Improvement of microstructure and acquirement of excellent mechanical properties of high-Nb Ti2AlC/TiAl alloy by Ta under ultrasonic action in solid-liquid zone

To promote element diffusion in the solid-liquid two-phase region, optimize solidification microstructure, and improve the matching degree of strength and toughness, Ti–46Al–8Nb-2.6C-xTa (at. %) alloys were prepared by arc melting under the action of ultrasound. The lamellar colony, precipitate phas...

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Main Authors: Lingyan Zhou, Hongze Fang, Xiaokang Yang, Ruirun Chen, Xianfei Ding, Yingmei Tan, Jingjie Guo
Format: Article
Language:English
Published: Elsevier 2023-09-01
Series:Journal of Materials Research and Technology
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2238785423018252
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author Lingyan Zhou
Hongze Fang
Xiaokang Yang
Ruirun Chen
Xianfei Ding
Yingmei Tan
Jingjie Guo
author_facet Lingyan Zhou
Hongze Fang
Xiaokang Yang
Ruirun Chen
Xianfei Ding
Yingmei Tan
Jingjie Guo
author_sort Lingyan Zhou
collection DOAJ
description To promote element diffusion in the solid-liquid two-phase region, optimize solidification microstructure, and improve the matching degree of strength and toughness, Ti–46Al–8Nb-2.6C-xTa (at. %) alloys were prepared by arc melting under the action of ultrasound. The lamellar colony, precipitate phase, elements distribution, and related mechanisms were analyzed. Results show that the relative content of the γ phase decreases, while the relative content of the α2 phase and Ti2AlC phase increases as the addition of Ta increases. The coarse long rod-shaped Ti2AlC transforms into short rod-shaped particles. The lamellar colony size reduces from 32.1 to 18.6 μm, the lamellar spacing reduces from 1.4 to 0.7 μm, and the aspect ratio of Ti2AlC reduces from 5.8 to 2.5 as the addition of Ta increases from 0 to 1.0 at. %. The acoustic streaming effect of ultrasound promotes the diffusion of tantalum in the solid-liquid two-phase region for a certain ultrasonic processing time. Tantalum is a heterogeneous nucleation particle of Ti2AlC particles and causes composition supercooling at the forefront of the solidification interface, which is the main reason for refining the microstructure. Compressive strength increases from 1996 to 2596 MPa and the strain increases from 25.4 to 29.3% as the addition of Ta increases from 0 to 0.6 at. %. The main reasons for improving the properties of alloy are the refinement of the microstructure and the formation of a large number of dislocations.
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spelling doaj.art-d0a66215978249a199d4782c5a0aae3a2023-10-30T06:03:06ZengElsevierJournal of Materials Research and Technology2238-78542023-09-012616491662Improvement of microstructure and acquirement of excellent mechanical properties of high-Nb Ti2AlC/TiAl alloy by Ta under ultrasonic action in solid-liquid zoneLingyan Zhou0Hongze Fang1Xiaokang Yang2Ruirun Chen3Xianfei Ding4Yingmei Tan5Jingjie Guo6National Key Laboratory for Precision Hot Processing of Metals, Harbin Institute of Technology, Harbin, Heilongjiang 150001, ChinaNational Key Laboratory for Precision Hot Processing of Metals, Harbin Institute of Technology, Harbin, Heilongjiang 150001, China; Corresponding author.National Key Laboratory for Precision Hot Processing of Metals, Harbin Institute of Technology, Harbin, Heilongjiang 150001, ChinaNational Key Laboratory for Precision Hot Processing of Metals, Harbin Institute of Technology, Harbin, Heilongjiang 150001, China; Corresponding author.Cast Titanium Alloy R&D Center, Beijing Institute of Aeronautical Materials, Beijing, 100095, ChinaSchool of Science, Harbin Institute of Technology, Shenzhen 518055, ChinaNational Key Laboratory for Precision Hot Processing of Metals, Harbin Institute of Technology, Harbin, Heilongjiang 150001, ChinaTo promote element diffusion in the solid-liquid two-phase region, optimize solidification microstructure, and improve the matching degree of strength and toughness, Ti–46Al–8Nb-2.6C-xTa (at. %) alloys were prepared by arc melting under the action of ultrasound. The lamellar colony, precipitate phase, elements distribution, and related mechanisms were analyzed. Results show that the relative content of the γ phase decreases, while the relative content of the α2 phase and Ti2AlC phase increases as the addition of Ta increases. The coarse long rod-shaped Ti2AlC transforms into short rod-shaped particles. The lamellar colony size reduces from 32.1 to 18.6 μm, the lamellar spacing reduces from 1.4 to 0.7 μm, and the aspect ratio of Ti2AlC reduces from 5.8 to 2.5 as the addition of Ta increases from 0 to 1.0 at. %. The acoustic streaming effect of ultrasound promotes the diffusion of tantalum in the solid-liquid two-phase region for a certain ultrasonic processing time. Tantalum is a heterogeneous nucleation particle of Ti2AlC particles and causes composition supercooling at the forefront of the solidification interface, which is the main reason for refining the microstructure. Compressive strength increases from 1996 to 2596 MPa and the strain increases from 25.4 to 29.3% as the addition of Ta increases from 0 to 0.6 at. %. The main reasons for improving the properties of alloy are the refinement of the microstructure and the formation of a large number of dislocations.http://www.sciencedirect.com/science/article/pii/S2238785423018252TiAlElemental solid solutionMicrostructure evolutionCompressive performanceLamellar colony
spellingShingle Lingyan Zhou
Hongze Fang
Xiaokang Yang
Ruirun Chen
Xianfei Ding
Yingmei Tan
Jingjie Guo
Improvement of microstructure and acquirement of excellent mechanical properties of high-Nb Ti2AlC/TiAl alloy by Ta under ultrasonic action in solid-liquid zone
Journal of Materials Research and Technology
TiAl
Elemental solid solution
Microstructure evolution
Compressive performance
Lamellar colony
title Improvement of microstructure and acquirement of excellent mechanical properties of high-Nb Ti2AlC/TiAl alloy by Ta under ultrasonic action in solid-liquid zone
title_full Improvement of microstructure and acquirement of excellent mechanical properties of high-Nb Ti2AlC/TiAl alloy by Ta under ultrasonic action in solid-liquid zone
title_fullStr Improvement of microstructure and acquirement of excellent mechanical properties of high-Nb Ti2AlC/TiAl alloy by Ta under ultrasonic action in solid-liquid zone
title_full_unstemmed Improvement of microstructure and acquirement of excellent mechanical properties of high-Nb Ti2AlC/TiAl alloy by Ta under ultrasonic action in solid-liquid zone
title_short Improvement of microstructure and acquirement of excellent mechanical properties of high-Nb Ti2AlC/TiAl alloy by Ta under ultrasonic action in solid-liquid zone
title_sort improvement of microstructure and acquirement of excellent mechanical properties of high nb ti2alc tial alloy by ta under ultrasonic action in solid liquid zone
topic TiAl
Elemental solid solution
Microstructure evolution
Compressive performance
Lamellar colony
url http://www.sciencedirect.com/science/article/pii/S2238785423018252
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