Transport of nitrate-containing groundwater to coastal areas through buried tunnel valleys, Denmark

Nitrogen impact on the aquatic environment, including coastal areas, is too high in many countries worldwide, particularly in areas with intensive agriculture. Efficient mitigation initiatives demand that important pathways and the fate of nitrate in the hydrological cycle are known. In this study,...

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Main Authors: Peter B.E. Sandersen, Hyojin Kim, Rasmus Jacobsen, Jesper B. Pedersen, Birgitte Hansen
Format: Article
Jezik:English
Izdano: Geological Survey of Denmark and Greenland 2023-11-01
Serija:GEUS Bulletin
Teme:
Online dostop:https://geusbulletin.org/index.php/geusb/article/view/8351/14410
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author Peter B.E. Sandersen
Hyojin Kim
Rasmus Jacobsen
Jesper B. Pedersen
Birgitte Hansen
author_facet Peter B.E. Sandersen
Hyojin Kim
Rasmus Jacobsen
Jesper B. Pedersen
Birgitte Hansen
author_sort Peter B.E. Sandersen
collection DOAJ
description Nitrogen impact on the aquatic environment, including coastal areas, is too high in many countries worldwide, particularly in areas with intensive agriculture. Efficient mitigation initiatives demand that important pathways and the fate of nitrate in the hydrological cycle are known. In this study, we focus on groundwater nitrate contamination in two near-shore catchment areas in north-west Denmark. Groundwater in the area is mainly located in buried tunnel valleys, which are subsurface structures eroded by meltwater during Pleistocene glaciations in former glaciated areas. Groundwater samples from the aquifers inside the buried valleys reveal the presence of up to 120 mg/l nitrate down to 10 m below sea level and about 1 km down from the stream outlet towards the coast. We interpret the complex tunnel-valley infill to be responsible for the spatial heterogeneity of the groundwater geochemistry, where sandy geological windows create localised hydraulic pathways and complex redox structures. Groundwater and stream water chemistry in the study area clearly demonstrate the role of groundwater in nitrate transport within the catchment as well as the direct pathway to the coast bypassing the stream and riverine systems. Our results show that the buried tunnel valleys potentially contribute to submarine groundwater discharge and therefore could be responsible for a hitherto unaccounted input of nitrogen to the marine environment.
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spelling doaj.art-cfbbf07caaf24f3e9941802c4446414f2023-11-29T10:12:08ZengGeological Survey of Denmark and GreenlandGEUS Bulletin2597-21542023-11-015311410.34194/geusb.v53.83518351Transport of nitrate-containing groundwater to coastal areas through buried tunnel valleys, DenmarkPeter B.E. Sandersen0Hyojin Kim1Rasmus Jacobsen2Jesper B. Pedersen3Birgitte Hansen4Department of Near-Surface Land and Marine Geology, Geological Survey of Denmark and Greenland, Aarhus, DenmarkDepartment of Geochemistry, Geological Survey of Denmark and Greenland, Copenhagen, DenmarkDepartment of Geochemistry, Geological Survey of Denmark and Greenland, Copenhagen, DenmarkHydroGeophysics Group, Department of Geoscience, Aarhus University, Aarhus, DenmarkDepartment of Geochemistry, Geological Survey of Denmark and Greenland, Copenhagen, DenmarkNitrogen impact on the aquatic environment, including coastal areas, is too high in many countries worldwide, particularly in areas with intensive agriculture. Efficient mitigation initiatives demand that important pathways and the fate of nitrate in the hydrological cycle are known. In this study, we focus on groundwater nitrate contamination in two near-shore catchment areas in north-west Denmark. Groundwater in the area is mainly located in buried tunnel valleys, which are subsurface structures eroded by meltwater during Pleistocene glaciations in former glaciated areas. Groundwater samples from the aquifers inside the buried valleys reveal the presence of up to 120 mg/l nitrate down to 10 m below sea level and about 1 km down from the stream outlet towards the coast. We interpret the complex tunnel-valley infill to be responsible for the spatial heterogeneity of the groundwater geochemistry, where sandy geological windows create localised hydraulic pathways and complex redox structures. Groundwater and stream water chemistry in the study area clearly demonstrate the role of groundwater in nitrate transport within the catchment as well as the direct pathway to the coast bypassing the stream and riverine systems. Our results show that the buried tunnel valleys potentially contribute to submarine groundwater discharge and therefore could be responsible for a hitherto unaccounted input of nitrogen to the marine environment.https://geusbulletin.org/index.php/geusb/article/view/8351/14410submarine groundwater dischargeredox modellingburied tunnel valleysnitrate in groundwaternitrogen flux to the marine environment
spellingShingle Peter B.E. Sandersen
Hyojin Kim
Rasmus Jacobsen
Jesper B. Pedersen
Birgitte Hansen
Transport of nitrate-containing groundwater to coastal areas through buried tunnel valleys, Denmark
GEUS Bulletin
submarine groundwater discharge
redox modelling
buried tunnel valleys
nitrate in groundwater
nitrogen flux to the marine environment
title Transport of nitrate-containing groundwater to coastal areas through buried tunnel valleys, Denmark
title_full Transport of nitrate-containing groundwater to coastal areas through buried tunnel valleys, Denmark
title_fullStr Transport of nitrate-containing groundwater to coastal areas through buried tunnel valleys, Denmark
title_full_unstemmed Transport of nitrate-containing groundwater to coastal areas through buried tunnel valleys, Denmark
title_short Transport of nitrate-containing groundwater to coastal areas through buried tunnel valleys, Denmark
title_sort transport of nitrate containing groundwater to coastal areas through buried tunnel valleys denmark
topic submarine groundwater discharge
redox modelling
buried tunnel valleys
nitrate in groundwater
nitrogen flux to the marine environment
url https://geusbulletin.org/index.php/geusb/article/view/8351/14410
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AT rasmusjacobsen transportofnitratecontaininggroundwatertocoastalareasthroughburiedtunnelvalleysdenmark
AT jesperbpedersen transportofnitratecontaininggroundwatertocoastalareasthroughburiedtunnelvalleysdenmark
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