Bis(μ-biphenyl-2,2′-dicarboxylato)bis[aqua(4,4′-dimethyl-2,2′-bipyridine-κ2N,N′)copper(II)]
The molecule of the title binuclear copper(II) complex, [Cu2(C14H8O4)2(C12H12N2)2(H2O)2], is bisected by a crystallographic twofold axis. Each CuII atom is coordinated in a distorted octahedral geometry by three O atoms from two biphenyl-2,2′-dicarboxylate anions, one aqua O atom and t...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2009-11-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536809040628 |
| _version_ | 1818283512124407808 |
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| author | Xi-Yan Dong Xiao-Jie Xu Lei Yang |
| author_facet | Xi-Yan Dong Xiao-Jie Xu Lei Yang |
| author_sort | Xi-Yan Dong |
| collection | DOAJ |
| description | The molecule of the title binuclear copper(II) complex, [Cu2(C14H8O4)2(C12H12N2)2(H2O)2], is bisected by a crystallographic twofold axis. Each CuII atom is coordinated in a distorted octahedral geometry by three O atoms from two biphenyl-2,2′-dicarboxylate anions, one aqua O atom and two N atoms of a 4,4′-dimethyl-2,2′-bipyridine ligand. Intramolecular O—H...O hydrogen bonds between the coordinated water molecules and the carboxylate O atoms are also present. |
| first_indexed | 2024-12-13T00:38:05Z |
| format | Article |
| id | doaj.art-d13550076bb745bf99c2e664c002982c |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-13T00:38:05Z |
| publishDate | 2009-11-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-d13550076bb745bf99c2e664c002982c2022-12-22T00:05:11ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-11-016511m1360m136010.1107/S1600536809040628Bis(μ-biphenyl-2,2′-dicarboxylato)bis[aqua(4,4′-dimethyl-2,2′-bipyridine-κ2N,N′)copper(II)]Xi-Yan DongXiao-Jie XuLei YangThe molecule of the title binuclear copper(II) complex, [Cu2(C14H8O4)2(C12H12N2)2(H2O)2], is bisected by a crystallographic twofold axis. Each CuII atom is coordinated in a distorted octahedral geometry by three O atoms from two biphenyl-2,2′-dicarboxylate anions, one aqua O atom and two N atoms of a 4,4′-dimethyl-2,2′-bipyridine ligand. Intramolecular O—H...O hydrogen bonds between the coordinated water molecules and the carboxylate O atoms are also present.http://scripts.iucr.org/cgi-bin/paper?S1600536809040628 |
| spellingShingle | Xi-Yan Dong Xiao-Jie Xu Lei Yang Bis(μ-biphenyl-2,2′-dicarboxylato)bis[aqua(4,4′-dimethyl-2,2′-bipyridine-κ2N,N′)copper(II)] Acta Crystallographica Section E |
| title | Bis(μ-biphenyl-2,2′-dicarboxylato)bis[aqua(4,4′-dimethyl-2,2′-bipyridine-κ2N,N′)copper(II)] |
| title_full | Bis(μ-biphenyl-2,2′-dicarboxylato)bis[aqua(4,4′-dimethyl-2,2′-bipyridine-κ2N,N′)copper(II)] |
| title_fullStr | Bis(μ-biphenyl-2,2′-dicarboxylato)bis[aqua(4,4′-dimethyl-2,2′-bipyridine-κ2N,N′)copper(II)] |
| title_full_unstemmed | Bis(μ-biphenyl-2,2′-dicarboxylato)bis[aqua(4,4′-dimethyl-2,2′-bipyridine-κ2N,N′)copper(II)] |
| title_short | Bis(μ-biphenyl-2,2′-dicarboxylato)bis[aqua(4,4′-dimethyl-2,2′-bipyridine-κ2N,N′)copper(II)] |
| title_sort | bis amp 956 biphenyl 2 2 amp 8242 dicarboxylato bis aqua 4 4 amp 8242 dimethyl 2 2 amp 8242 bipyridine amp 954 2n n amp 8242 copper ii |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536809040628 |
| work_keys_str_mv | AT xiyandong bisamp956biphenyl22amp8242dicarboxylatobisaqua44amp8242dimethyl22amp8242bipyridineamp9542nnamp8242copperii AT xiaojiexu bisamp956biphenyl22amp8242dicarboxylatobisaqua44amp8242dimethyl22amp8242bipyridineamp9542nnamp8242copperii AT leiyang bisamp956biphenyl22amp8242dicarboxylatobisaqua44amp8242dimethyl22amp8242bipyridineamp9542nnamp8242copperii |