A first attempt into the production of acylglycerol mixtures from Echium oil
Enzymatic glycerolysis of Echium oil (Echium plantagineum) has been carried out in the presence of four commercial lipases. Different pretreatment of the reaction mixture, such as high pressure homogenization and addition of food grade monoolein as an emulsifier, were evaluated to test their influen...
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Format: | Article |
Language: | English |
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Frontiers Media S.A.
2016-01-01
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Series: | Frontiers in Bioengineering and Biotechnology |
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Online Access: | http://journal.frontiersin.org/Journal/10.3389/fbioe.2015.00208/full |
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author | Luis eVázquez Alejandro eJordán Guillermo eReglero Guillermo eReglero Carlos F Torres |
author_facet | Luis eVázquez Alejandro eJordán Guillermo eReglero Guillermo eReglero Carlos F Torres |
author_sort | Luis eVázquez |
collection | DOAJ |
description | Enzymatic glycerolysis of Echium oil (Echium plantagineum) has been carried out in the presence of four commercial lipases. Different pretreatment of the reaction mixture, such as high pressure homogenization and addition of food grade monoolein as an emulsifier, were evaluated to test their influence on the glycerolysis reaction. In addition, the impact of reducing temperature and the utilization of a solvent generally recognized as safe as a flavoring agent, such as limonene, were also investigated. Conversion of ca. 60-70 % of triacylglycerols, and production of ca. 25-30 % of monoacylglycerols were attained. Finally, at the best reaction conditions, the glycerolysis reaction was scaled-up at pilot plant and the product mixture obtained, fractionated via molecular distillation. From this stage, two products were attained: a distillate containing 80 % of monoacylglycerols and a residue containing approximately 50% of diacylglycerols and 50 % of triacylglycerols. All these mixtures can be utilized as self-emulsifying vehicles for the formulation of bioactive substances and also as precursors for the production of structured bioactive lipids. |
first_indexed | 2024-12-14T10:54:07Z |
format | Article |
id | doaj.art-d0cf42b602b54d73ae7150b01dd7b77c |
institution | Directory Open Access Journal |
issn | 2296-4185 |
language | English |
last_indexed | 2024-12-14T10:54:07Z |
publishDate | 2016-01-01 |
publisher | Frontiers Media S.A. |
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series | Frontiers in Bioengineering and Biotechnology |
spelling | doaj.art-d0cf42b602b54d73ae7150b01dd7b77c2022-12-21T23:05:03ZengFrontiers Media S.A.Frontiers in Bioengineering and Biotechnology2296-41852016-01-01310.3389/fbioe.2015.00208135627A first attempt into the production of acylglycerol mixtures from Echium oilLuis eVázquez0Alejandro eJordán1Guillermo eReglero2Guillermo eReglero3Carlos F Torres4CIALCIALCIALIMDEA-Food InstituteCIALEnzymatic glycerolysis of Echium oil (Echium plantagineum) has been carried out in the presence of four commercial lipases. Different pretreatment of the reaction mixture, such as high pressure homogenization and addition of food grade monoolein as an emulsifier, were evaluated to test their influence on the glycerolysis reaction. In addition, the impact of reducing temperature and the utilization of a solvent generally recognized as safe as a flavoring agent, such as limonene, were also investigated. Conversion of ca. 60-70 % of triacylglycerols, and production of ca. 25-30 % of monoacylglycerols were attained. Finally, at the best reaction conditions, the glycerolysis reaction was scaled-up at pilot plant and the product mixture obtained, fractionated via molecular distillation. From this stage, two products were attained: a distillate containing 80 % of monoacylglycerols and a residue containing approximately 50% of diacylglycerols and 50 % of triacylglycerols. All these mixtures can be utilized as self-emulsifying vehicles for the formulation of bioactive substances and also as precursors for the production of structured bioactive lipids.http://journal.frontiersin.org/Journal/10.3389/fbioe.2015.00208/fullLipasemonoacylglycerolGlycerolysisSelf-emulsifyingEchium oil |
spellingShingle | Luis eVázquez Alejandro eJordán Guillermo eReglero Guillermo eReglero Carlos F Torres A first attempt into the production of acylglycerol mixtures from Echium oil Frontiers in Bioengineering and Biotechnology Lipase monoacylglycerol Glycerolysis Self-emulsifying Echium oil |
title | A first attempt into the production of acylglycerol mixtures from Echium oil |
title_full | A first attempt into the production of acylglycerol mixtures from Echium oil |
title_fullStr | A first attempt into the production of acylglycerol mixtures from Echium oil |
title_full_unstemmed | A first attempt into the production of acylglycerol mixtures from Echium oil |
title_short | A first attempt into the production of acylglycerol mixtures from Echium oil |
title_sort | first attempt into the production of acylglycerol mixtures from echium oil |
topic | Lipase monoacylglycerol Glycerolysis Self-emulsifying Echium oil |
url | http://journal.frontiersin.org/Journal/10.3389/fbioe.2015.00208/full |
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