New black indium oxide—tandem photothermal CO2-H2 methanol selective catalyst
Harsh reaction conditions are generally required for CO2 hydrogenation to shift the thermodynamic equilibrium towards methanol synthesis. Here, a new black indium oxide with two types of active sites, frustrated Lewis pairs and oxygen vacancies, is prepared, and facilitates a tandem synthesis of met...
| Main Authors: | , , , , , , , , , , , , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
Nature Portfolio
2022-03-01
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| Series: | Nature Communications |
| Online Access: | https://doi.org/10.1038/s41467-022-29222-7 |
| _version_ | 1811335522879012864 |
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| author | Zeshu Zhang Chengliang Mao Débora Motta Meira Paul N. Duchesne Athanasios A. Tountas Zhao Li Chenyue Qiu Sanli Tang Rui Song Xue Ding Junchuan Sun Jiangfan Yu Jane Y. Howe Wenguang Tu Lu Wang Geoffrey A. Ozin |
| author_facet | Zeshu Zhang Chengliang Mao Débora Motta Meira Paul N. Duchesne Athanasios A. Tountas Zhao Li Chenyue Qiu Sanli Tang Rui Song Xue Ding Junchuan Sun Jiangfan Yu Jane Y. Howe Wenguang Tu Lu Wang Geoffrey A. Ozin |
| author_sort | Zeshu Zhang |
| collection | DOAJ |
| description | Harsh reaction conditions are generally required for CO2 hydrogenation to shift the thermodynamic equilibrium towards methanol synthesis. Here, a new black indium oxide with two types of active sites, frustrated Lewis pairs and oxygen vacancies, is prepared, and facilitates a tandem synthesis of methanol at a low hydrogen concentration (50%) and ambient pressure. |
| first_indexed | 2024-04-13T17:25:20Z |
| format | Article |
| id | doaj.art-d0c5ff69a29242cbb8829176d7120e74 |
| institution | Directory Open Access Journal |
| issn | 2041-1723 |
| language | English |
| last_indexed | 2024-04-13T17:25:20Z |
| publishDate | 2022-03-01 |
| publisher | Nature Portfolio |
| record_format | Article |
| series | Nature Communications |
| spelling | doaj.art-d0c5ff69a29242cbb8829176d7120e742022-12-22T02:37:48ZengNature PortfolioNature Communications2041-17232022-03-011311810.1038/s41467-022-29222-7New black indium oxide—tandem photothermal CO2-H2 methanol selective catalystZeshu Zhang0Chengliang Mao1Débora Motta Meira2Paul N. Duchesne3Athanasios A. Tountas4Zhao Li5Chenyue Qiu6Sanli Tang7Rui Song8Xue Ding9Junchuan Sun10Jiangfan Yu11Jane Y. Howe12Wenguang Tu13Lu Wang14Geoffrey A. Ozin15School of Science and Engineering, The Chinese University of Hong Kong, ShenzhenSolar Fuels Group, Department of Chemistry, University of TorontoCLS@APS, Advanced Photon Source, Argonne National LaboratoryDepartment of Chemistry, Queen’s UniversitySolar Fuels Group, Department of Chemistry, University of TorontoSolar Fuels Group, Department of Chemistry, University of TorontoDepartment of Materials Science and Engineering, University of TorontoSolar Fuels Group, Department of Chemistry, University of TorontoSolar Fuels Group, Department of Chemistry, University of TorontoSchool of Science and Engineering, The Chinese University of Hong Kong, ShenzhenSchool of Science and Engineering, The Chinese University of Hong Kong, ShenzhenSchool of Science and Engineering, The Chinese University of Hong Kong, ShenzhenDepartment of Materials Science and Engineering, University of TorontoSchool of Science and Engineering, The Chinese University of Hong Kong, ShenzhenSchool of Science and Engineering, The Chinese University of Hong Kong, ShenzhenSolar Fuels Group, Department of Chemistry, University of TorontoHarsh reaction conditions are generally required for CO2 hydrogenation to shift the thermodynamic equilibrium towards methanol synthesis. Here, a new black indium oxide with two types of active sites, frustrated Lewis pairs and oxygen vacancies, is prepared, and facilitates a tandem synthesis of methanol at a low hydrogen concentration (50%) and ambient pressure.https://doi.org/10.1038/s41467-022-29222-7 |
| spellingShingle | Zeshu Zhang Chengliang Mao Débora Motta Meira Paul N. Duchesne Athanasios A. Tountas Zhao Li Chenyue Qiu Sanli Tang Rui Song Xue Ding Junchuan Sun Jiangfan Yu Jane Y. Howe Wenguang Tu Lu Wang Geoffrey A. Ozin New black indium oxide—tandem photothermal CO2-H2 methanol selective catalyst Nature Communications |
| title | New black indium oxide—tandem photothermal CO2-H2 methanol selective catalyst |
| title_full | New black indium oxide—tandem photothermal CO2-H2 methanol selective catalyst |
| title_fullStr | New black indium oxide—tandem photothermal CO2-H2 methanol selective catalyst |
| title_full_unstemmed | New black indium oxide—tandem photothermal CO2-H2 methanol selective catalyst |
| title_short | New black indium oxide—tandem photothermal CO2-H2 methanol selective catalyst |
| title_sort | new black indium oxide tandem photothermal co2 h2 methanol selective catalyst |
| url | https://doi.org/10.1038/s41467-022-29222-7 |
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