Do Red Seaweed Nanoparticles Enhance Bioremediation Capacity of Toxic Dyes from Aqueous Solution?

Based on their functional groups, the use of various seaweed forms in phytoremediation has recently gained significant eco-friendly importance. The objective of this study was to determine whether a novel, sustainable, and ecologically acceptable adsorbent could be employed to remove toxic textile d...

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Bibliographic Details
Main Authors: Abdallah Tageldein Mansour, Ahmed E. Alprol, Mohamed Ashour, Khaled M. A. Ramadan, Adnan H. M. Alhajji, Khamael M. Abualnaja
Format: Article
Language:English
Published: MDPI AG 2022-05-01
Series:Gels
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Online Access:https://www.mdpi.com/2310-2861/8/5/310
Description
Summary:Based on their functional groups, the use of various seaweed forms in phytoremediation has recently gained significant eco-friendly importance. The objective of this study was to determine whether a novel, sustainable, and ecologically acceptable adsorbent could be employed to remove toxic textile dye (Ismate Violet 2R (IV2R)) from an aqueous solution. The low-cost adsorbent was prepared from the nanoparticles form of the native red seaweed species, <i>Pterocladia capillacea</i>. Before and after the adsorption procedure, comprehensive characterization experiments on the bio-adsorbent were carried out, including BET, SEM, FTIR, UV, and dynamic light scattering (DLS) examination. The adsorption performance of the prepared nano-<i>Pterocladia capillacea</i> was optimized by adjusting operating parameters such as the initial dye concentration of 60 mg L<sup>−1</sup>, pH of 2, and contact time of 15 min, all of which were obtained by batch experiments in the lab. At the optimum conditions, the prepared adsorbent had maximum removal effectiveness of 87.2%. Most typical kinetics and isotherm models were used to test the experimental results. The equilibrium data fit well with the Langmuir isotherm model, with comparatively higher R<sup>2</sup> values and fewer standard errors, while the pseudo-second-order kinetic model fits better with a decent correlation coefficient. Thermodynamic parameters revealed that the sorption process on nano-alga was exothermic and spontaneous.
ISSN:2310-2861