Chemical Activation of Apricot Pit-Derived Carbon Sorbents for the Effective Removal of Dyes in Environmental Remediation

The aim of this work is to study the properties of carbon materials prepared from apricot stones by carbonization at 300–900 °C and chemical activation by KOH with different ratios between components. It was found that increasing the carbonization temperature to 800–900 °C leads to the degradation o...

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Main Authors: Vitalii Vashchynskyi, Olena Okhay, Tetiana Boychuk
Format: Article
Language:English
Published: MDPI AG 2023-09-01
Series:C
Subjects:
Online Access:https://www.mdpi.com/2311-5629/9/4/93
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author Vitalii Vashchynskyi
Olena Okhay
Tetiana Boychuk
author_facet Vitalii Vashchynskyi
Olena Okhay
Tetiana Boychuk
author_sort Vitalii Vashchynskyi
collection DOAJ
description The aim of this work is to study the properties of carbon materials prepared from apricot stones by carbonization at 300–900 °C and chemical activation by KOH with different ratios between components. It was found that increasing the carbonization temperature to 800–900 °C leads to the degradation of narrow micropores and the carbon matrix. The adsorbent materials were characterized with FTIR and SEM, and a specific surface area was calculated. Moreover, additional activation by HNO<sub>3</sub> and annealing at 450 °C led to an increase in surface area up to 1300 m<sup>2</sup>/g. The obtained N-enriched sorbents show adsorption activities of 190–235 mg/g for methylene blue and 210–260 mg/g for methyl orange. The results of this study can be useful for future scale-up using the apricot material as a low-cost adsorbent for the removal of dyes in environmental remediation production.
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spelling doaj.art-d05eb3215c28460eb38565c1ca6bce6c2023-12-22T13:59:14ZengMDPI AGC2311-56292023-09-01949310.3390/c9040093Chemical Activation of Apricot Pit-Derived Carbon Sorbents for the Effective Removal of Dyes in Environmental RemediationVitalii Vashchynskyi0Olena Okhay1Tetiana Boychuk2The Department of General Physics, Lviv Polytechnic National University, 12 S. Bandery Str., 79013 Lviv, UkraineCentre for Mechanical Technology and Automation (TEMA), University of Aveiro, 3810-193 Aveiro, PortugalInstitut de Ciència dels Materials (ICMUV), Universitat de València, Catedrático José Beltrán 2, 46980 Paterna, SpainThe aim of this work is to study the properties of carbon materials prepared from apricot stones by carbonization at 300–900 °C and chemical activation by KOH with different ratios between components. It was found that increasing the carbonization temperature to 800–900 °C leads to the degradation of narrow micropores and the carbon matrix. The adsorbent materials were characterized with FTIR and SEM, and a specific surface area was calculated. Moreover, additional activation by HNO<sub>3</sub> and annealing at 450 °C led to an increase in surface area up to 1300 m<sup>2</sup>/g. The obtained N-enriched sorbents show adsorption activities of 190–235 mg/g for methylene blue and 210–260 mg/g for methyl orange. The results of this study can be useful for future scale-up using the apricot material as a low-cost adsorbent for the removal of dyes in environmental remediation production.https://www.mdpi.com/2311-5629/9/4/93activated carbonsorbentchemical activationcarbonizationsorptionN-doping
spellingShingle Vitalii Vashchynskyi
Olena Okhay
Tetiana Boychuk
Chemical Activation of Apricot Pit-Derived Carbon Sorbents for the Effective Removal of Dyes in Environmental Remediation
C
activated carbon
sorbent
chemical activation
carbonization
sorption
N-doping
title Chemical Activation of Apricot Pit-Derived Carbon Sorbents for the Effective Removal of Dyes in Environmental Remediation
title_full Chemical Activation of Apricot Pit-Derived Carbon Sorbents for the Effective Removal of Dyes in Environmental Remediation
title_fullStr Chemical Activation of Apricot Pit-Derived Carbon Sorbents for the Effective Removal of Dyes in Environmental Remediation
title_full_unstemmed Chemical Activation of Apricot Pit-Derived Carbon Sorbents for the Effective Removal of Dyes in Environmental Remediation
title_short Chemical Activation of Apricot Pit-Derived Carbon Sorbents for the Effective Removal of Dyes in Environmental Remediation
title_sort chemical activation of apricot pit derived carbon sorbents for the effective removal of dyes in environmental remediation
topic activated carbon
sorbent
chemical activation
carbonization
sorption
N-doping
url https://www.mdpi.com/2311-5629/9/4/93
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AT olenaokhay chemicalactivationofapricotpitderivedcarbonsorbentsfortheeffectiveremovalofdyesinenvironmentalremediation
AT tetianaboychuk chemicalactivationofapricotpitderivedcarbonsorbentsfortheeffectiveremovalofdyesinenvironmentalremediation