Exciton coupling induces vibronic hyperchromism in light-harvesting complexes

Exciton coupling induces vibronic hyperchromism in light-harvesting complexes

The recently suggested possibility that weak vibronic transitions can be excitonically enhanced in light-harvesting complexes is studied in detail. A vibronic exciton dimer model that includes ground-state vibrations is investigated using the multi-configuration time-dependent Hartree method with a...

Full description

Bibliographic Details
Main Authors:	Jan Schulze, Magne Torbjörnsson, Oliver Kühn, Tõnu Pullerits
Format:	Article
Language:	English
Published:	IOP Publishing 2014-01-01
Series:	New Journal of Physics
Subjects:	coherence electronic 2D spectroscopy excitons vibronic coupling Huang–Rhys factor fluorescence line narrowing
Online Access:	https://doi.org/10.1088/1367-2630/16/4/045010

Similar Items

Optical Spectra of Oligofurans: A Theoretical Approach to the Transition Energies, Reorganization Energies, and the Vibronic Activity
by: Karolina Filipowska, et al.
Published: (2021-11-01)

Regulating Exciton–Phonon Coupling to Achieve a Near‐Unity Photoluminescence Quantum Yield in One‐Dimensional Hybrid Metal Halides
by: Hui Luo, et al.
Published: (2021-07-01)

On the origin of oscillations in two-dimensional spectra of excitonically-coupled molecular systems
by: Hong-Guang Duan, et al.
Published: (2015-01-01)

Interference among Multiple Vibronic Modes in Two-Dimensional Electronic Spectroscopy
by: Camille A. Farfan, et al.
Published: (2020-01-01)

Unusual Rearrangements of Radical Cations: The Role of Vibronic Coupling
by: Thomas Bally
Published: (2016-03-01)

Vibronic exciton–phonon states in stack-engineered van der Waals heterojunction photodiodes
by: Barati, Fatemeh, et al.
Published: (2023)

Exciton-carrier coupling in a metal halide perovskite nanocrystal assembly probed by two-dimensional coherent spectroscopy
by: Esteban Rojas-Gatjens, et al.
Published: (2024-01-01)

Asymmetry in the Qy Fluorescence and Absorption Spectra of Chlorophyll a Pertaining to Exciton Dynamics
by: Jeffrey R. Reimers, et al.
Published: (2020-12-01)

Tracking ultrafast reactions in organic materials through vibrational coherence: vibronic coupling mechanisms in singlet fission
by: Woojae Kim, et al.
Published: (2021-01-01)

Vibronic and Cationic Features of 2-Fluorobenzonitrile and 3-Fluorobenzonitrile Studied by REMPI and MATI Spectroscopy and Franck–Condon Simulations
by: Shuxian Li, et al.
Published: (2023-06-01)

A new tool for modelling lattices of organic polaritons
by: Thomas J Sturges, et al.
Published: (2022-01-01)

Color Stable Deep Blue Multi‐Resonance Organic Emitters with Narrow Emission and High Efficiency
by: Jihoon Kang, et al.
Published: (2023-09-01)

Ultrafast charge transfer and vibronic coupling in a laser-excited hybrid inorganic/organic interface
by: Matheus Jacobs, et al.
Published: (2020-01-01)

Purely Spin‐Vibronic Coupling Assisted Triplet to Singlet Up‐Conversion for Real Deep Blue Organic Light‐Emitting Diodes with Over 20% Efficiency and y Color Coordinate of 0.05
by: Vilas Venunath Patil, et al.
Published: (2021-10-01)

Vibronic Relaxation Pathways in Molecular Spin Qubit Na<sub>9</sub>[Ho(W<sub>5</sub>O<sub>18</sub>)<sub>2</sub>]·35H<sub>2</sub>O under Pressure
by: Janice L. Musfeldt, et al.
Published: (2023-02-01)

Dominant role of excitons in photosynthetic color-tuning and light-harvesting
by: Kõu Timpmann, et al.
Published: (2023-10-01)

Revealing the Exciton Fine Structure in Lead Halide Perovskite Nanocrystals
by: Lei Hou, et al.
Published: (2021-04-01)

High-Energy Long-Lived Emitting Mixed Excitons in Homopolymeric Adenine-Thymine DNA Duplexes
by: Ignacio Vayá, et al.
Published: (2022-05-01)

Angular‐Momentum Transfer Mediated by a Vibronic‐Bound‐State
by: Yun‐Yi Pai, et al.
Published: (2024-01-01)

Polaron Vibronic Progression Shapes the Optical Response of 2D Perovskites
by: Mateusz Dyksik, et al.
Published: (2024-02-01)

Nucleus-independent chemical shift profiles along the intrinsic distortion path for Jahn-Teller active molecules. Study on cyclopentadienyl radical and cobaltocene
by: Anđelković Ljubica, et al.
Published: (2015-01-01)

Signatures of Duschinsky Rotation in Femtosecond Coherence Spectra
by: Paul C. Arpin, et al.
Published: (2022-12-01)

Editorial: Vibrationally-Mediated Chemical Dynamics
by: Jacob C. Dean, et al.
Published: (2021-04-01)

Microwave studies of exciton condensation in germanium/
by: Basov, N. G. (Nikolai Gennadievich), 1922-
Published: (1979)

The Sign of Exciton-Photon Coupling in GaN-Based Triangular-like Ridge Cavity
by: Jing Zhou, et al.
Published: (2022-03-01)

Principle and Applications of the Coupling of Surface Plasmons and Excitons
by: Zhicong He, et al.
Published: (2020-03-01)

Hidden Euclidean Dynamical Symmetry in the U(<i>n</i> + 1) Vibron Model
by: Yu Zhang, et al.
Published: (2022-10-01)

Photocrosslinking Probes Proximity of Thymine Modifiers Tethering Excitonically Coupled Dye Aggregates to DNA Holliday Junction
by: Shibani Basu, et al.
Published: (2022-06-01)

A Simplified Treatment for Efficiently Modeling the Spectral Signal of Vibronic Transitions: Application to Aqueous Indole
by: Cheng Giuseppe Chen, et al.
Published: (2022-11-01)

Theoretical Description of Attosecond X-ray Absorption Spectroscopy of Frenkel Exciton Dynamics
by: Tim Hansen, et al.
Published: (2023-06-01)

Post-synthesis from Lewis acid–base interaction: an alternative way to generate light and harvest triplet excitons
by: Hengjia Liu, et al.
Published: (2022-07-01)

Wide Sargasso Sea /
by: Rhys, Jean
Published: (2006)

Exciton-plasmon coupling interactions: from principle to applications
by: Cao En, et al.
Published: (2018-01-01)

Theory of excitons /
by: 298547 Knox, Robert S.
Published: (1963)

Excitons in 2D perovskites for ultrafast terahertz photonic devices
by: Kumar, Abhishek, et al.
Published: (2020)

Advances in multi-dimensional coherent spectroscopy of semiconductor nanostructures
by: Galan Moody, et al.
Published: (2017-05-01)

Equivalence of Electron-Vibration Interaction and Charge-Induced Force Variations: A New O(1) Approach to an Old Problem
by: Tunna Baruah, et al.
Published: (2012-04-01)

Electronic and Molecular Structure of Transition Metal Complexes
by: Philip L.W. Tregenna-Piggott
Published: (2001-12-01)

Harvesting triplet excitons in lead-halide perovskites for room-temperature phosphorescence
by: Hu, Hongwei, et al.
Published: (2021)

Perylene Bisimide Cyclophanes: Structure–Property Relationships upon Variation of the Cavity Size
by: Jessica Rühe, et al.
Published: (2020-04-01)