Basalt Fiber Modified Ethylene Vinyl Acetate/Magnesium Hydroxide Composites with Balanced Flame Retardancy and Improved Mechanical Properties
In this study, we selected basalt fiber (BF) as a functional filler to improve the mechanical properties of ethylene vinyl acetate (EVA)-based flame retardant materials. Firstly, BF was modified by grafting γ-aminopropyl triethoxysilane (KH550). Fourier transform infrared spectroscopy (FTIR), thermo...
Main Authors: | , , , , , |
---|---|
Format: | Article |
Language: | English |
Published: |
MDPI AG
2020-09-01
|
Series: | Polymers |
Subjects: | |
Online Access: | https://www.mdpi.com/2073-4360/12/9/2107 |
_version_ | 1797553610775592960 |
---|---|
author | Dongwei Yao Guangzhong Yin Qingqing Bi Xu Yin Na Wang De-Yi Wang |
author_facet | Dongwei Yao Guangzhong Yin Qingqing Bi Xu Yin Na Wang De-Yi Wang |
author_sort | Dongwei Yao |
collection | DOAJ |
description | In this study, we selected basalt fiber (BF) as a functional filler to improve the mechanical properties of ethylene vinyl acetate (EVA)-based flame retardant materials. Firstly, BF was modified by grafting γ-aminopropyl triethoxysilane (KH550). Fourier transform infrared spectroscopy (FTIR), thermogravimetric analysis (TGA), scanning electron microscope (SEM), and energy dispersive X-ray spectroscopy (EDS) were used to comprehensively prove the successful modification of the BF surface. Subsequently, the modified BF was introduced into the EVA/magnesium hydroxide (MH) composites by melt blending. The limiting oxygen index (LOI), UL-94, cone calorimeter test, tensile test, and non-notched impact test were utilized to characterize both the flame retardant properties and mechanical properties of the EVA/MH composites. It was found that the mechanical properties were significantly enhanced without reducing the flame retardant properties of the EVA/MH composites. Notably, the surface treatment with silane is a simple and low-cost method for BF surface modification and the pathway designed in this study can be both practical and effective for polymer performance enhancement. |
first_indexed | 2024-03-10T16:18:02Z |
format | Article |
id | doaj.art-cf9c5dc15b564b45a8ba08cac385fa3a |
institution | Directory Open Access Journal |
issn | 2073-4360 |
language | English |
last_indexed | 2024-03-10T16:18:02Z |
publishDate | 2020-09-01 |
publisher | MDPI AG |
record_format | Article |
series | Polymers |
spelling | doaj.art-cf9c5dc15b564b45a8ba08cac385fa3a2023-11-20T13:54:26ZengMDPI AGPolymers2073-43602020-09-01129210710.3390/polym12092107Basalt Fiber Modified Ethylene Vinyl Acetate/Magnesium Hydroxide Composites with Balanced Flame Retardancy and Improved Mechanical PropertiesDongwei Yao0Guangzhong Yin1Qingqing Bi2Xu Yin3Na Wang4De-Yi Wang5Sino-Spanish Advanced Materials Institute, Shenyang University of Chemical Technology, Shenyang 110142, ChinaIMDEA Materials Institute, C/Eric Kandel, 2, Getafe, 28906 Madrid, SpainSino-Spanish Advanced Materials Institute, Shenyang University of Chemical Technology, Shenyang 110142, ChinaSino-Spanish Advanced Materials Institute, Shenyang University of Chemical Technology, Shenyang 110142, ChinaSino-Spanish Advanced Materials Institute, Shenyang University of Chemical Technology, Shenyang 110142, ChinaIMDEA Materials Institute, C/Eric Kandel, 2, Getafe, 28906 Madrid, SpainIn this study, we selected basalt fiber (BF) as a functional filler to improve the mechanical properties of ethylene vinyl acetate (EVA)-based flame retardant materials. Firstly, BF was modified by grafting γ-aminopropyl triethoxysilane (KH550). Fourier transform infrared spectroscopy (FTIR), thermogravimetric analysis (TGA), scanning electron microscope (SEM), and energy dispersive X-ray spectroscopy (EDS) were used to comprehensively prove the successful modification of the BF surface. Subsequently, the modified BF was introduced into the EVA/magnesium hydroxide (MH) composites by melt blending. The limiting oxygen index (LOI), UL-94, cone calorimeter test, tensile test, and non-notched impact test were utilized to characterize both the flame retardant properties and mechanical properties of the EVA/MH composites. It was found that the mechanical properties were significantly enhanced without reducing the flame retardant properties of the EVA/MH composites. Notably, the surface treatment with silane is a simple and low-cost method for BF surface modification and the pathway designed in this study can be both practical and effective for polymer performance enhancement.https://www.mdpi.com/2073-4360/12/9/2107ethylene vinyl acetate (EVA)magnesium hydroxide (MH)basalt fiber (BF)flame retardancymechanical properties |
spellingShingle | Dongwei Yao Guangzhong Yin Qingqing Bi Xu Yin Na Wang De-Yi Wang Basalt Fiber Modified Ethylene Vinyl Acetate/Magnesium Hydroxide Composites with Balanced Flame Retardancy and Improved Mechanical Properties Polymers ethylene vinyl acetate (EVA) magnesium hydroxide (MH) basalt fiber (BF) flame retardancy mechanical properties |
title | Basalt Fiber Modified Ethylene Vinyl Acetate/Magnesium Hydroxide Composites with Balanced Flame Retardancy and Improved Mechanical Properties |
title_full | Basalt Fiber Modified Ethylene Vinyl Acetate/Magnesium Hydroxide Composites with Balanced Flame Retardancy and Improved Mechanical Properties |
title_fullStr | Basalt Fiber Modified Ethylene Vinyl Acetate/Magnesium Hydroxide Composites with Balanced Flame Retardancy and Improved Mechanical Properties |
title_full_unstemmed | Basalt Fiber Modified Ethylene Vinyl Acetate/Magnesium Hydroxide Composites with Balanced Flame Retardancy and Improved Mechanical Properties |
title_short | Basalt Fiber Modified Ethylene Vinyl Acetate/Magnesium Hydroxide Composites with Balanced Flame Retardancy and Improved Mechanical Properties |
title_sort | basalt fiber modified ethylene vinyl acetate magnesium hydroxide composites with balanced flame retardancy and improved mechanical properties |
topic | ethylene vinyl acetate (EVA) magnesium hydroxide (MH) basalt fiber (BF) flame retardancy mechanical properties |
url | https://www.mdpi.com/2073-4360/12/9/2107 |
work_keys_str_mv | AT dongweiyao basaltfibermodifiedethylenevinylacetatemagnesiumhydroxidecompositeswithbalancedflameretardancyandimprovedmechanicalproperties AT guangzhongyin basaltfibermodifiedethylenevinylacetatemagnesiumhydroxidecompositeswithbalancedflameretardancyandimprovedmechanicalproperties AT qingqingbi basaltfibermodifiedethylenevinylacetatemagnesiumhydroxidecompositeswithbalancedflameretardancyandimprovedmechanicalproperties AT xuyin basaltfibermodifiedethylenevinylacetatemagnesiumhydroxidecompositeswithbalancedflameretardancyandimprovedmechanicalproperties AT nawang basaltfibermodifiedethylenevinylacetatemagnesiumhydroxidecompositeswithbalancedflameretardancyandimprovedmechanicalproperties AT deyiwang basaltfibermodifiedethylenevinylacetatemagnesiumhydroxidecompositeswithbalancedflameretardancyandimprovedmechanicalproperties |