Sustainably Adjusting the Up-Conversion White-Emitting Luminescence Properties of GdAlO3: Er3+/Yb3+/Tm3+ Phosphors

Doping heteroatom in phosphor can effectively improve luminescent properties, which has attracted great attention recently. GdAlO3 phosphors (GAP) doped with Er3+/Yb3+/Tm3+ were prepared via the co-precipitation method. Upon 980 nm excitation, strong blue, green, and red up-conversion (UC) emissions...

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Main Authors: Taoli Deng, Xianbang Jiang, Qiuyun Zhang
Format: Article
Language:English
Published: Frontiers Media S.A. 2020-09-01
Series:Frontiers in Chemistry
Subjects:
Online Access:https://www.frontiersin.org/article/10.3389/fchem.2020.00788/full
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author Taoli Deng
Xianbang Jiang
Qiuyun Zhang
author_facet Taoli Deng
Xianbang Jiang
Qiuyun Zhang
author_sort Taoli Deng
collection DOAJ
description Doping heteroatom in phosphor can effectively improve luminescent properties, which has attracted great attention recently. GdAlO3 phosphors (GAP) doped with Er3+/Yb3+/Tm3+ were prepared via the co-precipitation method. Upon 980 nm excitation, strong blue, green, and red up-conversion (UC) emissions centered at 476, 524, 546, and 659 nm were observed, which could be successfully combined to form pure white light. It was found that changing the doping concentration of Er3+ and Yb3+ ions, the calcination temperature of the precursor, the laser power of the excitation light source, and doping Li+ could systematically adjust red/green/blue colors of GdAlO3:Er3+/Yb3+/Tm3+ phosphors to optimize the white emitting luminescence. When the Er3+ doping concentration of the phosphors increased, each color distribution successfully moved, making the maximum shift of the CIE coordinate. Finally, the influence of each factor on adjusting the UC white light performance and its mechanism were explored.
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spelling doaj.art-cf5ad30cf2494477b6ec50ec8d9ab8242022-12-22T01:49:53ZengFrontiers Media S.A.Frontiers in Chemistry2296-26462020-09-01810.3389/fchem.2020.00788576353Sustainably Adjusting the Up-Conversion White-Emitting Luminescence Properties of GdAlO3: Er3+/Yb3+/Tm3+ PhosphorsTaoli DengXianbang JiangQiuyun ZhangDoping heteroatom in phosphor can effectively improve luminescent properties, which has attracted great attention recently. GdAlO3 phosphors (GAP) doped with Er3+/Yb3+/Tm3+ were prepared via the co-precipitation method. Upon 980 nm excitation, strong blue, green, and red up-conversion (UC) emissions centered at 476, 524, 546, and 659 nm were observed, which could be successfully combined to form pure white light. It was found that changing the doping concentration of Er3+ and Yb3+ ions, the calcination temperature of the precursor, the laser power of the excitation light source, and doping Li+ could systematically adjust red/green/blue colors of GdAlO3:Er3+/Yb3+/Tm3+ phosphors to optimize the white emitting luminescence. When the Er3+ doping concentration of the phosphors increased, each color distribution successfully moved, making the maximum shift of the CIE coordinate. Finally, the influence of each factor on adjusting the UC white light performance and its mechanism were explored.https://www.frontiersin.org/article/10.3389/fchem.2020.00788/fullsustainable chemistrywhite-emittingheteroatom-containing compoundslaser powerphosphors
spellingShingle Taoli Deng
Xianbang Jiang
Qiuyun Zhang
Sustainably Adjusting the Up-Conversion White-Emitting Luminescence Properties of GdAlO3: Er3+/Yb3+/Tm3+ Phosphors
Frontiers in Chemistry
sustainable chemistry
white-emitting
heteroatom-containing compounds
laser power
phosphors
title Sustainably Adjusting the Up-Conversion White-Emitting Luminescence Properties of GdAlO3: Er3+/Yb3+/Tm3+ Phosphors
title_full Sustainably Adjusting the Up-Conversion White-Emitting Luminescence Properties of GdAlO3: Er3+/Yb3+/Tm3+ Phosphors
title_fullStr Sustainably Adjusting the Up-Conversion White-Emitting Luminescence Properties of GdAlO3: Er3+/Yb3+/Tm3+ Phosphors
title_full_unstemmed Sustainably Adjusting the Up-Conversion White-Emitting Luminescence Properties of GdAlO3: Er3+/Yb3+/Tm3+ Phosphors
title_short Sustainably Adjusting the Up-Conversion White-Emitting Luminescence Properties of GdAlO3: Er3+/Yb3+/Tm3+ Phosphors
title_sort sustainably adjusting the up conversion white emitting luminescence properties of gdalo3 er3 yb3 tm3 phosphors
topic sustainable chemistry
white-emitting
heteroatom-containing compounds
laser power
phosphors
url https://www.frontiersin.org/article/10.3389/fchem.2020.00788/full
work_keys_str_mv AT taolideng sustainablyadjustingtheupconversionwhiteemittingluminescencepropertiesofgdalo3er3yb3tm3phosphors
AT xianbangjiang sustainablyadjustingtheupconversionwhiteemittingluminescencepropertiesofgdalo3er3yb3tm3phosphors
AT qiuyunzhang sustainablyadjustingtheupconversionwhiteemittingluminescencepropertiesofgdalo3er3yb3tm3phosphors