Study on removal of Se(IV) using Fe-Mn layered double hydroxides and Fe-Mn Dos (double oxides)
In this study, Fe-Mn-CO3 layered double hydroxide (LDHs) and Fe-Mn Double oxide (DOs) were synthesized by the co-recipitation methods for Se(IV) removal from aqueous solutions. The Se(IV) adsorption capacities and removal mechanism of Fe-Mn LDH and Fe-Mn DOs determined by batch and column experiment...
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Format: | Article |
Language: | English |
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Mongolian Academy of Sciences
2019-12-01
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Series: | Mongolian Journal of Chemistry |
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Online Access: | https://www.mongoliajol.info/index.php/MJC/article/view/1239 |
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author | Enkhtur Otgonjargal Kitae Baek Jung-Seok Yang Enkhtuul Surenjav Aruukhan Dashkhuu Khasbaatar |
author_facet | Enkhtur Otgonjargal Kitae Baek Jung-Seok Yang Enkhtuul Surenjav Aruukhan Dashkhuu Khasbaatar |
author_sort | Enkhtur Otgonjargal |
collection | DOAJ |
description | In this study, Fe-Mn-CO3 layered double hydroxide (LDHs) and Fe-Mn Double oxide (DOs) were synthesized by the co-recipitation methods for Se(IV) removal from aqueous solutions. The Se(IV) adsorption capacities and removal mechanism of Fe-Mn LDH and Fe-Mn DOs determined by batch and column experiments. The calculated Se(IV) adsorption capacities on Fe-Mn LDH and Fe-Mn DOs were 52.5 and 55.3 mg/g, respectively. Kinetic models applied to the adsorption of Se(IV)
on the Fe-Mn LDH and Fe-Mn DOs calculated using pseudo-first, second-order, Elovich, and Intraparticle diffusion kinetic models and all kinetic parameters were calculated and discussed. Isotherm studies were also performed using Langmuir,
Freundlich, Temkin, and Dubinin-Radushkevich equations in the temperature range of 283 - 323 K. Adsorption kinetics and isotherm experiments are well fitted pseudo-second order model and Freundlich isotherm, respectively. The production of this adsorbent is cost-effective for industrial applications. |
first_indexed | 2024-12-21T11:27:43Z |
format | Article |
id | doaj.art-cf4615742f4e46c9ac1d4245116a99d0 |
institution | Directory Open Access Journal |
issn | 2226-6739 2414-0082 |
language | English |
last_indexed | 2024-12-21T11:27:43Z |
publishDate | 2019-12-01 |
publisher | Mongolian Academy of Sciences |
record_format | Article |
series | Mongolian Journal of Chemistry |
spelling | doaj.art-cf4615742f4e46c9ac1d4245116a99d02022-12-21T19:05:37ZengMongolian Academy of SciencesMongolian Journal of Chemistry2226-67392414-00822019-12-012046293710.5564/mjc.v20i46.12391239Study on removal of Se(IV) using Fe-Mn layered double hydroxides and Fe-Mn Dos (double oxides)Enkhtur Otgonjargal0Kitae Baek1Jung-Seok Yang2Enkhtuul Surenjav3Aruukhan Dashkhuu Khasbaatar4Institute of Chemistry and Chemical Technology, Mongolian Academy of Sciences, 4th Building of MAS, Ulaanbaatar, 13330, MongoliaChonbuk National University, 567 Baekje-daero, Deokjin-gu, Jeongju, Jeollabukdo 570-752, Republic of KoreaKIST-Gangneung Institute, Gangneung, Gangwon 210-340, Republic of KoreaInstitute of Chemistry and Chemical Technology, Mongolian Academy of Sciences, 4th Building of MAS, Ulaanbaatar, 13330, MongoliaSchool of Engineering and Applied Sciences, National University of Mongolia, P.O.Box 46A/257, 14201 Main building of NUM, University street 1, Sukhbaatar district, Ulaanbaatar, MongoliaIn this study, Fe-Mn-CO3 layered double hydroxide (LDHs) and Fe-Mn Double oxide (DOs) were synthesized by the co-recipitation methods for Se(IV) removal from aqueous solutions. The Se(IV) adsorption capacities and removal mechanism of Fe-Mn LDH and Fe-Mn DOs determined by batch and column experiments. The calculated Se(IV) adsorption capacities on Fe-Mn LDH and Fe-Mn DOs were 52.5 and 55.3 mg/g, respectively. Kinetic models applied to the adsorption of Se(IV) on the Fe-Mn LDH and Fe-Mn DOs calculated using pseudo-first, second-order, Elovich, and Intraparticle diffusion kinetic models and all kinetic parameters were calculated and discussed. Isotherm studies were also performed using Langmuir, Freundlich, Temkin, and Dubinin-Radushkevich equations in the temperature range of 283 - 323 K. Adsorption kinetics and isotherm experiments are well fitted pseudo-second order model and Freundlich isotherm, respectively. The production of this adsorbent is cost-effective for industrial applications.https://www.mongoliajol.info/index.php/MJC/article/view/1239adsorptiondouble oxidelayered double hydroxideselenium |
spellingShingle | Enkhtur Otgonjargal Kitae Baek Jung-Seok Yang Enkhtuul Surenjav Aruukhan Dashkhuu Khasbaatar Study on removal of Se(IV) using Fe-Mn layered double hydroxides and Fe-Mn Dos (double oxides) Mongolian Journal of Chemistry adsorption double oxide layered double hydroxide selenium |
title | Study on removal of Se(IV) using Fe-Mn layered double hydroxides and Fe-Mn Dos (double oxides) |
title_full | Study on removal of Se(IV) using Fe-Mn layered double hydroxides and Fe-Mn Dos (double oxides) |
title_fullStr | Study on removal of Se(IV) using Fe-Mn layered double hydroxides and Fe-Mn Dos (double oxides) |
title_full_unstemmed | Study on removal of Se(IV) using Fe-Mn layered double hydroxides and Fe-Mn Dos (double oxides) |
title_short | Study on removal of Se(IV) using Fe-Mn layered double hydroxides and Fe-Mn Dos (double oxides) |
title_sort | study on removal of se iv using fe mn layered double hydroxides and fe mn dos double oxides |
topic | adsorption double oxide layered double hydroxide selenium |
url | https://www.mongoliajol.info/index.php/MJC/article/view/1239 |
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