Abramova Elena Grachova Post-Functionalization of Organometallic Complexes via Click-Reaction Molecules click-reaction CuAAC platinum complex iridium complex rhenium complex post-synthetic modification |
| title | Post-Functionalization of Organometallic Complexes via Click-Reaction |
| title_full | Post-Functionalization of Organometallic Complexes via Click-Reaction |
| title_fullStr | Post-Functionalization of Organometallic Complexes via Click-Reaction |
| title_full_unstemmed | Post-Functionalization of Organometallic Complexes via Click-Reaction |
| title_short | Post-Functionalization of Organometallic Complexes via Click-Reaction |
| title_sort | post functionalization of organometallic complexes via click reaction |
| topic | click-reaction CuAAC platinum complex iridium complex rhenium complex post-synthetic modification |
| url | https://www.mdpi.com/1420-3049/27/19/6494 |
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