Recent advances of thin film composite membranes for pervaporation applications: A comprehensive review

Thin film composite (TFC) membrane, composed of an ultrathin selective layer and a microporous support layer, has exhibited its great potential for pervaporation applications, because of the high permeability, facile fabrication, and individual optimization of the support and selective layers. In th...

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Main Authors: Tengyang Zhu, Qing Xia, Jian Zuo, Shutong Liu, Xi Yu, Yan Wang
Format: Article
Language:English
Published: KeAi Communications Co. Ltd. 2021-01-01
Series:Advanced Membranes
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2772823421000099
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author Tengyang Zhu
Qing Xia
Jian Zuo
Shutong Liu
Xi Yu
Yan Wang
author_facet Tengyang Zhu
Qing Xia
Jian Zuo
Shutong Liu
Xi Yu
Yan Wang
author_sort Tengyang Zhu
collection DOAJ
description Thin film composite (TFC) membrane, composed of an ultrathin selective layer and a microporous support layer, has exhibited its great potential for pervaporation applications, because of the high permeability, facile fabrication, and individual optimization of the support and selective layers. In this review paper, we summarize the research progress of TFC membranes in pervaporation applications detailly. Herein, pervaporation fundamentals are briefed, including performance parameters and transport mechanisms involved in liquid-liquid separation and pervaporation desalination. The fabrication methods of support and selective layers, i.e., non-solvent induced phase inversion and electrospunning for the former, as well as interfacial polymerization and layer by layer assembly for the latter are elaborated respectively. Furthermore, the optimization strategies of support and selective layers are also summarized, including material section, filler incorporation, membrane-forming condition, co-solvent assistance, and surface modification. Subsequently, the performance status of TFC membranes is analyzed for various applications, including organic dehydration, organic recovery, and desalination. Finally, the challenges and future perspectives are also presented. We hope that this review can give researchers some guidance for the design and further development of TFC membrane in pervaporation processes.
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spelling doaj.art-d13ecf974838402daae7670163581d892022-12-22T04:23:18ZengKeAi Communications Co. Ltd.Advanced Membranes2772-82342021-01-011100008Recent advances of thin film composite membranes for pervaporation applications: A comprehensive reviewTengyang Zhu0Qing Xia1Jian Zuo2Shutong Liu3Xi Yu4Yan Wang5Key Laboratory of Material Chemistry for Energy Conversion and Storage (Huazhong University of Science & Technology), Ministry of Education, 1037 Luoyu Road, Wuhan, 430074, China; Hubei Key Laboratory of Material Chemistry and Service Failure, School of Chemistry and Chemical Engineering, Huazhong University of Science & Technology, 1037 Luoyu Road, Wuhan, 430074, ChinaKey Laboratory of Material Chemistry for Energy Conversion and Storage (Huazhong University of Science & Technology), Ministry of Education, 1037 Luoyu Road, Wuhan, 430074, China; Hubei Key Laboratory of Material Chemistry and Service Failure, School of Chemistry and Chemical Engineering, Huazhong University of Science & Technology, 1037 Luoyu Road, Wuhan, 430074, ChinaChemical Engineering and Food Technology, Singapore Institute of Technology, 10 Dover Drive, 138683, SingaporeKey Laboratory of Material Chemistry for Energy Conversion and Storage (Huazhong University of Science & Technology), Ministry of Education, 1037 Luoyu Road, Wuhan, 430074, China; Hubei Key Laboratory of Material Chemistry and Service Failure, School of Chemistry and Chemical Engineering, Huazhong University of Science & Technology, 1037 Luoyu Road, Wuhan, 430074, ChinaKey Laboratory of Material Chemistry for Energy Conversion and Storage (Huazhong University of Science & Technology), Ministry of Education, 1037 Luoyu Road, Wuhan, 430074, China; Hubei Key Laboratory of Material Chemistry and Service Failure, School of Chemistry and Chemical Engineering, Huazhong University of Science & Technology, 1037 Luoyu Road, Wuhan, 430074, ChinaKey Laboratory of Material Chemistry for Energy Conversion and Storage (Huazhong University of Science & Technology), Ministry of Education, 1037 Luoyu Road, Wuhan, 430074, China; Hubei Key Laboratory of Material Chemistry and Service Failure, School of Chemistry and Chemical Engineering, Huazhong University of Science & Technology, 1037 Luoyu Road, Wuhan, 430074, China; Corresponding author. Key Laboratory of Material Chemistry for Energy Conversion and Storage (Huazhong University of Science & Technology), Ministry of Education, 1037 Luoyu Road, Wuhan, 430074, China.Thin film composite (TFC) membrane, composed of an ultrathin selective layer and a microporous support layer, has exhibited its great potential for pervaporation applications, because of the high permeability, facile fabrication, and individual optimization of the support and selective layers. In this review paper, we summarize the research progress of TFC membranes in pervaporation applications detailly. Herein, pervaporation fundamentals are briefed, including performance parameters and transport mechanisms involved in liquid-liquid separation and pervaporation desalination. The fabrication methods of support and selective layers, i.e., non-solvent induced phase inversion and electrospunning for the former, as well as interfacial polymerization and layer by layer assembly for the latter are elaborated respectively. Furthermore, the optimization strategies of support and selective layers are also summarized, including material section, filler incorporation, membrane-forming condition, co-solvent assistance, and surface modification. Subsequently, the performance status of TFC membranes is analyzed for various applications, including organic dehydration, organic recovery, and desalination. Finally, the challenges and future perspectives are also presented. We hope that this review can give researchers some guidance for the design and further development of TFC membrane in pervaporation processes.http://www.sciencedirect.com/science/article/pii/S2772823421000099Thin film composite membranePervaporationLiquid-liquid separationDesalination
spellingShingle Tengyang Zhu
Qing Xia
Jian Zuo
Shutong Liu
Xi Yu
Yan Wang
Recent advances of thin film composite membranes for pervaporation applications: A comprehensive review
Advanced Membranes
Thin film composite membrane
Pervaporation
Liquid-liquid separation
Desalination
title Recent advances of thin film composite membranes for pervaporation applications: A comprehensive review
title_full Recent advances of thin film composite membranes for pervaporation applications: A comprehensive review
title_fullStr Recent advances of thin film composite membranes for pervaporation applications: A comprehensive review
title_full_unstemmed Recent advances of thin film composite membranes for pervaporation applications: A comprehensive review
title_short Recent advances of thin film composite membranes for pervaporation applications: A comprehensive review
title_sort recent advances of thin film composite membranes for pervaporation applications a comprehensive review
topic Thin film composite membrane
Pervaporation
Liquid-liquid separation
Desalination
url http://www.sciencedirect.com/science/article/pii/S2772823421000099
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AT shutongliu recentadvancesofthinfilmcompositemembranesforpervaporationapplicationsacomprehensivereview
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