Chemical Activation of Apricot Pit-Derived Carbon Sorbents for the Effective Removal of Dyes in Environmental Remediation
The aim of this work is to study the properties of carbon materials prepared from apricot stones by carbonization at 300–900 °C and chemical activation by KOH with different ratios between components. It was found that increasing the carbonization temperature to 800–900 °C leads to the degradation o...
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MDPI AG
2023-09-01
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Online Access: | https://www.mdpi.com/2311-5629/9/4/93 |
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author | Vitalii Vashchynskyi Olena Okhay Tetiana Boychuk |
author_facet | Vitalii Vashchynskyi Olena Okhay Tetiana Boychuk |
author_sort | Vitalii Vashchynskyi |
collection | DOAJ |
description | The aim of this work is to study the properties of carbon materials prepared from apricot stones by carbonization at 300–900 °C and chemical activation by KOH with different ratios between components. It was found that increasing the carbonization temperature to 800–900 °C leads to the degradation of narrow micropores and the carbon matrix. The adsorbent materials were characterized with FTIR and SEM, and a specific surface area was calculated. Moreover, additional activation by HNO<sub>3</sub> and annealing at 450 °C led to an increase in surface area up to 1300 m<sup>2</sup>/g. The obtained N-enriched sorbents show adsorption activities of 190–235 mg/g for methylene blue and 210–260 mg/g for methyl orange. The results of this study can be useful for future scale-up using the apricot material as a low-cost adsorbent for the removal of dyes in environmental remediation production. |
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issn | 2311-5629 |
language | English |
last_indexed | 2024-03-08T20:55:06Z |
publishDate | 2023-09-01 |
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spelling | doaj.art-d05eb3215c28460eb38565c1ca6bce6c2023-12-22T13:59:14ZengMDPI AGC2311-56292023-09-01949310.3390/c9040093Chemical Activation of Apricot Pit-Derived Carbon Sorbents for the Effective Removal of Dyes in Environmental RemediationVitalii Vashchynskyi0Olena Okhay1Tetiana Boychuk2The Department of General Physics, Lviv Polytechnic National University, 12 S. Bandery Str., 79013 Lviv, UkraineCentre for Mechanical Technology and Automation (TEMA), University of Aveiro, 3810-193 Aveiro, PortugalInstitut de Ciència dels Materials (ICMUV), Universitat de València, Catedrático José Beltrán 2, 46980 Paterna, SpainThe aim of this work is to study the properties of carbon materials prepared from apricot stones by carbonization at 300–900 °C and chemical activation by KOH with different ratios between components. It was found that increasing the carbonization temperature to 800–900 °C leads to the degradation of narrow micropores and the carbon matrix. The adsorbent materials were characterized with FTIR and SEM, and a specific surface area was calculated. Moreover, additional activation by HNO<sub>3</sub> and annealing at 450 °C led to an increase in surface area up to 1300 m<sup>2</sup>/g. The obtained N-enriched sorbents show adsorption activities of 190–235 mg/g for methylene blue and 210–260 mg/g for methyl orange. The results of this study can be useful for future scale-up using the apricot material as a low-cost adsorbent for the removal of dyes in environmental remediation production.https://www.mdpi.com/2311-5629/9/4/93activated carbonsorbentchemical activationcarbonizationsorptionN-doping |
spellingShingle | Vitalii Vashchynskyi Olena Okhay Tetiana Boychuk Chemical Activation of Apricot Pit-Derived Carbon Sorbents for the Effective Removal of Dyes in Environmental Remediation C activated carbon sorbent chemical activation carbonization sorption N-doping |
title | Chemical Activation of Apricot Pit-Derived Carbon Sorbents for the Effective Removal of Dyes in Environmental Remediation |
title_full | Chemical Activation of Apricot Pit-Derived Carbon Sorbents for the Effective Removal of Dyes in Environmental Remediation |
title_fullStr | Chemical Activation of Apricot Pit-Derived Carbon Sorbents for the Effective Removal of Dyes in Environmental Remediation |
title_full_unstemmed | Chemical Activation of Apricot Pit-Derived Carbon Sorbents for the Effective Removal of Dyes in Environmental Remediation |
title_short | Chemical Activation of Apricot Pit-Derived Carbon Sorbents for the Effective Removal of Dyes in Environmental Remediation |
title_sort | chemical activation of apricot pit derived carbon sorbents for the effective removal of dyes in environmental remediation |
topic | activated carbon sorbent chemical activation carbonization sorption N-doping |
url | https://www.mdpi.com/2311-5629/9/4/93 |
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