Bifunctional Single-Atom Cobalt Electrocatalysts with Dense Active Sites Prepared via a Silica Xerogel Strategy for Rechargeable Zinc–Air Batteries
The N-doped cobalt-based (Co) bifunctional single atom catalyst (SAC) has emerged as one of the most promising candidates to substitute noble metal-based catalysts for highly efficient bifunctionality. Herein, a facile silica xerogel strategy is elaborately designed to synthesize uniformly dispersed...
| Main Authors: | , , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
MDPI AG
2022-01-01
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| Series: | Nanomaterials |
| Subjects: | |
| Online Access: | https://www.mdpi.com/2079-4991/12/3/381 |
| Summary: | The N-doped cobalt-based (Co) bifunctional single atom catalyst (SAC) has emerged as one of the most promising candidates to substitute noble metal-based catalysts for highly efficient bifunctionality. Herein, a facile silica xerogel strategy is elaborately designed to synthesize uniformly dispersed and dense Co-N<sub>x</sub> active sites on N-doped highly porous carbon networks (Co-N-C SAC) using economic biomass materials. This strategy promotes the generation of massive mesopores and micropores for substantially improving the formation of Co-N<sub>x</sub> moieties and unique network architecture. The Co-N-C SAC electrocatalysts exhibit an excellent bifunctional activity with a potential gap (ΔE) of 0.81 V in alkaline medias, outperforming those of the most highly active bifunctional electrocatalysts. On top of that, Co-N-C SAC also possesses outstanding performance in ZABs with superior power density/specific capacity. This proposed synthetic method will provide a new inspiration for fabricating various high-content SACs for varied applications. |
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| ISSN: | 2079-4991 |