Hydrogen Emanations in Intracratonic Areas: New Guide Lines for Early Exploration Basin Screening

Offshore the emissions of dihydrogen are highlighted by the smokers along the oceanic ridges. Onshore in situ measurements in ophiolitic contexts and in old cratons have also proven the existence of numerous H<sub>2</sub> emissive areas. When H<sub>2</sub> emanations affect t...

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Main Authors: Isabelle Moretti, Emyrose Brouilly, Keanu Loiseau, Alain Prinzhofer, Eric Deville
Format: Article
Language:English
Published: MDPI AG 2021-03-01
Series:Geosciences
Subjects:
Online Access:https://www.mdpi.com/2076-3263/11/3/145
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author Isabelle Moretti
Emyrose Brouilly
Keanu Loiseau
Alain Prinzhofer
Eric Deville
author_facet Isabelle Moretti
Emyrose Brouilly
Keanu Loiseau
Alain Prinzhofer
Eric Deville
author_sort Isabelle Moretti
collection DOAJ
description Offshore the emissions of dihydrogen are highlighted by the smokers along the oceanic ridges. Onshore in situ measurements in ophiolitic contexts and in old cratons have also proven the existence of numerous H<sub>2</sub> emissive areas. When H<sub>2</sub> emanations affect the soils, small depressions and vegetation gaps are observed. These depressions, called <i>fairy circles</i>, have similarities with the pockmark and vent structures recognized for long time in the sea floor when natural gas escapes but also differences. In this paper we present a statistic approach of the density, size, and shape of the <i>fairy circles</i> in various basins. New data from Brazil and Australia are compared to the existing database already gathered in Russia, USA, and again Brazil. The comparison suggests that Australia could be one of the most promising areas for H<sub>2</sub> exploration, de facto a couple of wells already found H<sub>2</sub>, whereas they were drilled to look for hydrocarbons. The sum of areas from where H<sub>2</sub> is seeping overpasses 45 km<sup>2</sup> in Kangaroo Island as in the Yorke Peninsula. The size of the emitting structures, expressed in average diameter, varies from few meters to kilometers and the footprint expressed in % of the ground within the structures varies from 1 to 17%. However, globally the sets of <i>fairy circles</i> in the various basins are rather similar and one may consider that their characteristics are homogeneous and may help to characterize these H<sub>2</sub> emitting zones. Two kinds of size repartitions are observed, one with two maxima (25 m and between 220 m ± 25%) one with a simple Gaussian shape with a single maximum around 175 m ± 20%. Various geomorphological characteristics allow us to differentiate depressions of the ground due to gas emissions from karstic dolines. The more relevant ones are their slope and the ratio diameter vs. depth. At the opposite of the pockmark structures observed on the seafloor for which exclusion zones have been described, the H<sub>2</sub> emitting structures may intersect and they often growth by coalescence. These H<sub>2</sub> emitting structures are always observed, up to now, above Archean or Neoproterozoic cratons; it suggests that anoxia at the time the sedimentation and iron content play a key role in the H<sub>2</sub> sourcing.
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spelling doaj.art-cfcf812810184871baa2e069d18e0cce2023-11-21T11:35:00ZengMDPI AGGeosciences2076-32632021-03-0111314510.3390/geosciences11030145Hydrogen Emanations in Intracratonic Areas: New Guide Lines for Early Exploration Basin ScreeningIsabelle Moretti0Emyrose Brouilly1Keanu Loiseau2Alain Prinzhofer3Eric Deville4UPPA, LFCR, Rue de L’université, 64000 Pau, FranceUPPA, LFCR, Rue de L’université, 64000 Pau, FranceUPPA, LFCR, Rue de L’université, 64000 Pau, FranceGeo4U, Rio de Janeiro 22250-040, BrazilIfpschool, 92852 Rueil Malmaison, FranceOffshore the emissions of dihydrogen are highlighted by the smokers along the oceanic ridges. Onshore in situ measurements in ophiolitic contexts and in old cratons have also proven the existence of numerous H<sub>2</sub> emissive areas. When H<sub>2</sub> emanations affect the soils, small depressions and vegetation gaps are observed. These depressions, called <i>fairy circles</i>, have similarities with the pockmark and vent structures recognized for long time in the sea floor when natural gas escapes but also differences. In this paper we present a statistic approach of the density, size, and shape of the <i>fairy circles</i> in various basins. New data from Brazil and Australia are compared to the existing database already gathered in Russia, USA, and again Brazil. The comparison suggests that Australia could be one of the most promising areas for H<sub>2</sub> exploration, de facto a couple of wells already found H<sub>2</sub>, whereas they were drilled to look for hydrocarbons. The sum of areas from where H<sub>2</sub> is seeping overpasses 45 km<sup>2</sup> in Kangaroo Island as in the Yorke Peninsula. The size of the emitting structures, expressed in average diameter, varies from few meters to kilometers and the footprint expressed in % of the ground within the structures varies from 1 to 17%. However, globally the sets of <i>fairy circles</i> in the various basins are rather similar and one may consider that their characteristics are homogeneous and may help to characterize these H<sub>2</sub> emitting zones. Two kinds of size repartitions are observed, one with two maxima (25 m and between 220 m ± 25%) one with a simple Gaussian shape with a single maximum around 175 m ± 20%. Various geomorphological characteristics allow us to differentiate depressions of the ground due to gas emissions from karstic dolines. The more relevant ones are their slope and the ratio diameter vs. depth. At the opposite of the pockmark structures observed on the seafloor for which exclusion zones have been described, the H<sub>2</sub> emitting structures may intersect and they often growth by coalescence. These H<sub>2</sub> emitting structures are always observed, up to now, above Archean or Neoproterozoic cratons; it suggests that anoxia at the time the sedimentation and iron content play a key role in the H<sub>2</sub> sourcing.https://www.mdpi.com/2076-3263/11/3/145natural hydrogenBrazilAustraliaRussiagas escape
spellingShingle Isabelle Moretti
Emyrose Brouilly
Keanu Loiseau
Alain Prinzhofer
Eric Deville
Hydrogen Emanations in Intracratonic Areas: New Guide Lines for Early Exploration Basin Screening
Geosciences
natural hydrogen
Brazil
Australia
Russia
gas escape
title Hydrogen Emanations in Intracratonic Areas: New Guide Lines for Early Exploration Basin Screening
title_full Hydrogen Emanations in Intracratonic Areas: New Guide Lines for Early Exploration Basin Screening
title_fullStr Hydrogen Emanations in Intracratonic Areas: New Guide Lines for Early Exploration Basin Screening
title_full_unstemmed Hydrogen Emanations in Intracratonic Areas: New Guide Lines for Early Exploration Basin Screening
title_short Hydrogen Emanations in Intracratonic Areas: New Guide Lines for Early Exploration Basin Screening
title_sort hydrogen emanations in intracratonic areas new guide lines for early exploration basin screening
topic natural hydrogen
Brazil
Australia
Russia
gas escape
url https://www.mdpi.com/2076-3263/11/3/145
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AT alainprinzhofer hydrogenemanationsinintracratonicareasnewguidelinesforearlyexplorationbasinscreening
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