Kinetics and Equilibrium Study of Black Krom KJR Dye Sorption by Bone-based Activated Carbon

In this work, the sorption capacity of a bone-based activated carbon for the Black Krom KJR dye removal was investigated in a batch system. Preliminary sorption tests were performed in order to assess the effects of initial pH, sorption temperature, stirring speed and the particle size on the sorpti...

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Main Authors: Aparecido Nivaldo Módenes, Fabiano Bisinella Scheufele, Claudio José Glitz Jr, Andréia Colombo, Fernando Rodolfo Espinoza-Quiñones, Alexander Dimitrov Kroumov
Format: Article
Language:English
Published: Bulgarian Academy of Sciences 2014-09-01
Series:International Journal Bioautomation
Subjects:
Online Access:http://www.biomed.bas.bg/bioautomation/2014/vol_18.3/files/18.3_08.pdf
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author Aparecido Nivaldo Módenes
Fabiano Bisinella Scheufele
Claudio José Glitz Jr
Andréia Colombo
Fernando Rodolfo Espinoza-Quiñones
Alexander Dimitrov Kroumov
author_facet Aparecido Nivaldo Módenes
Fabiano Bisinella Scheufele
Claudio José Glitz Jr
Andréia Colombo
Fernando Rodolfo Espinoza-Quiñones
Alexander Dimitrov Kroumov
author_sort Aparecido Nivaldo Módenes
collection DOAJ
description In this work, the sorption capacity of a bone-based activated carbon for the Black Krom KJR dye removal was investigated in a batch system. Preliminary sorption tests were performed in order to assess the effects of initial pH, sorption temperature, stirring speed and the particle size on the sorption process. The most reliable conditions were used to perform the kinetic and equilibrium tests in duplicate. From the kinetic sorption experiments, an equilibrium time of 24 h was achieved with a sorption capacity of 53 mg·g-1. Kinetic dye sorption data was well represented by both the pseudo second order and Elovich models. Among used isotherm models, the Langmuir model exhibited best fit to the equilibrium sorption data, showing a maximum sorption capacity value of 154 ± 8 mg·g-1 and affinity constant value of 0.0114 ± 0.0012 g·L-1, respectively. Based on these results, it is remarkable the great potential exhibited by the bone-based activated carbon adsorbent for its application in industrial wastewater treatment systems.
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spelling doaj.art-cfd8c3cbed514d18ad272ab4fa7f4db82022-12-22T00:59:50ZengBulgarian Academy of SciencesInternational Journal Bioautomation1314-19021314-23212014-09-01183251264Kinetics and Equilibrium Study of Black Krom KJR Dye Sorption by Bone-based Activated CarbonAparecido Nivaldo Módenes0Fabiano Bisinella ScheufeleClaudio José Glitz JrAndréia ColomboFernando Rodolfo Espinoza-QuiñonesAlexander Dimitrov KroumovDepartment of Chemical Engineering, West Parana State University, Campus of Toledo, Rua da Faculdade 645, Jardim Santa Maria, 85903-000, Toledo, PR, BrazilIn this work, the sorption capacity of a bone-based activated carbon for the Black Krom KJR dye removal was investigated in a batch system. Preliminary sorption tests were performed in order to assess the effects of initial pH, sorption temperature, stirring speed and the particle size on the sorption process. The most reliable conditions were used to perform the kinetic and equilibrium tests in duplicate. From the kinetic sorption experiments, an equilibrium time of 24 h was achieved with a sorption capacity of 53 mg·g-1. Kinetic dye sorption data was well represented by both the pseudo second order and Elovich models. Among used isotherm models, the Langmuir model exhibited best fit to the equilibrium sorption data, showing a maximum sorption capacity value of 154 ± 8 mg·g-1 and affinity constant value of 0.0114 ± 0.0012 g·L-1, respectively. Based on these results, it is remarkable the great potential exhibited by the bone-based activated carbon adsorbent for its application in industrial wastewater treatment systems.http://www.biomed.bas.bg/bioautomation/2014/vol_18.3/files/18.3_08.pdfAdsorptionBone-based activated carbonBlack Krom KJR dye uptakeWastewater treatment
spellingShingle Aparecido Nivaldo Módenes
Fabiano Bisinella Scheufele
Claudio José Glitz Jr
Andréia Colombo
Fernando Rodolfo Espinoza-Quiñones
Alexander Dimitrov Kroumov
Kinetics and Equilibrium Study of Black Krom KJR Dye Sorption by Bone-based Activated Carbon
International Journal Bioautomation
Adsorption
Bone-based activated carbon
Black Krom KJR dye uptake
Wastewater treatment
title Kinetics and Equilibrium Study of Black Krom KJR Dye Sorption by Bone-based Activated Carbon
title_full Kinetics and Equilibrium Study of Black Krom KJR Dye Sorption by Bone-based Activated Carbon
title_fullStr Kinetics and Equilibrium Study of Black Krom KJR Dye Sorption by Bone-based Activated Carbon
title_full_unstemmed Kinetics and Equilibrium Study of Black Krom KJR Dye Sorption by Bone-based Activated Carbon
title_short Kinetics and Equilibrium Study of Black Krom KJR Dye Sorption by Bone-based Activated Carbon
title_sort kinetics and equilibrium study of black krom kjr dye sorption by bone based activated carbon
topic Adsorption
Bone-based activated carbon
Black Krom KJR dye uptake
Wastewater treatment
url http://www.biomed.bas.bg/bioautomation/2014/vol_18.3/files/18.3_08.pdf
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