Multi-Walled Carbon-Nanotube-Reinforced PMMA Nanocomposites: An Experimental Study of Their Friction and Wear Properties
This manuscript presents an experimental investigation of the friction and wear properties of poly (methyl methacrylate) (PMMA) nanocomposites reinforced with functionalized multi-walled carbon nanotubes (MWCNTs). The aim of this study is to evaluate the potential of MWCNTs as a reinforcement materi...
Main Authors: | , , , , , , , |
---|---|
Format: | Article |
Language: | English |
Published: |
MDPI AG
2023-06-01
|
Series: | Polymers |
Subjects: | |
Online Access: | https://www.mdpi.com/2073-4360/15/13/2785 |
_version_ | 1797591016919793664 |
---|---|
author | Vijay Patel Unnati Joshi Anand Joshi Blessing Kudzai Matanda Kamlesh Chauhan Ankit D. Oza Diana-Petronela Burduhos-Nergis Dumitru-Doru Burduhos-Nergis |
author_facet | Vijay Patel Unnati Joshi Anand Joshi Blessing Kudzai Matanda Kamlesh Chauhan Ankit D. Oza Diana-Petronela Burduhos-Nergis Dumitru-Doru Burduhos-Nergis |
author_sort | Vijay Patel |
collection | DOAJ |
description | This manuscript presents an experimental investigation of the friction and wear properties of poly (methyl methacrylate) (PMMA) nanocomposites reinforced with functionalized multi-walled carbon nanotubes (MWCNTs). The aim of this study is to evaluate the potential of MWCNTs as a reinforcement material for enhancing the tribological performance of PMMA. Three types of multi-walled carbon nanotubes, i.e., pristine, hydroxyl functionalized, and carboxyl functionalized, were utilized in this study. The nanocomposite samples were prepared by dispersing varying concentrations of MWCNTs (0.1 wt.%, 0.5 wt.%, and 1 wt.%) within the PMMA matrix via a 3D mixing approach, followed by injection molding/compression molding. The resulting nanocomposite films were characterized using scanning electron microscopy (SEM) to observe the dispersion of MWCNTs within the PMMA matrix. The friction and wear tests were conducted using a pin-on-disk tribometer under dry sliding conditions. The effects of functionalization and MWCNT content on the tribological behaviors of the nanocomposites were analyzed. The nanocomposites exhibited lower friction coefficients and reduced wear rates compared to pure PMMA. The lowest friction coefficient and wear rate were achieved at an optimum MWCNT loading of 0.5 wt.%. It was further revealed that the amount of MWCNT reinforcement, average load, and track diameter significantly affect the coefficient of friction (COF) and rate of wear. The COF and wear rate are best at a filler loading of 0.5 wt.%, a 20 Kg load, and 90 mm. The improved tribological performance of the MWCNT-reinforced PMMA nanocomposites can be attributed to the effective transfer of load between the MWCNTs and the PMMA matrix, as well as the reinforcement effect of the MWCNTs. The MWCNTs acted as reinforcing agents, enhancing the mechanical properties and wear resistance of the nanocomposites. |
first_indexed | 2024-03-11T01:31:43Z |
format | Article |
id | doaj.art-d0f18176cb9048eda06842b7ea5bec1b |
institution | Directory Open Access Journal |
issn | 2073-4360 |
language | English |
last_indexed | 2024-03-11T01:31:43Z |
publishDate | 2023-06-01 |
publisher | MDPI AG |
record_format | Article |
series | Polymers |
spelling | doaj.art-d0f18176cb9048eda06842b7ea5bec1b2023-11-18T17:20:03ZengMDPI AGPolymers2073-43602023-06-011513278510.3390/polym15132785Multi-Walled Carbon-Nanotube-Reinforced PMMA Nanocomposites: An Experimental Study of Their Friction and Wear PropertiesVijay Patel0Unnati Joshi1Anand Joshi2Blessing Kudzai Matanda3Kamlesh Chauhan4Ankit D. Oza5Diana-Petronela Burduhos-Nergis6Dumitru-Doru Burduhos-Nergis7Department of Mechanical Engineering, Parul University, Vadodara 391760, Gujarat, IndiaDepartment of Mechanical Engineering, Parul University, Vadodara 391760, Gujarat, IndiaDepartment of Mechatronics Engineering, Parul University, Vadodara 391760, Gujarat, IndiaDepartment of Mechanical Engineering, Parul University, Vadodara 391760, Gujarat, IndiaDepartment of Mechanical Engineering, Charusat University, Anand 388421, Gujarat, IndiaDepartment of Computer Sciences and Engineering, Institute of Advanced Research, Gandhinagar 382426, Gujarat, IndiaFaculty of Materials Science and Engineering, Gheorghe Asachi Technical University of Iasi, 700050 Iasi, RomaniaFaculty of Materials Science and Engineering, Gheorghe Asachi Technical University of Iasi, 700050 Iasi, RomaniaThis manuscript presents an experimental investigation of the friction and wear properties of poly (methyl methacrylate) (PMMA) nanocomposites reinforced with functionalized multi-walled carbon nanotubes (MWCNTs). The aim of this study is to evaluate the potential of MWCNTs as a reinforcement material for enhancing the tribological performance of PMMA. Three types of multi-walled carbon nanotubes, i.e., pristine, hydroxyl functionalized, and carboxyl functionalized, were utilized in this study. The nanocomposite samples were prepared by dispersing varying concentrations of MWCNTs (0.1 wt.