The Two-Stage Air–CO Activation in the Preparation of Activated Carbons. I. Characterization by Gas Adsorption

Three different methods for the preparation of activated carbons from almond shells and olive stones have been carried out in the temperature range 1073–1123 K: (a) carbonization in N 2 followed by activation in CO 2 ; (b) direct activation in CO 2 and (c) treatment of the raw material in air at 573...

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Main Authors: F. Rodríguez-Reinoso, A. Linares-Solano, M. Molina-Sabio, J. de D. López-González
Format: Article
Language:English
Published: SAGE Publications 1984-09-01
Series:Adsorption Science & Technology
Online Access:https://doi.org/10.1177/026361748400100304
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author F. Rodríguez-Reinoso
A. Linares-Solano
M. Molina-Sabio
J. de D. López-González
author_facet F. Rodríguez-Reinoso
A. Linares-Solano
M. Molina-Sabio
J. de D. López-González
author_sort F. Rodríguez-Reinoso
collection DOAJ
description Three different methods for the preparation of activated carbons from almond shells and olive stones have been carried out in the temperature range 1073–1123 K: (a) carbonization in N 2 followed by activation in CO 2 ; (b) direct activation in CO 2 and (c) treatment of the raw material in air at 573 K followed by activation in CO 2 . The characterization of the samples by gas adsorption and mercury porosimetry has shown that methods (a) and (b) yield similar results (and consequently it is preferable to use the direct activation) and that method (c) gives the best results, both in an adsorptive capacity and in the overall yield. On the other hand, the carbons from almond shells are more micro- and mesoporous whereas those from olive stones are more macroporous; in any case, the adsorptive capacity for gas adsorption of activated carbons prepared from both raw materials is very large.
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spelling doaj.art-d040d2b9a0f84eeba15edbb24c99140a2024-03-02T17:50:11ZengSAGE PublicationsAdsorption Science & Technology0263-61742048-40381984-09-01110.1177/026361748400100304The Two-Stage Air–CO Activation in the Preparation of Activated Carbons. I. Characterization by Gas AdsorptionF. Rodríguez-ReinosoA. Linares-SolanoM. Molina-SabioJ. de D. López-González0 Departamento de Química Inorgánica, Universidad Nacional de Educación a Distancia, Madrid, SpainThree different methods for the preparation of activated carbons from almond shells and olive stones have been carried out in the temperature range 1073–1123 K: (a) carbonization in N 2 followed by activation in CO 2 ; (b) direct activation in CO 2 and (c) treatment of the raw material in air at 573 K followed by activation in CO 2 . The characterization of the samples by gas adsorption and mercury porosimetry has shown that methods (a) and (b) yield similar results (and consequently it is preferable to use the direct activation) and that method (c) gives the best results, both in an adsorptive capacity and in the overall yield. On the other hand, the carbons from almond shells are more micro- and mesoporous whereas those from olive stones are more macroporous; in any case, the adsorptive capacity for gas adsorption of activated carbons prepared from both raw materials is very large.https://doi.org/10.1177/026361748400100304
spellingShingle F. Rodríguez-Reinoso
A. Linares-Solano
M. Molina-Sabio
J. de D. López-González
The Two-Stage Air–CO Activation in the Preparation of Activated Carbons. I. Characterization by Gas Adsorption
Adsorption Science & Technology
title The Two-Stage Air–CO Activation in the Preparation of Activated Carbons. I. Characterization by Gas Adsorption
title_full The Two-Stage Air–CO Activation in the Preparation of Activated Carbons. I. Characterization by Gas Adsorption
title_fullStr The Two-Stage Air–CO Activation in the Preparation of Activated Carbons. I. Characterization by Gas Adsorption
title_full_unstemmed The Two-Stage Air–CO Activation in the Preparation of Activated Carbons. I. Characterization by Gas Adsorption
title_short The Two-Stage Air–CO Activation in the Preparation of Activated Carbons. I. Characterization by Gas Adsorption
title_sort two stage air co activation in the preparation of activated carbons i characterization by gas adsorption
url https://doi.org/10.1177/026361748400100304
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