pH-Responsive Graphene Oxide-Based 2D/3D Composite for Enhancing Anti-Corrosion Properties of Epoxy Coating
The functionalized graphene oxide (GO)-based composites as fillers added into organic coatings are desired for realizing the longstanding corrosion protection of carbon steel. Here, the pH-responsive two-dimensional/three-dimensional (2D/3D) GO-based composite (ZIF–90–AAP/GO) was developed by enviro...
| Main Authors: | , , , , , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
MDPI AG
2024-02-01
|
| Series: | Nanomaterials |
| Subjects: | |
| Online Access: | https://www.mdpi.com/2079-4991/14/4/323 |
| _version_ | 1797297359651078144 |
|---|---|
| author | Jian Wang Yangyang Cao Jieru Wan Meng Zhang Yunqiang Li Yanli Wang Dalei Song Tao Zhang Jun Wang |
| author_facet | Jian Wang Yangyang Cao Jieru Wan Meng Zhang Yunqiang Li Yanli Wang Dalei Song Tao Zhang Jun Wang |
| author_sort | Jian Wang |
| collection | DOAJ |
| description | The functionalized graphene oxide (GO)-based composites as fillers added into organic coatings are desired for realizing the longstanding corrosion protection of carbon steel. Here, the pH-responsive two-dimensional/three-dimensional (2D/3D) GO-based composite (ZIF–90–AAP/GO) was developed by environmentally friendly corrosion inhibitor 4-aminoantipyrine (AAP) anchored on the in situ growth of zeolite imidazolate framework–90 (ZIF–90) on the GO surface (ZIF–90/GO) through the Schiff base reaction. The active filler (ZIF–90–AAP/GO) was incorporated into an epoxy coating (EP) to obtain a high-performance self-healing coating on the surface of carbon steel. ZIF–90–AAP can greatly improve dispersion and compatibility of GO in EP. The low-frequency impedance modulus of ZIF–90–AAP/GO–EP can still reach up to 1.35 × 10<sup>10</sup> Ω⋅cm<sup>2</sup> after 40 days, which is about three orders of magnitude higher than that of the EP containing GO (GO–EP) relying on its passive and active corrosion protection. Meanwhile, ZIF–90–AAP/GO–EP exhibits excellent self-healing performance. The self-healing rate of ZIF–90–AAP/GO changes from negative to positive after 24 h, which results from the effective corrosion inhibition activity of ZIF–90–AAP for carbon steel based on the pH-triggered controlled release of AAP. The developed pH-responsive 2D/3D GO-based composite coating is very attractive for the corrosion protection of carbon steel. |
| first_indexed | 2024-03-07T22:19:22Z |
| format | Article |
| id | doaj.art-cfa48c02a2494300880859950360f398 |
| institution | Directory Open Access Journal |
| issn | 2079-4991 |
| language | English |
| last_indexed | 2024-03-07T22:19:22Z |
| publishDate | 2024-02-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Nanomaterials |
| spelling | doaj.art-cfa48c02a2494300880859950360f3982024-02-23T15:29:20ZengMDPI AGNanomaterials2079-49912024-02-0114432310.3390/nano14040323pH-Responsive Graphene Oxide-Based 2D/3D Composite for Enhancing Anti-Corrosion Properties of Epoxy CoatingJian Wang0Yangyang Cao1Jieru Wan2Meng Zhang3Yunqiang Li4Yanli Wang5Dalei Song6Tao Zhang7Jun Wang8Key Laboratory of Superlight Materials and Surface Technology, Ministry of Education, College of Materials Science and Chemical Engineering, Harbin Engineering University, Harbin 150001, ChinaKey Laboratory of Superlight Materials and Surface Technology, Ministry of Education, College of Materials Science and Chemical Engineering, Harbin Engineering University, Harbin 150001, ChinaKey Laboratory of Superlight Materials and Surface Technology, Ministry of Education, College of Materials Science and Chemical Engineering, Harbin Engineering University, Harbin 150001, ChinaKey Laboratory of Superlight Materials and Surface Technology, Ministry of Education, College of Materials Science and Chemical Engineering, Harbin Engineering University, Harbin 150001, ChinaKey Laboratory of Superlight Materials and Surface Technology, Ministry of Education, College of Materials Science and Chemical Engineering, Harbin Engineering University, Harbin 150001, ChinaKey Laboratory of Superlight Materials and Surface Technology, Ministry of Education, College of Materials Science and Chemical Engineering, Harbin Engineering University, Harbin 150001, ChinaKey Laboratory of