Corrosion Behavior of Sensitized AISI 304 Stainless Steel in Acid Chloride Solution

Corrosion resistance of sensitized austenitic stainless steel (SS) in chloride environments is currently the subject of numerous studies. Most of them are focused on neutral chloride solutions at room temperature and the experiments are carried out on ground stainless steels surfaces. This paper dea...

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Main Authors: Viera Zatkalíková, Milan Uhríčik, Lenka Markovičová, Lenka Kuchariková
Format: Article
Language:English
Published: MDPI AG 2022-11-01
Series:Materials
Subjects:
Online Access:https://www.mdpi.com/1996-1944/15/23/8543
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author Viera Zatkalíková
Milan Uhríčik
Lenka Markovičová
Lenka Kuchariková
author_facet Viera Zatkalíková
Milan Uhríčik
Lenka Markovičová
Lenka Kuchariková
author_sort Viera Zatkalíková
collection DOAJ
description Corrosion resistance of sensitized austenitic stainless steel (SS) in chloride environments is currently the subject of numerous studies. Most of them are focused on neutral chloride solutions at room temperature and the experiments are carried out on ground stainless steels surfaces. This paper deals with the corrosion behavior of sensitized AISI 304 stainless steel in acid 1 M chloride solution (pH = 1.1) at the temperatures of 20 ± 3 °C and 50 °C. The specimens after sensitization are tested as covered by high-temperature surface oxides (“heat tinted”), and also after their chemical removal to assess the impact of the surface state on corrosion resistance. Potentiodynamic polarization (PP) and exposure immersion test are used as the independent corrosion tests. Microstructure before/after exposure immersion test is evaluated by optical microscopy (OM) and SEM. The results obtained showed that sensitization significantly conditions corrosion regardless of the removal of high-temperature oxides, and the elevated temperature mainly acts as its accelerating factor.
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spelling doaj.art-cfb80e1aae944e9495f87c8bee0ec9a62023-11-24T11:30:02ZengMDPI AGMaterials1996-19442022-11-011523854310.3390/ma15238543Corrosion Behavior of Sensitized AISI 304 Stainless Steel in Acid Chloride SolutionViera Zatkalíková0Milan Uhríčik1Lenka Markovičová2Lenka Kuchariková3Department of Materials Engineering, Faculty of Mechanical Engineering, University of Žilina, Univerzitná 8215/1, 010 26 Žilina, SlovakiaDepartment of Materials Engineering, Faculty of Mechanical Engineering, University of Žilina, Univerzitná 8215/1, 010 26 Žilina, SlovakiaDepartment of Materials Engineering, Faculty of Mechanical Engineering, University of Žilina, Univerzitná 8215/1, 010 26 Žilina, SlovakiaDepartment of Materials Engineering, Faculty of Mechanical Engineering, University of Žilina, Univerzitná 8215/1, 010 26 Žilina, SlovakiaCorrosion resistance of sensitized austenitic stainless steel (SS) in chloride environments is currently the subject of numerous studies. Most of them are focused on neutral chloride solutions at room temperature and the experiments are carried out on ground stainless steels surfaces. This paper deals with the corrosion behavior of sensitized AISI 304 stainless steel in acid 1 M chloride solution (pH = 1.1) at the temperatures of 20 ± 3 °C and 50 °C. The specimens after sensitization are tested as covered by high-temperature surface oxides (“heat tinted”), and also after their chemical removal to assess the impact of the surface state on corrosion resistance. Potentiodynamic polarization (PP) and exposure immersion test are used as the independent corrosion tests. Microstructure before/after exposure immersion test is evaluated by optical microscopy (OM) and SEM. The results obtained showed that sensitization significantly conditions corrosion regardless of the removal of high-temperature oxides, and the elevated temperature mainly acts as its accelerating factor.https://www.mdpi.com/1996-1944/15/23/8543sensitizationaustenitic stainless steelcorrosionchromium depletionpotentiodynamic polarizationexposure immersion test
spellingShingle Viera Zatkalíková
Milan Uhríčik
Lenka Markovičová
Lenka Kuchariková
Corrosion Behavior of Sensitized AISI 304 Stainless Steel in Acid Chloride Solution
Materials
sensitization
austenitic stainless steel
corrosion
chromium depletion
potentiodynamic polarization
exposure immersion test
title Corrosion Behavior of Sensitized AISI 304 Stainless Steel in Acid Chloride Solution
title_full Corrosion Behavior of Sensitized AISI 304 Stainless Steel in Acid Chloride Solution
title_fullStr Corrosion Behavior of Sensitized AISI 304 Stainless Steel in Acid Chloride Solution
title_full_unstemmed Corrosion Behavior of Sensitized AISI 304 Stainless Steel in Acid Chloride Solution
title_short Corrosion Behavior of Sensitized AISI 304 Stainless Steel in Acid Chloride Solution
title_sort corrosion behavior of sensitized aisi 304 stainless steel in acid chloride solution
topic sensitization
austenitic stainless steel
corrosion
chromium depletion
potentiodynamic polarization
exposure immersion test
url https://www.mdpi.com/1996-1944/15/23/8543
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AT milanuhricik corrosionbehaviorofsensitizedaisi304stainlesssteelinacidchloridesolution
AT lenkamarkovicova corrosionbehaviorofsensitizedaisi304stainlesssteelinacidchloridesolution
AT lenkakucharikova corrosionbehaviorofsensitizedaisi304stainlesssteelinacidchloridesolution