Synthesis And Biological Activity Studies of Some Novel Metal Complexes Derivate From 2-(2-Imino-1- Methylimidazolidin-4-Ylidene) Hydrazinecarbothioamide
2-(2-imino-1-methylimidazolidin-4-ylidene)hydrazinecarbothioamide reactwith chlorides of Cr(III), Co(II), Ni(II) and Cu(II) to yield metal ion complexes ofdefinite composition. These compounds were characterized by elemental analyses,magnetic susceptibility measurements, UV-visible, 1H-NMR and FT-IR...
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| Format: | Article |
| Language: | English |
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Unviversity of Technology- Iraq
2010-01-01
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| Series: | Engineering and Technology Journal |
| Subjects: | |
| Online Access: | https://etj.uotechnology.edu.iq/article_26894_3decdada50afb53bd2184e0635449921.pdf |
| _version_ | 1797325399185686528 |
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| author | Ali A. Juwaied Ahmed Abdulamier Hussain Alamiery |
| author_facet | Ali A. Juwaied Ahmed Abdulamier Hussain Alamiery |
| author_sort | Ali A. Juwaied |
| collection | DOAJ |
| description | 2-(2-imino-1-methylimidazolidin-4-ylidene)hydrazinecarbothioamide reactwith chlorides of Cr(III), Co(II), Ni(II) and Cu(II) to yield metal ion complexes ofdefinite composition. These compounds were characterized by elemental analyses,magnetic susceptibility measurements, UV-visible, 1H-NMR and FT-IR spectralinvestigations. The ligand was studied by using of theoretical method (Simiempirical AMI module in the CS ChemOffice molecular modeling package) bycalculation of heat of formation, bond length, bond angle and dihedral angle. Thestability for the prepared complexes was studied theoretically by the DensityFunction Theory (DFT). The free ligand and their metal complexes have beentested in vitro against a number of micro-organisms (Staphylococcus aureus, E.coli, Proteus vulgaris, Pseudomonas, and Klebsiella pneumoniae), in order toassess their antimicrobial activities. The ligand and its complexes showedconsiderable activity against all bacteria. |
| first_indexed | 2024-03-08T06:08:56Z |
| format | Article |
| id | doaj.art-d107924bc4eb4935bff6543685124a24 |
| institution | Directory Open Access Journal |
| issn | 1681-6900 2412-0758 |
| language | English |
| last_indexed | 2024-03-08T06:08:56Z |
| publishDate | 2010-01-01 |
| publisher | Unviversity of Technology- Iraq |
| record_format | Article |
| series | Engineering and Technology Journal |
| spelling | doaj.art-d107924bc4eb4935bff6543685124a242024-02-04T17:44:31ZengUnviversity of Technology- IraqEngineering and Technology Journal1681-69002412-07582010-01-01281294210.30684/etj.28.1.326894Synthesis And Biological Activity Studies of Some Novel Metal Complexes Derivate From 2-(2-Imino-1- Methylimidazolidin-4-Ylidene) HydrazinecarbothioamideAli A. JuwaiedAhmed Abdulamier Hussain Alamiery2-(2-imino-1-methylimidazolidin-4-ylidene)hydrazinecarbothioamide reactwith chlorides of Cr(III), Co(II), Ni(II) and Cu(II) to yield metal ion complexes ofdefinite composition. These compounds were characterized by elemental analyses,magnetic susceptibility measurements, UV-visible, 1H-NMR and FT-IR spectralinvestigations. The ligand was studied by using of theoretical method (Simiempirical AMI module in the CS ChemOffice molecular modeling package) bycalculation of heat of formation, bond length, bond angle and dihedral angle. Thestability for the prepared complexes was studied theoretically by the DensityFunction Theory (DFT). The free ligand and their metal complexes have beentested in vitro against a number of micro-organisms (Staphylococcus aureus, E.coli, Proteus vulgaris, Pseudomonas, and Klebsiella pneumoniae), in order toassess their antimicrobial activities. The ligand and its complexes showedconsiderable activity against all bacteria.https://etj.uotechnology.edu.iq/article_26894_3decdada50afb53bd2184e0635449921.pdfbidentate ligandcarbothioamidemetal complexesspectral investigations |
| spellingShingle | Ali A. Juwaied Ahmed Abdulamier Hussain Alamiery Synthesis And Biological Activity Studies of Some Novel Metal Complexes Derivate From 2-(2-Imino-1- Methylimidazolidin-4-Ylidene) Hydrazinecarbothioamide Engineering and Technology Journal bidentate ligand carbothioamide metal complexes spectral investigations |
| title | Synthesis And Biological Activity Studies of Some Novel Metal Complexes Derivate From 2-(2-Imino-1- Methylimidazolidin-4-Ylidene) Hydrazinecarbothioamide |
| title_full | Synthesis And Biological Activity Studies of Some Novel Metal Complexes Derivate From 2-(2-Imino-1- Methylimidazolidin-4-Ylidene) Hydrazinecarbothioamide |
| title_fullStr | Synthesis And Biological Activity Studies of Some Novel Metal Complexes Derivate From 2-(2-Imino-1- Methylimidazolidin-4-Ylidene) Hydrazinecarbothioamide |
| title_full_unstemmed | Synthesis And Biological Activity Studies of Some Novel Metal Complexes Derivate From 2-(2-Imino-1- Methylimidazolidin-4-Ylidene) Hydrazinecarbothioamide |
| title_short | Synthesis And Biological Activity Studies of Some Novel Metal Complexes Derivate From 2-(2-Imino-1- Methylimidazolidin-4-Ylidene) Hydrazinecarbothioamide |
| title_sort | synthesis and biological activity studies of some novel metal complexes derivate from 2 2 imino 1 methylimidazolidin 4 ylidene hydrazinecarbothioamide |
| topic | bidentate ligand carbothioamide metal complexes spectral investigations |
| url | https://etj.uotechnology.edu.iq/article_26894_3decdada50afb53bd2184e0635449921.pdf |
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