Multi-Walled Carbon-Nanotube-Reinforced PMMA Nanocomposites: An Experimental Study of Their Friction and Wear Properties

This manuscript presents an experimental investigation of the friction and wear properties of poly (methyl methacrylate) (PMMA) nanocomposites reinforced with functionalized multi-walled carbon nanotubes (MWCNTs). The aim of this study is to evaluate the potential of MWCNTs as a reinforcement materi...

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Main Authors: Vijay Patel, Unnati Joshi, Anand Joshi, Blessing Kudzai Matanda, Kamlesh Chauhan, Ankit D. Oza, Diana-Petronela Burduhos-Nergis, Dumitru-Doru Burduhos-Nergis
Format: Article
Language:English
Published: MDPI AG 2023-06-01
Series:Polymers
Subjects:
Online Access:https://www.mdpi.com/2073-4360/15/13/2785
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author Vijay Patel
Unnati Joshi
Anand Joshi
Blessing Kudzai Matanda
Kamlesh Chauhan
Ankit D. Oza
Diana-Petronela Burduhos-Nergis
Dumitru-Doru Burduhos-Nergis
author_facet Vijay Patel
Unnati Joshi
Anand Joshi
Blessing Kudzai Matanda
Kamlesh Chauhan
Ankit D. Oza
Diana-Petronela Burduhos-Nergis
Dumitru-Doru Burduhos-Nergis
author_sort Vijay Patel
collection DOAJ
description This manuscript presents an experimental investigation of the friction and wear properties of poly (methyl methacrylate) (PMMA) nanocomposites reinforced with functionalized multi-walled carbon nanotubes (MWCNTs). The aim of this study is to evaluate the potential of MWCNTs as a reinforcement material for enhancing the tribological performance of PMMA. Three types of multi-walled carbon nanotubes, i.e., pristine, hydroxyl functionalized, and carboxyl functionalized, were utilized in this study. The nanocomposite samples were prepared by dispersing varying concentrations of MWCNTs (0.1 wt.%, 0.5 wt.%, and 1 wt.%) within the PMMA matrix via a 3D mixing approach, followed by injection molding/compression molding. The resulting nanocomposite films were characterized using scanning electron microscopy (SEM) to observe the dispersion of MWCNTs within the PMMA matrix. The friction and wear tests were conducted using a pin-on-disk tribometer under dry sliding conditions. The effects of functionalization and MWCNT content on the tribological behaviors of the nanocomposites were analyzed. The nanocomposites exhibited lower friction coefficients and reduced wear rates compared to pure PMMA. The lowest friction coefficient and wear rate were achieved at an optimum MWCNT loading of 0.5 wt.%. It was further revealed that the amount of MWCNT reinforcement, average load, and track diameter significantly affect the coefficient of friction (COF) and rate of wear. The COF and wear rate are best at a filler loading of 0.5 wt.%, a 20 Kg load, and 90 mm. The improved tribological performance of the MWCNT-reinforced PMMA nanocomposites can be attributed to the effective transfer of load between the MWCNTs and the PMMA matrix, as well as the reinforcement effect of the MWCNTs. The MWCNTs acted as reinforcing agents, enhancing the mechanical properties and wear resistance of the nanocomposites.
