Determination of Phthalate Esters in Beverages and Water Samples by Solid Phase Extraction with Resin Based COFs as Filler
Resin based covalent organic framework material was used as filler for solid phase extraction (SPE), and the solid phase extraction effect was compared with that of traditional COF material (TpBD COFs). The enrichment capacity of four phthalate esters (dimethyl phthalate, diethyl phthalate, dibutyl...
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MDPI AG
2021-11-01
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author | Yunjie Ma Xin Gao Yang Ruan Hang Cui Li Zhang Wei Zhang Shaoyan Wang |
author_facet | Yunjie Ma Xin Gao Yang Ruan Hang Cui Li Zhang Wei Zhang Shaoyan Wang |
author_sort | Yunjie Ma |
collection | DOAJ |
description | Resin based covalent organic framework material was used as filler for solid phase extraction (SPE), and the solid phase extraction effect was compared with that of traditional COF material (TpBD COFs). The enrichment capacity of four phthalate esters (dimethyl phthalate, diethyl phthalate, dibutyl phthalate, dioctyl phthalate) in beverage samples was investigated by SPE. Adsorption experiments showed that the kinetic adsorption behavior of COF materials for phthalate esters (PAEs) was more consistent with the quasi-second-order kinetic adsorption model, and the static adsorption behavior is more in line with the Freundlich isothermal adsorption model. Solid phase extraction experiments proved that the SPE column prepared with two COF materials as adsorbents had good adsorption effects, high recovery (water: 97.99–100.56% and beverage: 97.93–100.23%) and were reusable (50 cycles), which could meet the requirements for trace detection of phthalate ester. It was found that the solid phase extraction effect was better than the four types of commercial SPE columns. The new COF material reduced the cost of monomer use and provided the possibility for its industrial production. Meanwhile, it also provided a new feasible scheme for enriching trace phthalate esters in practical samples. |
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spelling | doaj.art-d0d4b38653a94ba2940d3ab6383f76a92023-11-23T03:13:59ZengMDPI AGWater2073-44412021-11-011323333810.3390/w13233338Determination of Phthalate Esters in Beverages and Water Samples by Solid Phase Extraction with Resin Based COFs as FillerYunjie Ma0Xin Gao1Yang Ruan2Hang Cui3Li Zhang4Wei Zhang5Shaoyan Wang6School of Chemical Engineering, Liaoning Provincial Key Laboratory of Fine Separation Technique, University of Science and Technology, Liaoning, Anshan 114051, ChinaSchool of Chemical Engineering, Liaoning Provincial Key Laboratory of Fine Separation Technique, University of Science and Technology, Liaoning, Anshan 114051, ChinaSchool of Chemical Engineering, Liaoning Provincial Key Laboratory of Fine Separation Technique, University of Science and Technology, Liaoning, Anshan 114051, ChinaSchool of Chemical Engineering, Liaoning Provincial Key Laboratory of Fine Separation Technique, University of Science and Technology, Liaoning, Anshan 114051, ChinaSchool of Chemical Engineering, Liaoning Provincial Key Laboratory of Fine Separation Technique, University of Science and Technology, Liaoning, Anshan 114051, ChinaSchool of Chemical Engineering, Liaoning Provincial Key Laboratory of Fine Separation Technique, University of Science and Technology, Liaoning, Anshan 114051, ChinaSchool of Chemical Engineering, Liaoning Provincial Key Laboratory of Fine Separation Technique, University of Science and Technology, Liaoning, Anshan 114051, ChinaResin based covalent organic framework material was used as filler for solid phase extraction (SPE), and the solid phase extraction effect was compared with that of traditional COF material (TpBD COFs). The enrichment capacity of four phthalate esters (dimethyl phthalate, diethyl phthalate, dibutyl phthalate, dioctyl phthalate) in beverage samples was investigated by SPE. Adsorption experiments showed that the kinetic adsorption behavior of COF materials for phthalate esters (PAEs) was more consistent with the quasi-second-order kinetic adsorption model, and the static adsorption behavior is more in line with the Freundlich isothermal adsorption model. Solid phase extraction experiments proved that the SPE column prepared with two COF materials as adsorbents had good adsorption effects, high recovery (water: 97.99–100.56% and beverage: 97.93–100.23%) and were reusable (50 cycles), which could meet the requirements for trace detection of phthalate ester. It was found that the solid phase extraction effect was better than the four types of commercial SPE columns. The new COF material reduced the cost of monomer use and provided the possibility for its industrial production. Meanwhile, it also provided a new feasible scheme for enriching trace phthalate esters in practical samples.https://www.mdpi.com/2073-4441/13/23/3338resin-based COFsphthalate esterssolid phase extractiontrace analysis |
spellingShingle | Yunjie Ma Xin Gao Yang Ruan Hang Cui Li Zhang Wei Zhang Shaoyan Wang Determination of Phthalate Esters in Beverages and Water Samples by Solid Phase Extraction with Resin Based COFs as Filler Water resin-based COFs phthalate esters solid phase extraction trace analysis |
title | Determination of Phthalate Esters in Beverages and Water Samples by Solid Phase Extraction with Resin Based COFs as Filler |
title_full | Determination of Phthalate Esters in Beverages and Water Samples by Solid Phase Extraction with Resin Based COFs as Filler |
title_fullStr | Determination of Phthalate Esters in Beverages and Water Samples by Solid Phase Extraction with Resin Based COFs as Filler |
title_full_unstemmed | Determination of Phthalate Esters in Beverages and Water Samples by Solid Phase Extraction with Resin Based COFs as Filler |
title_short | Determination of Phthalate Esters in Beverages and Water Samples by Solid Phase Extraction with Resin Based COFs as Filler |
title_sort | determination of phthalate esters in beverages and water samples by solid phase extraction with resin based cofs as filler |
topic | resin-based COFs phthalate esters solid phase extraction trace analysis |
url | https://www.mdpi.com/2073-4441/13/23/3338 |
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