(E)-3-Isopropyl-1-methyl-2,6-diphenylpiperidin-4-one O-nicotinoyl oxime
In the title compound, C27H29N3O2, the piperidine ring exists in a chair conformation with an equatorial orientation of the phenyl and methyl substituents. The C—C=N bond angles are significantly different [119.1 (2) and 127.2 (2)°]. The phenyl rings are inclined to one another by 44.90 (14)°, and b...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2014-05-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536814007363 |
| _version_ | 1818321591994417152 |
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| author | T. Vinuchakkaravarthy R. Sivakumar T. Srinivasan V. Thanikachalam D. Velmurugan |
| author_facet | T. Vinuchakkaravarthy R. Sivakumar T. Srinivasan V. Thanikachalam D. Velmurugan |
| author_sort | T. Vinuchakkaravarthy |
| collection | DOAJ |
| description | In the title compound, C27H29N3O2, the piperidine ring exists in a chair conformation with an equatorial orientation of the phenyl and methyl substituents. The C—C=N bond angles are significantly different [119.1 (2) and 127.2 (2)°]. The phenyl rings are inclined to one another by 44.90 (14)°, and by 80.85 (13) and 79.62 (12)° to the mean plane of the piperidine ring. The terminal pyridine ring is inclined to the piperidine ring mean plane by 74.79 (15)°. In the crystal, molecules are linked by C—H...π interactions, forming a three-dimensional network. |
| first_indexed | 2024-12-13T10:43:21Z |
| format | Article |
| id | doaj.art-d07387044dc84ca29b2f3fefe4cce9c8 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-13T10:43:21Z |
| publishDate | 2014-05-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-d07387044dc84ca29b2f3fefe4cce9c82022-12-21T23:50:23ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682014-05-01705o551o55110.1107/S1600536814007363su2680(E)-3-Isopropyl-1-methyl-2,6-diphenylpiperidin-4-one O-nicotinoyl oximeT. Vinuchakkaravarthy0R. Sivakumar1T. Srinivasan2V. Thanikachalam3D. Velmurugan4Centre of Advanced Study in Crystallography and Biophysics, University of Madras, Maraimalai Campus (Guindy Campus), Chennai 600 025, IndiaDepartment of Chemistry, Annamalai University, Annamalai Nagar, Chidambaram 608 002, IndiaCentre of Advanced Study in Crystallography and Biophysics, University of Madras, Maraimalai Campus (Guindy Campus), Chennai 600 025, IndiaDepartment of Chemistry, Annamalai University, Annamalai Nagar, Chidambaram 608 002, IndiaCentre of Advanced Study in Crystallography and Biophysics, University of Madras, Maraimalai Campus (Guindy Campus), Chennai 600 025, IndiaIn the title compound, C27H29N3O2, the piperidine ring exists in a chair conformation with an equatorial orientation of the phenyl and methyl substituents. The C—C=N bond angles are significantly different [119.1 (2) and 127.2 (2)°]. The phenyl rings are inclined to one another by 44.90 (14)°, and by 80.85 (13) and 79.62 (12)° to the mean plane of the piperidine ring. The terminal pyridine ring is inclined to the piperidine ring mean plane by 74.79 (15)°. In the crystal, molecules are linked by C—H...π interactions, forming a three-dimensional network.http://scripts.iucr.org/cgi-bin/paper?S1600536814007363 |
| spellingShingle | T. Vinuchakkaravarthy R. Sivakumar T. Srinivasan V. Thanikachalam D. Velmurugan (E)-3-Isopropyl-1-methyl-2,6-diphenylpiperidin-4-one O-nicotinoyl oxime Acta Crystallographica Section E |
| title | (E)-3-Isopropyl-1-methyl-2,6-diphenylpiperidin-4-one O-nicotinoyl oxime |
| title_full | (E)-3-Isopropyl-1-methyl-2,6-diphenylpiperidin-4-one O-nicotinoyl oxime |
| title_fullStr | (E)-3-Isopropyl-1-methyl-2,6-diphenylpiperidin-4-one O-nicotinoyl oxime |
| title_full_unstemmed | (E)-3-Isopropyl-1-methyl-2,6-diphenylpiperidin-4-one O-nicotinoyl oxime |
| title_short | (E)-3-Isopropyl-1-methyl-2,6-diphenylpiperidin-4-one O-nicotinoyl oxime |
| title_sort | e 3 isopropyl 1 methyl 2 6 diphenylpiperidin 4 one o nicotinoyl oxime |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536814007363 |
| work_keys_str_mv | AT tvinuchakkaravarthy e3isopropyl1methyl26diphenylpiperidin4oneonicotinoyloxime AT rsivakumar e3isopropyl1methyl26diphenylpiperidin4oneonicotinoyloxime AT tsrinivasan e3isopropyl1methyl26diphenylpiperidin4oneonicotinoyloxime AT vthanikachalam e3isopropyl1methyl26diphenylpiperidin4oneonicotinoyloxime AT dvelmurugan e3isopropyl1methyl26diphenylpiperidin4oneonicotinoyloxime |