Synthesis, Characterization, and Thin-Film Transistor Response of Benzo[i]pentahelicene-3,6-dione
Organic semiconductors hold the promise of simple, large area solution deposition, low thermal budgets as well as compatibility with flexible substrates, thus emerging as viable alternatives for cost-effective (opto)-electronic devices. In this study, we report the optimized synthesis and characteri...
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MDPI AG
2022-01-01
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Series: | Molecules |
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Online Access: | https://www.mdpi.com/1420-3049/27/3/863 |
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author | Maria Paola Bracciale Guhyun Kwon Dongil Ho Choongik Kim Maria Laura Santarelli Assunta Marrocchi |
author_facet | Maria Paola Bracciale Guhyun Kwon Dongil Ho Choongik Kim Maria Laura Santarelli Assunta Marrocchi |
author_sort | Maria Paola Bracciale |
collection | DOAJ |
description | Organic semiconductors hold the promise of simple, large area solution deposition, low thermal budgets as well as compatibility with flexible substrates, thus emerging as viable alternatives for cost-effective (opto)-electronic devices. In this study, we report the optimized synthesis and characterization of a helically shaped polycyclic aromatic compound, namely benzo[i]pentahelicene-3,6-dione, and explored its use in the fabrication of organic field effect transistors. In addition, we investigated its thermal, optical absorption, and electrochemical properties. Finally, the single crystal X-ray characterization is reported. |
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format | Article |
id | doaj.art-d024c6c7c2244ce48186e79379768cdd |
institution | Directory Open Access Journal |
issn | 1420-3049 |
language | English |
last_indexed | 2024-03-09T23:28:40Z |
publishDate | 2022-01-01 |
publisher | MDPI AG |
record_format | Article |
series | Molecules |
spelling | doaj.art-d024c6c7c2244ce48186e79379768cdd2023-11-23T17:13:38ZengMDPI AGMolecules1420-30492022-01-0127386310.3390/molecules27030863Synthesis, Characterization, and Thin-Film Transistor Response of Benzo[i]pentahelicene-3,6-dioneMaria Paola Bracciale0Guhyun Kwon1Dongil Ho2Choongik Kim3Maria Laura Santarelli4Assunta Marrocchi5Department of Chemical Engineering Materials and Environment, University of Rome “Sapienza”, Via Eudossiana 18, 00184 Rome, ItalyDepartment of Chemical and Biomolecular Engineering, Sogang University, Seoul 04107, KoreaDepartment of Chemical and Biomolecular Engineering, Sogang University, Seoul 04107, KoreaDepartment of Chemical and Biomolecular Engineering, Sogang University, Seoul 04107, KoreaDepartment of Chemical Engineering Materials and Environment, University of Rome “Sapienza”, Via Eudossiana 18, 00184 Rome, ItalyDepartment of Chemistry, Biology and Biotechnology, University of Perugia, Via Elce di Sotto 8, 06123 Perugia, ItalyOrganic semiconductors hold the promise of simple, large area solution deposition, low thermal budgets as well as compatibility with flexible substrates, thus emerging as viable alternatives for cost-effective (opto)-electronic devices. In this study, we report the optimized synthesis and characterization of a helically shaped polycyclic aromatic compound, namely benzo[i]pentahelicene-3,6-dione, and explored its use in the fabrication of organic field effect transistors. In addition, we investigated its thermal, optical absorption, and electrochemical properties. Finally, the single crystal X-ray characterization is reported.https://www.mdpi.com/1420-3049/27/3/863helicenesorganic thin film transistorsDiels-Alder reaction |
spellingShingle | Maria Paola Bracciale Guhyun Kwon Dongil Ho Choongik Kim Maria Laura Santarelli Assunta Marrocchi Synthesis, Characterization, and Thin-Film Transistor Response of Benzo[i]pentahelicene-3,6-dione Molecules helicenes organic thin film transistors Diels-Alder reaction |
title | Synthesis, Characterization, and Thin-Film Transistor Response of Benzo[i]pentahelicene-3,6-dione |
title_full | Synthesis, Characterization, and Thin-Film Transistor Response of Benzo[i]pentahelicene-3,6-dione |
title_fullStr | Synthesis, Characterization, and Thin-Film Transistor Response of Benzo[i]pentahelicene-3,6-dione |
title_full_unstemmed | Synthesis, Characterization, and Thin-Film Transistor Response of Benzo[i]pentahelicene-3,6-dione |
title_short | Synthesis, Characterization, and Thin-Film Transistor Response of Benzo[i]pentahelicene-3,6-dione |
title_sort | synthesis characterization and thin film transistor response of benzo i pentahelicene 3 6 dione |
topic | helicenes organic thin film transistors Diels-Alder reaction |
url | https://www.mdpi.com/1420-3049/27/3/863 |
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