Superlight Materials and Surface Technology, Ministry of Education, College of Materials Science and Chemical Engineering, Harbin Engineering University, Harbin 150001, ChinaKey Laboratory of Superlight Materials and Surface Technology, Ministry of Education, College of Materials Science and Chemical Engineering, Harbin Engineering University, Harbin 150001, ChinaKey Laboratory of Superlight Materials and Surface Technology, Ministry of Education, College of Materials Science and Chemical Engineering, Harbin Engineering University, Harbin 150001, ChinaThe functionalized graphene oxide (GO)-based composites as fillers added into organic coatings are desired for realizing the longstanding corrosion protection of carbon steel. Here, the pH-responsive two-dimensional/three-dimensional (2D/3D) GO-based composite (ZIF–90–AAP/GO) was developed by environmentally friendly corrosion inhibitor 4-aminoantipyrine (AAP) anchored on the in situ growth of zeolite imidazolate framework–90 (ZIF–90) on the GO surface (ZIF–90/GO) through the Schiff base reaction. The active filler (ZIF–90–AAP/GO) was incorporated into an epoxy coating (EP) to obtain a high-performance self-healing coating on the surface of carbon steel. ZIF–90–AAP can greatly improve dispersion and compatibility of GO in EP. The low-frequency impedance modulus of ZIF–90–AAP/GO–EP can still reach up to 1.35 × 10<sup>10</sup> Ω⋅cm<sup>2</sup> after 40 days, which is about three orders of magnitude higher than that of the EP containing GO (GO–EP) relying on its passive and active corrosion protection. Meanwhile, ZIF–90–AAP/GO–EP exhibits excellent self-healing performance. The self-healing rate of ZIF–90–AAP/GO changes from negative to positive after 24 h, which results from the effective corrosion inhibition activity of ZIF–90–AAP for carbon steel based on the pH-triggered controlled release of AAP. The developed pH-responsive 2D/3D GO-based composite coating is very attractive for the corrosion protection of carbon steel.https://www.mdpi.com/2079-4991/14/4/323ZIF–90graphene oxideself-healingcoatingcorrosion protection |
| spellingShingle | Jian Wang Yangyang Cao Jieru Wan Meng Zhang Yunqiang Li Yanli Wang Dalei Song Tao Zhang Jun Wang pH-Responsive Graphene Oxide-Based 2D/3D Composite for Enhancing Anti-Corrosion Properties of Epoxy Coating Nanomaterials ZIF–90 graphene oxide self-healing coating corrosion protection |
| title | pH-Responsive Graphene Oxide-Based 2D/3D Composite for Enhancing Anti-Corrosion Properties of Epoxy Coating |
| title_full | pH-Responsive Graphene Oxide-Based 2D/3D Composite for Enhancing Anti-Corrosion Properties of Epoxy Coating |
| title_fullStr | pH-Responsive Graphene Oxide-Based 2D/3D Composite for Enhancing Anti-Corrosion Properties of Epoxy Coating |
| title_full_unstemmed | pH-Responsive Graphene Oxide-Based 2D/3D Composite for Enhancing Anti-Corrosion Properties of Epoxy Coating |
| title_short | pH-Responsive Graphene Oxide-Based 2D/3D Composite for Enhancing Anti-Corrosion Properties of Epoxy Coating |
| title_sort | ph responsive graphene oxide based 2d 3d composite for enhancing anti corrosion properties of epoxy coating |
| topic | ZIF–90 graphene oxide self-healing coating corrosion protection |
| url | https://www.mdpi.com/2079-4991/14/4/323 |
| work_keys_str_mv | AT jianwang phresponsivegrapheneoxidebased2d3dcompositeforenhancinganticorrosionpropertiesofepoxycoating AT yangyangcao phresponsivegrapheneoxidebased2d3dcompositeforenhancinganticorrosionpropertiesofepoxycoating AT jieruwan phresponsivegrapheneoxidebased2d3dcompositeforenhancinganticorrosionpropertiesofepoxycoating AT mengzhang phresponsivegrapheneoxidebased2d3dcompositeforenhancinganticorrosionpropertiesofepoxycoating AT yunqiangli phresponsivegrapheneoxidebased2d3dcompositeforenhancinganticorrosionpropertiesofepoxycoating AT yanliwang phresponsivegrapheneoxidebased2d3dcompositeforenhancinganticorrosionpropertiesofepoxycoating AT daleisong phresponsivegrapheneoxidebased2d3dcompositeforenhancinganticorrosionpropertiesofepoxycoating AT taozhang phresponsivegrapheneoxidebased2d3dcompositeforenhancinganticorrosionpropertiesofepoxycoating AT junwang phresponsivegrapheneoxidebased2d3dcompositeforenhancinganticorrosionpropertiesofepoxycoating |