Spectroscopic and structural characterization of hexaamminecobalt(III) dibromide permanganate
Structural and spectroscopic characterization (SXRD, IR, liq. N2 temperature Raman, UV) of hexaamminecobalt(III) dibromide permanganate, [Co(NH3)6]Br2(MnO4) (compound 1), are described. There is a 3D hydrogen bond network including N–H···O–Mn and N–H···Br interactions, which could serve as potential...
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| Format: | Article |
| Language: | English |
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Serbian Chemical Society
2023-01-01
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| Series: | Journal of the Serbian Chemical Society |
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| Online Access: | https://doiserbia.nb.rs/img/doi/0352-5139/2023/0352-51392300062B.pdf |
| _version_ | 1797215521340391424 |
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| author | Barta Holló Berta Bayat Niloofar Bereczki Laura Petruševski Vladimir M. Béres Kende Attila Farkas Attila Szilágyi Imre Miklós Kótai László |
| author_facet | Barta Holló Berta Bayat Niloofar Bereczki Laura Petruševski Vladimir M. Béres Kende Attila Farkas Attila Szilágyi Imre Miklós Kótai László |
| author_sort | Barta Holló Berta |
| collection | DOAJ |
| description | Structural and spectroscopic characterization (SXRD, IR, liq. N2 temperature Raman, UV) of hexaamminecobalt(III) dibromide permanganate, [Co(NH3)6]Br2(MnO4) (compound 1), are described. There is a 3D hydrogen bond network including N–H···O–Mn and N–H···Br interactions, which could serve as potential reaction centres for solid-phase redox reactions between the ammonia ligands and/or bromide ions as reductants and permanganate ions as oxidant agents. The effect of the nature of halogen ions on the structural and spectroscopic properties of [Co(NH3)6]Br2(MnO4) and the analogous chloride compound, [Co(NH3)6]Cl2(MnO4) (compound 2), are discussed in detail. |
| first_indexed | 2024-04-24T11:31:23Z |
| format | Article |
| id | doaj.art-cfe62b7d997d4a3e8ca511beb4d11f86 |
| institution | Directory Open Access Journal |
| issn | 0352-5139 1820-7421 |
| language | English |
| last_indexed | 2024-04-24T11:31:23Z |
| publishDate | 2023-01-01 |
| publisher | Serbian Chemical Society |
| record_format | Article |
| series | Journal of the Serbian Chemical Society |
| spelling | doaj.art-cfe62b7d997d4a3e8ca511beb4d11f862024-04-10T10:17:11ZengSerbian Chemical SocietyJournal of the Serbian Chemical Society0352-51391820-74212023-01-0188121237125210.2298/JSC230702062B0352-51392300062BSpectroscopic and structural characterization of hexaamminecobalt(III) dibromide permanganateBarta Holló Berta0https://orcid.org/0000-0002-5786-442XBayat Niloofar1Bereczki Laura2Petruševski Vladimir M.3Béres Kende Attila4https://orcid.org/0000-0003-4257-0581Farkas Attila5https://orcid.org/0000-0002-8877-2587Szilágyi Imre Miklós6Kótai László7https://orcid.org/0000-0001-6375-3120Department of Chemistry, Biochemistry and Environmental Protection, Faculty of Sciences, University of Novi Sad, Novi Sad, SerbiaInstitute of Materials and Environmental Chemistry, Research Centre for Natural Sciences, Budapest, Hungary + Department of Inorganic and Analytical Chemistry, Budapest University of Technology and Economics, Budapest, HungaryInstitute of Materials and Environmental Chemistry, Research Centre for Natural Sciences, Budapest, Hungary + Centre for Structural Science, Research Centre for Natural Sciences, Budapest, HungaryFaculty of Natural Sciences and Mathematics, Ss. Cyril and Methodius University, Skopje, North MacedoniaInstitute of Materials and Environmental Chemistry, Research Centre for Natural Sciences, Budapest, Hungary + György Hevesy PhD School of Chemistry, Institute of Chemistry, ELTE Eötvös Loránd University, Budapest, HungaryDepartment of Organic Chemistry and Technology, Budapest University of Technology and Economics, Budapest, HungaryInstitute of Materials and Environmental Chemistry, Research Centre for Natural Sciences, Budapest, HungaryInstitute of Materials and Environmental Chemistry, Research Centre for Natural Sciences, Budapest, Hungary + Deuton-X Ltd., Érd, HungaryStructural and spectroscopic characterization (SXRD, IR, liq. N2 temperature Raman, UV) of hexaamminecobalt(III) dibromide permanganate, [Co(NH3)6]Br2(MnO4) (compound 1), are described. There is a 3D hydrogen bond network including N–H···O–Mn and N–H···Br interactions, which could serve as potential reaction centres for solid-phase redox reactions between the ammonia ligands and/or bromide ions as reductants and permanganate ions as oxidant agents. The effect of the nature of halogen ions on the structural and spectroscopic properties of [Co(NH3)6]Br2(MnO4) and the analogous chloride compound, [Co(NH3)6]Cl2(MnO4) (compound 2), are discussed in detail.https://doiserbia.nb.rs/img/doi/0352-5139/2023/0352-51392300062B.pdfpermanganateamminecobalt(iii)ir and raman spectroscopysolid-phase quasi-intramolecular redox reaction. |
| spellingShingle | Barta Holló Berta Bayat Niloofar Bereczki Laura Petruševski Vladimir M. Béres Kende Attila Farkas Attila Szilágyi Imre Miklós Kótai László Spectroscopic and structural characterization of hexaamminecobalt(III) dibromide permanganate Journal of the Serbian Chemical Society permanganate ammine cobalt(iii) ir and raman spectroscopy solid-phase quasi-intramolecular redox reaction. |
| title | Spectroscopic and structural characterization of hexaamminecobalt(III) dibromide permanganate |
| title_full | Spectroscopic and structural characterization of hexaamminecobalt(III) dibromide permanganate |
| title_fullStr | Spectroscopic and structural characterization of hexaamminecobalt(III) dibromide permanganate |
| title_full_unstemmed | Spectroscopic and structural characterization of hexaamminecobalt(III) dibromide permanganate |
| title_short | Spectroscopic and structural characterization of hexaamminecobalt(III) dibromide permanganate |
| title_sort | spectroscopic and structural characterization of hexaamminecobalt iii dibromide permanganate |
| topic | permanganate ammine cobalt(iii) ir and raman spectroscopy solid-phase quasi-intramolecular redox reaction. |
| url | https://doiserbia.nb.rs/img/doi/0352-5139/2023/0352-51392300062B.pdf |
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