Preparation and Characterization of PHBV/PCL-Diol Blend Films
Biodegradable thin films based on poly(3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV) and poly(caprolactone diol) (PCL-diol) blend were developed using the solution casting method. PHBV is biodegradable, biocompatible, and produced naturally by bacterial activity, but its use is restricted by high c...
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| Format: | Article |
| Language: | English |
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MDPI AG
2023-12-01
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| Series: | Polymers |
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| Online Access: | https://www.mdpi.com/2073-4360/15/24/4694 |
| _version_ | 1797379596410159104 |
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| author | Tamara Erceg Sanja Rackov Pal Terek Branka Pilić |
| author_facet | Tamara Erceg Sanja Rackov Pal Terek Branka Pilić |
| author_sort | Tamara Erceg |
| collection | DOAJ |
| description | Biodegradable thin films based on poly(3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV) and poly(caprolactone diol) (PCL-diol) blend were developed using the solution casting method. PHBV is biodegradable, biocompatible, and produced naturally by bacterial activity, but its use is restricted by high crystallinity and low resistance to thermal degradation with melting temperatures close to degradation thus narrowing the processing window. Solution casting was chosen as a cost-effective method reducing energy consumption and avoiding thermal degradation during processing. The increase in PCL-diol in blend composition (40–60 wt%) enhances the film-forming ability of PHBV and the wettability along with the decrease in the roughness of the resulting materials as revealed by contact angle measurements, scanning electron microscopy (SEM), and atomic force microscopy (AFM). Optimal composition in terms of filmogenity and surface structure has been achieved by the addition of PCL-diol in the amount of 60 wt%. FTIR confirmed the expected chemical structures with no evidence of chemical interactions between the two polymers. |
| first_indexed | 2024-03-08T20:25:26Z |
| format | Article |
| id | doaj.art-d0b9fe49a59148f182d536fee190d4b5 |
| institution | Directory Open Access Journal |
| issn | 2073-4360 |
| language | English |
| last_indexed | 2024-03-08T20:25:26Z |
| publishDate | 2023-12-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Polymers |
| spelling | doaj.art-d0b9fe49a59148f182d536fee190d4b52023-12-22T14:36:42ZengMDPI AGPolymers2073-43602023-12-011524469410.3390/polym15244694Preparation and Characterization of PHBV/PCL-Diol Blend FilmsTamara Erceg0Sanja Rackov1Pal Terek2Branka Pilić3Faculty of Technology Novi Sad, University of Novi Sad, 21000 Novi Sad, SerbiaFaculty of Technology Novi Sad, University of Novi Sad, 21000 Novi Sad, SerbiaFaculty of Technical Sciences, University of Novi Sad, 21000 Novi Sad, SerbiaFaculty of Technology Novi Sad, University of Novi Sad, 21000 Novi Sad, SerbiaBiodegradable thin films based on poly(3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV) and poly(caprolactone diol) (PCL-diol) blend were developed using the solution casting method. PHBV is biodegradable, biocompatible, and produced naturally by bacterial activity, but its use is restricted by high crystallinity and low resistance to thermal degradation with melting temperatures close to degradation thus narrowing the processing window. Solution casting was chosen as a cost-effective method reducing energy consumption and avoiding thermal degradation during processing. The increase in PCL-diol in blend composition (40–60 wt%) enhances the film-forming ability of PHBV and the wettability along with the decrease in the roughness of the resulting materials as revealed by contact angle measurements, scanning electron microscopy (SEM), and atomic force microscopy (AFM). Optimal composition in terms of filmogenity and surface structure has been achieved by the addition of PCL-diol in the amount of 60 wt%. FTIR confirmed the expected chemical structures with no evidence of chemical interactions between the two polymers.https://www.mdpi.com/2073-4360/15/24/4694poly(3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV)poly(caprolactone diol) (PCL-diol)blendbiopolymersfilm-forming ability |
| spellingShingle | Tamara Erceg Sanja Rackov Pal Terek Branka Pilić Preparation and Characterization of PHBV/PCL-Diol Blend Films Polymers poly(3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV) poly(caprolactone diol) (PCL-diol) blend biopolymers film-forming ability |
| title | Preparation and Characterization of PHBV/PCL-Diol Blend Films |
| title_full | Preparation and Characterization of PHBV/PCL-Diol Blend Films |
| title_fullStr | Preparation and Characterization of PHBV/PCL-Diol Blend Films |
| title_full_unstemmed | Preparation and Characterization of PHBV/PCL-Diol Blend Films |
| title_short | Preparation and Characterization of PHBV/PCL-Diol Blend Films |
| title_sort | preparation and characterization of phbv pcl diol blend films |
| topic | poly(3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV) poly(caprolactone diol) (PCL-diol) blend biopolymers film-forming ability |
| url | https://www.mdpi.com/2073-4360/15/24/4694 |
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