Sodium [N,N′-ethylenebis(d-penicillaminato)]indate(III) tetrahydrate
The asymmetric unit of the title compound {systematic name: sodium [2-({2-[(1-carboxylato-2-methyl-2-sulfanidylpropyl)amino]ethyl}amino)-3-methyl-3-sulfanidylbutanoato-κ4S,N,N′,S′]indate(III) tetrahydrate}, Na[In(C12H20N2O4S2)]·4H2O, contains four indate(III) complex anions {[In(d-ebp)]−; d-H4ebp =...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2019-11-01
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| Series: | IUCrData |
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| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2414314619015293 |
| _version_ | 1818969902701084672 |
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| author | Nobuto Yoshinari Takumi Konno |
| author_facet | Nobuto Yoshinari Takumi Konno |
| author_sort | Nobuto Yoshinari |
| collection | DOAJ |
| description | The asymmetric unit of the title compound {systematic name: sodium [2-({2-[(1-carboxylato-2-methyl-2-sulfanidylpropyl)amino]ethyl}amino)-3-methyl-3-sulfanidylbutanoato-κ4S,N,N′,S′]indate(III) tetrahydrate}, Na[In(C12H20N2O4S2)]·4H2O, contains four indate(III) complex anions {[In(d-ebp)]−; d-H4ebp = N,N′-ethyelenebis(d-penicillamine)], four sodium(I) cations and sixteen water molecules. The indate(III) anions and sodium cations are alternately connected through coordination bonds between Na+ ions and the carboxylate groups of the complex anions, forming an infinite sixfold right-handed helix along the c-axis direction. In the crystal, the helices are linked by O—H...O hydrogen bonds between water molecules bound to Na+ ions and carboxylate groups. The crystal studied was twinned via a twofold axis about [001]. |
| first_indexed | 2024-12-20T14:27:58Z |
| format | Article |
| id | doaj.art-cf8bd5cb830f4bc7853c4ff002e14bb5 |
| institution | Directory Open Access Journal |
| issn | 2414-3146 |
| language | English |
| last_indexed | 2024-12-20T14:27:58Z |
| publishDate | 2019-11-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | IUCrData |
| spelling | doaj.art-cf8bd5cb830f4bc7853c4ff002e14bb52022-12-21T19:37:43ZengInternational Union of CrystallographyIUCrData2414-31462019-11-01411x19152910.1107/S2414314619015293sj4211Sodium [N,N′-ethylenebis(d-penicillaminato)]indate(III) tetrahydrateNobuto Yoshinari0Takumi Konno1Department of Chemistry, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, JapanDepartment of Chemistry, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, JapanThe asymmetric unit of the title compound {systematic name: sodium [2-({2-[(1-carboxylato-2-methyl-2-sulfanidylpropyl)amino]ethyl}amino)-3-methyl-3-sulfanidylbutanoato-κ4S,N,N′,S′]indate(III) tetrahydrate}, Na[In(C12H20N2O4S2)]·4H2O, contains four indate(III) complex anions {[In(d-ebp)]−; d-H4ebp = N,N′-ethyelenebis(d-penicillamine)], four sodium(I) cations and sixteen water molecules. The indate(III) anions and sodium cations are alternately connected through coordination bonds between Na+ ions and the carboxylate groups of the complex anions, forming an infinite sixfold right-handed helix along the c-axis direction. In the crystal, the helices are linked by O—H...O hydrogen bonds between water molecules bound to Na+ ions and carboxylate groups. The crystal studied was twinned via a twofold axis about [001].http://scripts.iucr.org/cgi-bin/paper?S2414314619015293indium ionthiolato complexcoordination compoundcrystal structuretwinning |
| spellingShingle | Nobuto Yoshinari Takumi Konno Sodium [N,N′-ethylenebis(d-penicillaminato)]indate(III) tetrahydrate IUCrData indium ion thiolato complex coordination compound crystal structure twinning |
| title | Sodium [N,N′-ethylenebis(d-penicillaminato)]indate(III) tetrahydrate |
| title_full | Sodium [N,N′-ethylenebis(d-penicillaminato)]indate(III) tetrahydrate |
| title_fullStr | Sodium [N,N′-ethylenebis(d-penicillaminato)]indate(III) tetrahydrate |
| title_full_unstemmed | Sodium [N,N′-ethylenebis(d-penicillaminato)]indate(III) tetrahydrate |
| title_short | Sodium [N,N′-ethylenebis(d-penicillaminato)]indate(III) tetrahydrate |
| title_sort | sodium n n ethylenebis d penicillaminato indate iii tetrahydrate |
| topic | indium ion thiolato complex coordination compound crystal structure twinning |
| url | http://scripts.iucr.org/cgi-bin/paper?S2414314619015293 |
| work_keys_str_mv | AT nobutoyoshinari sodiumnnethylenebisdpenicillaminatoindateiiitetrahydrate AT takumikonno sodiumnnethylenebisdpenicillaminatoindateiiitetrahydrate |