Molecularly imprinted polymer synthesis and selective solid phase extraction applications for the detection of ziram, a dithiocarbamate fungicide
It is becoming more and more critical to identify and eliminate pesticide residues that are intended to be used in combating agriculture but pose a threat to all living things due to their unconscious use. In this study, a high-performance molecular imprinted material (MIP) was synthesized to remove...
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| Format: | Article |
| Language: | English |
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Elsevier
2021-08-01
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| Series: | Chemical Engineering Journal Advances |
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| Online Access: | http://www.sciencedirect.com/science/article/pii/S266682112100034X |
| _version_ | 1818354565094834176 |
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| author | Çiğdem Öter Özlem Selçuk Zorer |
| author_facet | Çiğdem Öter Özlem Selçuk Zorer |
| author_sort | Çiğdem Öter |
| collection | DOAJ |
| description | It is becoming more and more critical to identify and eliminate pesticide residues that are intended to be used in combating agriculture but pose a threat to all living things due to their unconscious use. In this study, a high-performance molecular imprinted material (MIP) was synthesized to remove ziram, a dithiocarbamate fungicide, from its liquid phase. After characterization studies of the printed polymer synthesized by the suspension polymerization process, the re-bonding ability and the suitability of the adsorption process to kinetic and isothermal models were compared with an non-imprinted reference polymer (NIP). Selectivity of MIP adsorbent prepared by imprinting method against template molecule ziram; their adsorption ability against different dithiocarbamate fungicides (maneb, ferbam, and propineb) was determined by testing. Some extraction parameters were optimized to evaluate the extraction performance of MIPs used as adsorbents in the solid-phase extraction column. It has been found that under optimized conditions, the developed MIP-SPE method provides high recovery for ziram. This method was developed; it was determined that MIP-SPE showed higher extraction efficiency against ziram than commercial C18-SPE and non-print polymer solid-phase extraction (NIP-SPE) processes. Thus, the MIP-SPE method has proven to be an environmentally friendly, sensitive, easy-to-work, time-saving, efficient sample pretreatment method that uses less solvent. These findings will provide a fundamentally technical for the removal of the trace hazardous pollutants. |
| first_indexed | 2024-12-13T19:27:26Z |
| format | Article |
| id | doaj.art-d096dd253f6e4d1f871847136acbfa49 |
| institution | Directory Open Access Journal |
| issn | 2666-8211 |
| language | English |
| last_indexed | 2024-12-13T19:27:26Z |
| publishDate | 2021-08-01 |
| publisher | Elsevier |
| record_format | Article |
| series | Chemical Engineering Journal Advances |
| spelling | doaj.art-d096dd253f6e4d1f871847136acbfa492022-12-21T23:34:00ZengElsevierChemical Engineering Journal Advances2666-82112021-08-017100118Molecularly imprinted polymer synthesis and selective solid phase extraction applications for the detection of ziram, a dithiocarbamate fungicideÇiğdem Öter0Özlem Selçuk Zorer1Corresponding author.; Faculty of Science, Department of Chemistry, Van Yuzuncu Yil University, 65080 Van, TurkeyFaculty of Science, Department of Chemistry, Van Yuzuncu Yil University, 65080 Van, TurkeyIt is becoming more and more critical to identify and eliminate pesticide residues that are intended to be used in combating agriculture but pose a threat to all living things due to their unconscious use. In this study, a high-performance molecular imprinted material (MIP) was synthesized to remove ziram, a dithiocarbamate fungicide, from its liquid phase. After characterization studies of the printed polymer synthesized by the suspension polymerization process, the re-bonding ability and the suitability of the adsorption process to kinetic and isothermal models were compared with an non-imprinted reference polymer (NIP). Selectivity of MIP adsorbent prepared by imprinting method against template molecule ziram; their adsorption ability against different dithiocarbamate fungicides (maneb, ferbam, and propineb) was determined by testing. Some extraction parameters were optimized to evaluate the extraction performance of MIPs used as adsorbents in the solid-phase extraction column. It has been found that under optimized conditions, the developed MIP-SPE method provides high recovery for ziram. This method was developed; it was determined that MIP-SPE showed higher extraction efficiency against ziram than commercial C18-SPE and non-print polymer solid-phase extraction (NIP-SPE) processes. Thus, the MIP-SPE method has proven to be an environmentally friendly, sensitive, easy-to-work, time-saving, efficient sample pretreatment method that uses less solvent. These findings will provide a fundamentally technical for the removal of the trace hazardous pollutants.http://www.sciencedirect.com/science/article/pii/S266682112100034XMolecularly imprinted polymersPollutantsSolid-phase extractionSuspension polymerizationZiram |
| spellingShingle | Çiğdem Öter Özlem Selçuk Zorer Molecularly imprinted polymer synthesis and selective solid phase extraction applications for the detection of ziram, a dithiocarbamate fungicide Chemical Engineering Journal Advances Molecularly imprinted polymers Pollutants Solid-phase extraction Suspension polymerization Ziram |
| title | Molecularly imprinted polymer synthesis and selective solid phase extraction applications for the detection of ziram, a dithiocarbamate fungicide |
| title_full | Molecularly imprinted polymer synthesis and selective solid phase extraction applications for the detection of ziram, a dithiocarbamate fungicide |
| title_fullStr | Molecularly imprinted polymer synthesis and selective solid phase extraction applications for the detection of ziram, a dithiocarbamate fungicide |
| title_full_unstemmed | Molecularly imprinted polymer synthesis and selective solid phase extraction applications for the detection of ziram, a dithiocarbamate fungicide |
| title_short | Molecularly imprinted polymer synthesis and selective solid phase extraction applications for the detection of ziram, a dithiocarbamate fungicide |
| title_sort | molecularly imprinted polymer synthesis and selective solid phase extraction applications for the detection of ziram a dithiocarbamate fungicide |
| topic | Molecularly imprinted polymers Pollutants Solid-phase extraction Suspension polymerization Ziram |
| url | http://www.sciencedirect.com/science/article/pii/S266682112100034X |
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