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spelling doaj.art-d0f18176cb9048eda06842b7ea5bec1b2023-11-18T17:20:03ZengMDPI AGPolymers2073-43602023-06-011513278510.3390/polym15132785Multi-Walled Carbon-Nanotube-Reinforced PMMA Nanocomposites: An Experimental Study of Their Friction and Wear PropertiesVijay Patel0Unnati Joshi1Anand Joshi2Blessing Kudzai Matanda3Kamlesh Chauhan4Ankit D. Oza5Diana-Petronela Burduhos-Nergis6Dumitru-Doru Burduhos-Nergis7Department of Mechanical Engineering, Parul University, Vadodara 391760, Gujarat, IndiaDepartment of Mechanical Engineering, Parul University, Vadodara 391760, Gujarat, IndiaDepartment of Mechatronics Engineering, Parul University, Vadodara 391760, Gujarat, IndiaDepartment of Mechanical Engineering, Parul University, Vadodara 391760, Gujarat, IndiaDepartment of Mechanical Engineering, Charusat University, Anand 388421, Gujarat, IndiaDepartment of Computer Sciences and Engineering, Institute of Advanced Research, Gandhinagar 382426, Gujarat, IndiaFaculty of Materials Science and Engineering, Gheorghe Asachi Technical University of Iasi, 700050 Iasi, RomaniaFaculty of Materials Science and Engineering, Gheorghe Asachi Technical University of Iasi, 700050 Iasi, RomaniaThis manuscript presents an experimental investigation of the friction and wear properties of poly (methyl methacrylate) (PMMA) nanocomposites reinforced with functionalized multi-walled carbon nanotubes (MWCNTs). The aim of this study is to evaluate the potential of MWCNTs as a reinforcement material for enhancing the tribological performance of PMMA. Three types of multi-walled carbon nanotubes, i.e., pristine, hydroxyl functionalized, and carboxyl functionalized, were utilized in this study. The nanocomposite samples were prepared by dispersing varying concentrations of MWCNTs (0.1 wt.%, 0.5 wt.%, and 1 wt.%) within the PMMA matrix via a 3D mixing approach, followed by injection molding/compression molding. The resulting nanocomposite films were characterized using scanning electron microscopy (SEM) to observe the dispersion of MWCNTs within the PMMA matrix. The friction and wear tests were conducted using a pin-on-disk tribometer under dry sliding conditions. The effects of functionalization and MWCNT content on the tribological behaviors of the nanocomposites were analyzed. The nanocomposites exhibited lower friction coefficients and reduced wear rates compared to pure PMMA. The lowest friction coefficient and wear rate were achieved at an optimum MWCNT loading of 0.5 wt.%. It was further revealed that the amount of MWCNT reinforcement, average load, and track diameter significantly affect the coefficient of friction (COF) and rate of wear. The COF and wear rate are best at a filler loading of 0.5 wt.%, a 20 Kg load, and 90 mm. The improved tribological performance of the MWCNT-reinforced PMMA nanocomposites can be attributed to the effective transfer of load between the MWCNTs and the PMMA matrix, as well as the reinforcement effect of the MWCNTs. The MWCNTs acted as reinforcing agents, enhancing the mechanical properties and wear resistance of the nanocomposites.https://www.mdpi.com/2073-4360/15/13/2785nanocompositetribologyscanning electron microscopycarbon nanotubes
spellingShingle Vijay Patel
Unnati Joshi
Anand Joshi
Blessing Kudzai Matanda
Kamlesh Chauhan
Ankit D. Oza
Diana-Petronela Burduhos-Nergis
Dumitru-Doru Burduhos-Nergis
Multi-Walled Carbon-Nanotube-Reinforced PMMA Nanocomposites: An Experimental Study of Their Friction and Wear Properties
Polymers
nanocomposite
tribology
scanning electron microscopy
carbon nanotubes
title Multi-Walled Carbon-Nanotube-Reinforced PMMA Nanocomposites: An Experimental Study of Their Friction and Wear Properties
title_full Multi-Walled Carbon-Nanotube-Reinforced PMMA Nanocomposites: An Experimental Study of Their Friction and Wear Properties
title_fullStr Multi-Walled Carbon-Nanotube-Reinforced PMMA Nanocomposites: An Experimental Study of Their Friction and Wear Properties
title_full_unstemmed Multi-Walled Carbon-Nanotube-Reinforced PMMA Nanocomposites: An Experimental Study of Their Friction and Wear Properties
title_short Multi-Walled Carbon-Nanotube-Reinforced PMMA Nanocomposites: An Experimental Study of Their Friction and Wear Properties
title_sort multi walled carbon nanotube reinforced pmma nanocomposites an experimental study of their friction and wear properties
topic nanocomposite
tribology
scanning electron microscopy
carbon nanotubes
url https://www.mdpi.com/2073-4360/15/13/2785
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