Synthesis of polymer-supported porphyrinatoiron and its application for catalytic oxidation of cyclohexane(高聚物负载卟啉铁的合成及其催化环己烷氧化反应研究)
在制备单氨基取代卟啉铁Fe(ATPP)Cl的基础上，以具有良好成膜特性的丙烯腈/丙烯酸共聚物为栽体，通过氨基与羧基的缩合，得到新型的高聚物负载卟啉铁(Poly-Fe(ATPP)Cl).以分子氧-抗坏血酸-Poly-Fe(ATPP) Cl作为细胞色素P-450的氧化模拟体系，研究了其对环己烷在常温常压下温和氧化的催化性能，并考察反应时间、还原剂用量、轴向配体以及催化剂的回收利用等因素的影响....
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| Format: | Article |
| Language: | zho |
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Zhejiang University Press
2006-05-01
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| Series: | Zhejiang Daxue xuebao. Lixue ban |
| Subjects: | |
| Online Access: | https://doi.org/zjup/1008-9497.2006.33.3.320-323 |
| _version_ | 1827303445721251840 |
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| author | MAKa-di(马卡迪) HEJie(何洁) WUJian(吴健) |
| author_facet | MAKa-di(马卡迪) HEJie(何洁) WUJian(吴健) |
| author_sort | MAKa-di(马卡迪) |
| collection | DOAJ |
| description | 在制备单氨基取代卟啉铁Fe(ATPP)Cl的基础上，以具有良好成膜特性的丙烯腈/丙烯酸共聚物为栽体，通过氨基与羧基的缩合，得到新型的高聚物负载卟啉铁(Poly-Fe(ATPP)Cl).以分子氧-抗坏血酸-Poly-Fe(ATPP) Cl作为细胞色素P-450的氧化模拟体系，研究了其对环己烷在常温常压下温和氧化的催化性能，并考察反应时间、还原剂用量、轴向配体以及催化剂的回收利用等因素的影响. |
| first_indexed | 2024-04-24T17:01:47Z |
| format | Article |
| id | doaj.art-d12a45b1ef304805a347efc69d8979a0 |
| institution | Directory Open Access Journal |
| issn | 1008-9497 |
| language | zho |
| last_indexed | 2024-04-24T17:01:47Z |
| publishDate | 2006-05-01 |
| publisher | Zhejiang University Press |
| record_format | Article |
| series | Zhejiang Daxue xuebao. Lixue ban |
| spelling | doaj.art-d12a45b1ef304805a347efc69d8979a02024-03-29T01:58:23ZzhoZhejiang University PressZhejiang Daxue xuebao. Lixue ban1008-94972006-05-01333320323zjup/1008-9497.2006.33.3.320-323Synthesis of polymer-supported porphyrinatoiron and its application for catalytic oxidation of cyclohexane(高聚物负载卟啉铁的合成及其催化环己烷氧化反应研究)MAKa-di(马卡迪)0HEJie(何洁)1WUJian(吴健)2Department of Chemistry, Zhejiang University, Hangzhou 310027, China(浙江大学化学系，浙江 杭州 310027)Department of Chemistry, Zhejiang University, Hangzhou 310027, China(浙江大学化学系，浙江 杭州 310027)Department of Chemistry, Zhejiang University, Hangzhou 310027, China(浙江大学化学系，浙江 杭州 310027)在制备单氨基取代卟啉铁Fe(ATPP)Cl的基础上，以具有良好成膜特性的丙烯腈/丙烯酸共聚物为栽体，通过氨基与羧基的缩合，得到新型的高聚物负载卟啉铁(Poly-Fe(ATPP)Cl).以分子氧-抗坏血酸-Poly-Fe(ATPP) Cl作为细胞色素P-450的氧化模拟体系，研究了其对环己烷在常温常压下温和氧化的催化性能，并考察反应时间、还原剂用量、轴向配体以及催化剂的回收利用等因素的影响.https://doi.org/zjup/1008-9497.2006.33.3.320-323卟啉铁高聚物负载金属卟啉环己烷催化氧化 |
| spellingShingle | MAKa-di(马卡迪) HEJie(何洁) WUJian(吴健) Synthesis of polymer-supported porphyrinatoiron and its application for catalytic oxidation of cyclohexane(高聚物负载卟啉铁的合成及其催化环己烷氧化反应研究) Zhejiang Daxue xuebao. Lixue ban 卟啉铁 高聚物负载金属卟啉 环己烷 催化氧化 |
| title | Synthesis of polymer-supported porphyrinatoiron and its application for catalytic oxidation of cyclohexane(高聚物负载卟啉铁的合成及其催化环己烷氧化反应研究) |
| title_full | Synthesis of polymer-supported porphyrinatoiron and its application for catalytic oxidation of cyclohexane(高聚物负载卟啉铁的合成及其催化环己烷氧化反应研究) |
| title_fullStr | Synthesis of polymer-supported porphyrinatoiron and its application for catalytic oxidation of cyclohexane(高聚物负载卟啉铁的合成及其催化环己烷氧化反应研究) |
| title_full_unstemmed | Synthesis of polymer-supported porphyrinatoiron and its application for catalytic oxidation of cyclohexane(高聚物负载卟啉铁的合成及其催化环己烷氧化反应研究) |
| title_short | Synthesis of polymer-supported porphyrinatoiron and its application for catalytic oxidation of cyclohexane(高聚物负载卟啉铁的合成及其催化环己烷氧化反应研究) |
| title_sort | synthesis of polymer supported porphyrinatoiron and its application for catalytic oxidation of cyclohexane 高聚物负载卟啉铁的合成及其催化环己烷氧化反应研究 |
| topic | 卟啉铁 高聚物负载金属卟啉 环己烷 催化氧化 |
| url | https://doi.org/zjup/1008-9497.2006.33.3.320-323 |
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