TiSiCN as Coatings Resistant to Corrosion and Neutron Activation
The aim of the present paper was to evaluate the effect of neutron activation on TiSiCN carbonitrides coatings prepared at different C/N ratios (0.4 for under stoichiometric and 1.6 for over stoichiometric). The coatings were prepared by cathodic arc deposition using one cathode constructed of Ti88...
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MDPI AG
2023-02-01
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| Online Access: | https://www.mdpi.com/1996-1944/16/5/1835 |
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| author | Matlab N. Mirzayev Anca C. Parau Lyubomir Slavov Mihaela Dinu Dimitar Neov Zdravka Slavkova Evgeni P. Popov Maria Belova Kanan Hasanov Fuad A. Aliyev Alina Vladescu (Dragomir) |
| author_facet | Matlab N. Mirzayev Anca C. Parau Lyubomir Slavov Mihaela Dinu Dimitar Neov Zdravka Slavkova Evgeni P. Popov Maria Belova Kanan Hasanov Fuad A. Aliyev Alina Vladescu (Dragomir) |
| author_sort | Matlab N. Mirzayev |
| collection | DOAJ |
| description | The aim of the present paper was to evaluate the effect of neutron activation on TiSiCN carbonitrides coatings prepared at different C/N ratios (0.4 for under stoichiometric and 1.6 for over stoichiometric). The coatings were prepared by cathodic arc deposition using one cathode constructed of Ti88 at.%-Si12 at.% (99.99% purity). The coatings were comparatively examined for elemental and phase composition, morphology, and anticorrosive properties in 3.5% NaCl solution. All the coatings exhibited f.c.c. solid solution structures and had a (111) preferred orientation. Under stoichiometric structure, they proved to be resistant to corrosive attack in 3.5% NaCl and of these coatings the TiSiCN was found to have the best corrosion resistance. From all tested coatings, TiSiCN have proven to be the most suitable candidates for operation under severe conditions that are present in nuclear applications (high temperature, corrosion, etc.). |
| first_indexed | 2024-03-11T07:19:59Z |
| format | Article |
| id | doaj.art-cfb5595ae6e84cb2a0e32cc5fb49e5d6 |
| institution | Directory Open Access Journal |
| issn | 1996-1944 |
| language | English |
| last_indexed | 2024-03-11T07:19:59Z |
| publishDate | 2023-02-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Materials |
| spelling | doaj.art-cfb5595ae6e84cb2a0e32cc5fb49e5d62023-11-17T08:03:32ZengMDPI AGMaterials1996-19442023-02-01165183510.3390/ma16051835TiSiCN as Coatings Resistant to Corrosion and Neutron ActivationMatlab N. Mirzayev0Anca C. Parau1Lyubomir Slavov2Mihaela Dinu3Dimitar Neov4Zdravka Slavkova5Evgeni P. Popov6Maria Belova7Kanan Hasanov8Fuad A. Aliyev9Alina Vladescu (Dragomir)10Joint Institute for Nuclear Research, 141980 Dubna, RussiaNational Institute of Research and Development for Optoelectronics INOE 2000, 409 Atomistilor St., 77125 Magurele, RomaniaInstitute of Electronics, Bulgarian Academy of Sciences, 1784 Sofia, BulgariaNational Institute of Research and Development for Optoelectronics INOE 2000, 409 Atomistilor St., 77125 Magurele, RomaniaJoint Institute for Nuclear Research, 141980 Dubna, RussiaInstitute of Solid-State Physics, Bulgarian Academy of Sciences, 1784 Sofia, BulgariaJoint Institute for Nuclear Research, 141980 Dubna, RussiaJoint Institute for Nuclear Research, 141980 Dubna, RussiaInstitute of Radiation Problems, Azerbaijan National Academy of Sciences, AZ1143 Baku, AzerbaijanJoint Institute for Nuclear Research, 141980 Dubna, RussiaNational Institute of Research and Development for Optoelectronics INOE 2000, 409 Atomistilor St., 77125 Magurele, RomaniaThe aim of the present paper was to evaluate the effect of neutron activation on TiSiCN carbonitrides coatings prepared at different C/N ratios (0.4 for under stoichiometric and 1.6 for over stoichiometric). The coatings were prepared by cathodic arc deposition using one cathode constructed of Ti88 at.%-Si12 at.% (99.99% purity). The coatings were comparatively examined for elemental and phase composition, morphology, and anticorrosive properties in 3.5% NaCl solution. All the coatings exhibited f.c.c. solid solution structures and had a (111) preferred orientation. Under stoichiometric structure, they proved to be resistant to corrosive attack in 3.5% NaCl and of these coatings the TiSiCN was found to have the best corrosion resistance. From all tested coatings, TiSiCN have proven to be the most suitable candidates for operation under severe conditions that are present in nuclear applications (high temperature, corrosion, etc.).https://www.mdpi.com/1996-1944/16/5/1835carbonitridescorrosion resistancesurface morphologyneutron activation analysiscrystal structurepotentiodynamic polarization |
| spellingShingle | Matlab N. Mirzayev Anca C. Parau Lyubomir Slavov Mihaela Dinu Dimitar Neov Zdravka Slavkova Evgeni P. Popov Maria Belova Kanan Hasanov Fuad A. Aliyev Alina Vladescu (Dragomir) TiSiCN as Coatings Resistant to Corrosion and Neutron Activation Materials carbonitrides corrosion resistance surface morphology neutron activation analysis crystal structure potentiodynamic polarization |
| title | TiSiCN as Coatings Resistant to Corrosion and Neutron Activation |
| title_full | TiSiCN as Coatings Resistant to Corrosion and Neutron Activation |
| title_fullStr | TiSiCN as Coatings Resistant to Corrosion and Neutron Activation |
| title_full_unstemmed | TiSiCN as Coatings Resistant to Corrosion and Neutron Activation |
| title_short | TiSiCN as Coatings Resistant to Corrosion and Neutron Activation |
| title_sort | tisicn as coatings resistant to corrosion and neutron activation |
| topic | carbonitrides corrosion resistance surface morphology neutron activation analysis crystal structure potentiodynamic polarization |
| url | https://www.mdpi.com/1996-1944/16/5/1835 |
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