Crystal structure of (perchlorato-κO)(1,4,7,10-tetraazacyclododecane-κ4N)copper(II) perchlorate
The crystal structure of the title salt, [Cu(ClO4)(C8H20N4)]ClO4, is reported. The CuII ion exhibits a square-pyramidal geometry and is coordinated by the four N atoms of the neutral 1,4,7,10-tetraazacyclododecane (cyclen) ligand and an O atom from one perchlorate anion, with the second perchlorate...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2017-01-01
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| Series: | Acta Crystallographica Section E: Crystallographic Communications |
| Subjects: | |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2056989016019563 |
| _version_ | 1818959769831997440 |
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| author | Jessica L. Gray Deidra L. Gerlach Elizabeth T. Papish |
| author_facet | Jessica L. Gray Deidra L. Gerlach Elizabeth T. Papish |
| author_sort | Jessica L. Gray |
| collection | DOAJ |
| description | The crystal structure of the title salt, [Cu(ClO4)(C8H20N4)]ClO4, is reported. The CuII ion exhibits a square-pyramidal geometry and is coordinated by the four N atoms of the neutral 1,4,7,10-tetraazacyclododecane (cyclen) ligand and an O atom from one perchlorate anion, with the second perchlorate ion hydrogen-bonded to one of the amine N atoms of the cyclen ligand. Additional N—H...O hydrogen bonds between the amine H atoms and the coordinating and non-coordinating perchlorate groups create a three-dimensional network structure. Crystals were grown from a concentrated methanol solution at ambient temperature, resulting in no co-crystallization of solvent. |
| first_indexed | 2024-12-20T11:46:55Z |
| format | Article |
| id | doaj.art-d082e5f4f2a441cfa2727801262547a8 |
| institution | Directory Open Access Journal |
| issn | 2056-9890 |
| language | English |
| last_indexed | 2024-12-20T11:46:55Z |
| publishDate | 2017-01-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E: Crystallographic Communications |
| spelling | doaj.art-d082e5f4f2a441cfa2727801262547a82022-12-21T19:41:51ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902017-01-01731313410.1107/S2056989016019563zl2687Crystal structure of (perchlorato-κO)(1,4,7,10-tetraazacyclododecane-κ4N)copper(II) perchlorateJessica L. Gray0Deidra L. Gerlach1Elizabeth T. Papish2Department of Chemistry, University of Alabama, 250 Hackberry Lane, Tuscaloosa, AL 35487-0336, USADepartment of Chemistry, University of Alabama, 250 Hackberry Lane, Tuscaloosa, AL 35487-0336, USADepartment of Chemistry, University of Alabama, 250 Hackberry Lane, Tuscaloosa, AL 35487-0336, USAThe crystal structure of the title salt, [Cu(ClO4)(C8H20N4)]ClO4, is reported. The CuII ion exhibits a square-pyramidal geometry and is coordinated by the four N atoms of the neutral 1,4,7,10-tetraazacyclododecane (cyclen) ligand and an O atom from one perchlorate anion, with the second perchlorate ion hydrogen-bonded to one of the amine N atoms of the cyclen ligand. Additional N—H...O hydrogen bonds between the amine H atoms and the coordinating and non-coordinating perchlorate groups create a three-dimensional network structure. Crystals were grown from a concentrated methanol solution at ambient temperature, resulting in no co-crystallization of solvent.http://scripts.iucr.org/cgi-bin/paper?S2056989016019563crystal structurecopper(II)cyclenperchlorate |
| spellingShingle | Jessica L. Gray Deidra L. Gerlach Elizabeth T. Papish Crystal structure of (perchlorato-κO)(1,4,7,10-tetraazacyclododecane-κ4N)copper(II) perchlorate Acta Crystallographica Section E: Crystallographic Communications crystal structure copper(II) cyclen perchlorate |
| title | Crystal structure of (perchlorato-κO)(1,4,7,10-tetraazacyclododecane-κ4N)copper(II) perchlorate |
| title_full | Crystal structure of (perchlorato-κO)(1,4,7,10-tetraazacyclododecane-κ4N)copper(II) perchlorate |
| title_fullStr | Crystal structure of (perchlorato-κO)(1,4,7,10-tetraazacyclododecane-κ4N)copper(II) perchlorate |
| title_full_unstemmed | Crystal structure of (perchlorato-κO)(1,4,7,10-tetraazacyclododecane-κ4N)copper(II) perchlorate |
| title_short | Crystal structure of (perchlorato-κO)(1,4,7,10-tetraazacyclododecane-κ4N)copper(II) perchlorate |
| title_sort | crystal structure of perchlorato κo 1 4 7 10 tetraazacyclododecane κ4n copper ii perchlorate |
| topic | crystal structure copper(II) cyclen perchlorate |
| url | http://scripts.iucr.org/cgi-bin/paper?S2056989016019563 |
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