%, 0.5 wt.%, and 1 wt.%) within the PMMA matrix via a 3D mixing approach, followed by injection molding/compression molding. The resulting nanocomposite films were characterized using scanning electron microscopy (SEM) to observe the dispersion of MWCNTs within the PMMA matrix. The friction and wear tests were conducted using a pin-on-disk tribometer under dry sliding conditions. The effects of functionalization and MWCNT content on the tribological behaviors of the nanocomposites were analyzed. The nanocomposites exhibited lower friction coefficients and reduced wear rates compared to pure PMMA. The lowest friction coefficient and wear rate were achieved at an optimum MWCNT loading of 0.5 wt.%. It was further revealed that the amount of MWCNT reinforcement, average load, and track diameter significantly affect the coefficient of friction (COF) and rate of wear. The COF and wear rate are best at a filler loading of 0.5 wt.%, a 20 Kg load, and 90 mm. The improved tribological performance of the MWCNT-reinforced PMMA nanocomposites can be attributed to the effective transfer of load between the MWCNTs and the PMMA matrix, as well as the reinforcement effect of the MWCNTs. The MWCNTs acted as reinforcing agents, enhancing the mechanical properties and wear resistance of the nanocomposites.https://www.mdpi.com/2073-4360/15/13/2785nanocompositetribologyscanning electron microscopycarbon nanotubes |
spellingShingle | Vijay Patel Unnati Joshi Anand Joshi Blessing Kudzai Matanda Kamlesh Chauhan Ankit D. Oza Diana-Petronela Burduhos-Nergis Dumitru-Doru Burduhos-Nergis Multi-Walled Carbon-Nanotube-Reinforced PMMA Nanocomposites: An Experimental Study of Their Friction and Wear Properties Polymers nanocomposite tribology scanning electron microscopy carbon nanotubes |
title | Multi-Walled Carbon-Nanotube-Reinforced PMMA Nanocomposites: An Experimental Study of Their Friction and Wear Properties |
title_full | Multi-Walled Carbon-Nanotube-Reinforced PMMA Nanocomposites: An Experimental Study of Their Friction and Wear Properties |
title_fullStr | Multi-Walled Carbon-Nanotube-Reinforced PMMA Nanocomposites: An Experimental Study of Their Friction and Wear Properties |
title_full_unstemmed | Multi-Walled Carbon-Nanotube-Reinforced PMMA Nanocomposites: An Experimental Study of Their Friction and Wear Properties |
title_short | Multi-Walled Carbon-Nanotube-Reinforced PMMA Nanocomposites: An Experimental Study of Their Friction and Wear Properties |
title_sort | multi walled carbon nanotube reinforced pmma nanocomposites an experimental study of their friction and wear properties |
topic | nanocomposite tribology scanning electron microscopy carbon nanotubes |
url | https://www.mdpi.com/2073-4360/15/13/2785 |
work_keys_str_mv | AT vijaypatel multiwalledcarbonnanotubereinforcedpmmananocompositesanexperimentalstudyoftheirfrictionandwearproperties AT unnatijoshi multiwalledcarbonnanotubereinforcedpmmananocompositesanexperimentalstudyoftheirfrictionandwearproperties AT anandjoshi multiwalledcarbonnanotubereinforcedpmmananocompositesanexperimentalstudyoftheirfrictionandwearproperties AT blessingkudzaimatanda multiwalledcarbonnanotubereinforcedpmmananocompositesanexperimentalstudyoftheirfrictionandwearproperties AT kamleshchauhan multiwalledcarbonnanotubereinforcedpmmananocompositesanexperimentalstudyoftheirfrictionandwearproperties AT ankitdoza multiwalledcarbonnanotubereinforcedpmmananocompositesanexperimentalstudyoftheirfrictionandwearproperties AT dianapetronelaburduhosnergis multiwalledcarbonnanotubereinforcedpmmananocompositesanexperimentalstudyoftheirfrictionandwearproperties AT dumitrudoruburduhosnergis multiwalledcarbonnanotubereinforcedpmmananocompositesanexperimentalstudyoftheirfrictionandwearproperties |