meso-[5,5,7,12,12,14-Hexamethyl-1,4,8,11-tetraazacyclotetradeca-1(14),7-diene]nickel(II) dibromide dihydrate
The asymmetric unit of the title complex, [Ni(C16H32N4)]Br2·2H2O, contains two [Ni(C16H32N4)]2+ cations, four Br− anions and four uncoordinated H2O molecules. The Ni atoms are in a slightly distorted square-planar coordination by the four macrocyclic N atoms, which are alm...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2010-06-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810016831 |
| _version_ | 1819105056688963584 |
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| author | Feifei Shi Xiaodan Chen Rong Rong Qianqian Bao |
| author_facet | Feifei Shi Xiaodan Chen Rong Rong Qianqian Bao |
| author_sort | Feifei Shi |
| collection | DOAJ |
| description | The asymmetric unit of the title complex, [Ni(C16H32N4)]Br2·2H2O, contains two [Ni(C16H32N4)]2+ cations, four Br− anions and four uncoordinated H2O molecules. The Ni atoms are in a slightly distorted square-planar coordination by the four macrocyclic N atoms, which are almost coplanar [N—N—N—N torsion angles of 2.97 (6) and 3.12 (7)°]. In the crystal, a network of N—H...Br, O—H...Br and N—H...O hydrogen bonds leads to the formation of a chain structure. |
| first_indexed | 2024-12-22T02:16:11Z |
| format | Article |
| id | doaj.art-d10c27ceabe54d50833dbd59a2f47c15 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-22T02:16:11Z |
| publishDate | 2010-06-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-d10c27ceabe54d50833dbd59a2f47c152022-12-21T18:42:16ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-06-01666m665m66610.1107/S1600536810016831meso-[5,5,7,12,12,14-Hexamethyl-1,4,8,11-tetraazacyclotetradeca-1(14),7-diene]nickel(II) dibromide dihydrateFeifei ShiXiaodan ChenRong RongQianqian BaoThe asymmetric unit of the title complex, [Ni(C16H32N4)]Br2·2H2O, contains two [Ni(C16H32N4)]2+ cations, four Br− anions and four uncoordinated H2O molecules. The Ni atoms are in a slightly distorted square-planar coordination by the four macrocyclic N atoms, which are almost coplanar [N—N—N—N torsion angles of 2.97 (6) and 3.12 (7)°]. In the crystal, a network of N—H...Br, O—H...Br and N—H...O hydrogen bonds leads to the formation of a chain structure.http://scripts.iucr.org/cgi-bin/paper?S1600536810016831 |
| spellingShingle | Feifei Shi Xiaodan Chen Rong Rong Qianqian Bao meso-[5,5,7,12,12,14-Hexamethyl-1,4,8,11-tetraazacyclotetradeca-1(14),7-diene]nickel(II) dibromide dihydrate Acta Crystallographica Section E |
| title | meso-[5,5,7,12,12,14-Hexamethyl-1,4,8,11-tetraazacyclotetradeca-1(14),7-diene]nickel(II) dibromide dihydrate |
| title_full | meso-[5,5,7,12,12,14-Hexamethyl-1,4,8,11-tetraazacyclotetradeca-1(14),7-diene]nickel(II) dibromide dihydrate |
| title_fullStr | meso-[5,5,7,12,12,14-Hexamethyl-1,4,8,11-tetraazacyclotetradeca-1(14),7-diene]nickel(II) dibromide dihydrate |
| title_full_unstemmed | meso-[5,5,7,12,12,14-Hexamethyl-1,4,8,11-tetraazacyclotetradeca-1(14),7-diene]nickel(II) dibromide dihydrate |
| title_short | meso-[5,5,7,12,12,14-Hexamethyl-1,4,8,11-tetraazacyclotetradeca-1(14),7-diene]nickel(II) dibromide dihydrate |
| title_sort | meso 5 5 7 12 12 14 hexamethyl 1 4 8 11 tetraazacyclotetradeca 1 14 7 diene nickel ii dibromide dihydrate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536810016831 |
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