Use of C,N-chelated triorganotin(IV) fluoride for fluorination of organic compounds, coordination compounds, phosphines, silanes and stannanes
C,N-chelated triorganotin(IV) compounds containing the LCN ligand, where LCN is {2-[(CH3)2 NCH2]C6 H4} -, reveal the monomeric structure in solution as well as in the solid state with pentacoordinated tin atom in trigonal bipyramidal coordination polyhedra. These compounds were used as mild and very...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
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De Gruyter
2011-09-01
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| Series: | Main Group Metal Chemistry |
| Subjects: | |
| Online Access: | https://doi.org/10.1515/mgmc.2011.002 |
| _version_ | 1819124280398446592 |
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| author | Švec Petr Růžička Aleš |
| author_facet | Švec Petr Růžička Aleš |
| author_sort | Švec Petr |
| collection | DOAJ |
| description | C,N-chelated triorganotin(IV) compounds containing the LCN ligand, where LCN is {2-[(CH3)2 NCH2]C6 H4} -, reveal the monomeric structure in solution as well as in the solid state with pentacoordinated tin atom in trigonal bipyramidal coordination polyhedra. These compounds were used as mild and very efficient metathetical fluorinating agents in fluorinations of various organic, inorganic substrates and organometallic species containing E-Cl (E = C, Si, P, S and metal) bond(s) (metal halides, phosphines, silanes, etc.) as well as the F ion selective carriers with low detection limits. |
| first_indexed | 2024-12-22T07:21:44Z |
| format | Article |
| id | doaj.art-cfc61d72c9e74a61b3037268036b1e2a |
| institution | Directory Open Access Journal |
| issn | 0792-1241 2191-0219 |
| language | English |
| last_indexed | 2024-12-22T07:21:44Z |
| publishDate | 2011-09-01 |
| publisher | De Gruyter |
| record_format | Article |
| series | Main Group Metal Chemistry |
| spelling | doaj.art-cfc61d72c9e74a61b3037268036b1e2a2022-12-21T18:34:15ZengDe GruyterMain Group Metal Chemistry0792-12412191-02192011-09-01341-272510.1515/mgmc.2011.002Use of C,N-chelated triorganotin(IV) fluoride for fluorination of organic compounds, coordination compounds, phosphines, silanes and stannanesŠvec PetrRůžička Aleš0Department of General and Inorganic Chemistry, Faculty of Chemical Technology, University of Pardubice, Studentská 573, CZ-532 10, Pardubice, Czech RepublicC,N-chelated triorganotin(IV) compounds containing the LCN ligand, where LCN is {2-[(CH3)2 NCH2]C6 H4} -, reveal the monomeric structure in solution as well as in the solid state with pentacoordinated tin atom in trigonal bipyramidal coordination polyhedra. These compounds were used as mild and very efficient metathetical fluorinating agents in fluorinations of various organic, inorganic substrates and organometallic species containing E-Cl (E = C, Si, P, S and metal) bond(s) (metal halides, phosphines, silanes, etc.) as well as the F ion selective carriers with low detection limits.https://doi.org/10.1515/mgmc.2011.002c,n-ligandfluoridefluorinationorganotin(iv) compoundsstructure |
| spellingShingle | Švec Petr Růžička Aleš Use of C,N-chelated triorganotin(IV) fluoride for fluorination of organic compounds, coordination compounds, phosphines, silanes and stannanes Main Group Metal Chemistry c,n-ligand fluoride fluorination organotin(iv) compounds structure |
| title | Use of C,N-chelated triorganotin(IV) fluoride for fluorination of organic compounds, coordination compounds, phosphines, silanes and stannanes |
| title_full | Use of C,N-chelated triorganotin(IV) fluoride for fluorination of organic compounds, coordination compounds, phosphines, silanes and stannanes |
| title_fullStr | Use of C,N-chelated triorganotin(IV) fluoride for fluorination of organic compounds, coordination compounds, phosphines, silanes and stannanes |
| title_full_unstemmed | Use of C,N-chelated triorganotin(IV) fluoride for fluorination of organic compounds, coordination compounds, phosphines, silanes and stannanes |
| title_short | Use of C,N-chelated triorganotin(IV) fluoride for fluorination of organic compounds, coordination compounds, phosphines, silanes and stannanes |
| title_sort | use of c n chelated triorganotin iv fluoride for fluorination of organic compounds coordination compounds phosphines silanes and stannanes |
| topic | c,n-ligand fluoride fluorination organotin(iv) compounds structure |
| url | https://doi.org/10.1515/mgmc.2011.002 |
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