Nickel (I) paramagnetic complexes stabilized by norbornadiene
During the reaction between the norbornadiene and bis-η3 -allyl nickel complexes Niall2 (all-C3H5, 1-CH3C3H4, 2-CH3C3H4) ESR method detected the presence of a paramagnetic nickel (I). The concentration is about 10-4—10-6 of the concentration of nickel imposed into the system. Dependence of paramagne...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | Russian |
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MIREA - Russian Technological University
2007-10-01
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| Series: | Тонкие химические технологии |
| Online Access: | https://www.finechem-mirea.ru/jour/article/view/1337 |
| _version_ | 1797882290968199168 |
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| author | Y. Y. Othman P. V. Melnikov E. A. Polenov V. R. Flid |
| author_facet | Y. Y. Othman P. V. Melnikov E. A. Polenov V. R. Flid |
| author_sort | Y. Y. Othman |
| collection | DOAJ |
| description | During the reaction between the norbornadiene and bis-η3 -allyl nickel complexes Niall2 (all-C3H5, 1-CH3C3H4, 2-CH3C3H4) ESR method detected the presence of a paramagnetic nickel (I). The concentration is about 10-4—10-6 of the concentration of nickel imposed into the system. Dependence of paramagnetic particles concentration vs. temperature was detected. Based on the findings the structures of the complexes of nickel (I) are discussed, as well as possible ways of their formation. |
| first_indexed | 2024-04-10T03:32:22Z |
| format | Article |
| id | doaj.art-d02ef22b460d4435ad7bf463080184e6 |
| institution | Directory Open Access Journal |
| issn | 2410-6593 2686-7575 |
| language | Russian |
| last_indexed | 2024-04-10T03:32:22Z |
| publishDate | 2007-10-01 |
| publisher | MIREA - Russian Technological University |
| record_format | Article |
| series | Тонкие химические технологии |
| spelling | doaj.art-d02ef22b460d4435ad7bf463080184e62023-03-13T07:25:28ZrusMIREA - Russian Technological UniversityТонкие химические технологии2410-65932686-75752007-10-012517201332Nickel (I) paramagnetic complexes stabilized by norbornadieneY. Y. Othman0P. V. Melnikov1E. A. Polenov2V. R. Flid3M.V. Lomonosov Moscow State University of Fine Chemical Technologies, 86, Vernadskogo pr., Moscow 119571M.V. Lomonosov Moscow State University of Fine Chemical Technologies, 86, Vernadskogo pr., Moscow 119571M.V. Lomonosov Moscow State University of Fine Chemical Technologies, 86, Vernadskogo pr., Moscow 119571M.V. Lomonosov Moscow State University of Fine Chemical Technologies, 86, Vernadskogo pr., Moscow 119571During the reaction between the norbornadiene and bis-η3 -allyl nickel complexes Niall2 (all-C3H5, 1-CH3C3H4, 2-CH3C3H4) ESR method detected the presence of a paramagnetic nickel (I). The concentration is about 10-4—10-6 of the concentration of nickel imposed into the system. Dependence of paramagnetic particles concentration vs. temperature was detected. Based on the findings the structures of the complexes of nickel (I) are discussed, as well as possible ways of their formation.https://www.finechem-mirea.ru/jour/article/view/1337 |
| spellingShingle | Y. Y. Othman P. V. Melnikov E. A. Polenov V. R. Flid Nickel (I) paramagnetic complexes stabilized by norbornadiene Тонкие химические технологии |
| title | Nickel (I) paramagnetic complexes stabilized by norbornadiene |
| title_full | Nickel (I) paramagnetic complexes stabilized by norbornadiene |
| title_fullStr | Nickel (I) paramagnetic complexes stabilized by norbornadiene |
| title_full_unstemmed | Nickel (I) paramagnetic complexes stabilized by norbornadiene |
| title_short | Nickel (I) paramagnetic complexes stabilized by norbornadiene |
| title_sort | nickel i paramagnetic complexes stabilized by norbornadiene |
| url | https://www.finechem-mirea.ru/jour/article/view/1337 |
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