Negative Magnetoresistance in Hopping Regime of Lightly Doped Thermoelectric SnSe

Semiconducting SnSe, an analog of black phosphorus, recently attracted great scientific interest due to a disputed report of a large thermoelectric figure of merit, which has not been reproduced subsequently. Here we concentrate on the low-temperature ground state. To gain a better understanding of...

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Bibliographic Details
Main Authors: Marija Zorić, Naveen Singh Dhami, Kristian Bader, Peter Gille, Ana Smontara, Petar Popčević
Format: Article
Language:English
Published: MDPI AG 2023-04-01
Series:Materials
Subjects:
Online Access:https://www.mdpi.com/1996-1944/16/7/2863
Description
Summary:Semiconducting SnSe, an analog of black phosphorus, recently attracted great scientific interest due to a disputed report of a large thermoelectric figure of merit, which has not been reproduced subsequently. Here we concentrate on the low-temperature ground state. To gain a better understanding of the system, we present magneto-transport properties in high-quality single crystals of as-grown, lightly doped SnSe down to liquid helium temperatures. We show that SnSe behaves as a p-type doped semiconductor in the vicinity of a metal-insulator transition. Electronic transport at the lowest temperatures is dominated by the hopping mechanism. Negative magnetoresistance at low fields is well described by antilocalization, while positive magnetoresistance at higher fields is consistent with the shrinkage of localized impurity wavefunctions. At higher temperatures, a dilute metallic regime is realized where elusive <i>T</i><sup>2</sup> and <i>B</i><sup>2</sup> resistivity dependence is observed, posing a challenge to theoretical comprehension of the underlying physical mechanism.
ISSN:1996-1944