The study of intermolecular energy transfers in electronic energy quenching for molecular collisions N<sub>2</sub>-N<sub>2</sub>, N<sub>2</sub>-O<sub>2</sub>, O<sub>2</sub>-O<sub>2</sub>
Contributions of intermolecular electron energy transfers in the electronic quenching are calculated for molecular collisions N<sub>2</sub>(A<sup>3</sup>Σ<sub><I>u</I></sub><sup>+</sup>, W<sup>3</sup>Δ<su...
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| Format: | Article |
| Language: | English |
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Copernicus Publications
2008-05-01
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| Series: | Annales Geophysicae |
| Online Access: | https://www.ann-geophys.net/26/1149/2008/angeo-26-1149-2008.pdf |
| _version_ | 1818946033971888128 |
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| author | A. S. Kirillov |
| author_facet | A. S. Kirillov |
| author_sort | A. S. Kirillov |
| collection | DOAJ |
| description | Contributions of intermolecular electron energy transfers in the electronic
quenching are calculated for molecular collisions N<sub>2</sub>(A<sup>3</sup>Σ<sub><I>u</I></sub><sup>+</sup>, W<sup>3</sup>Δ<sub><I>u</I></sub>)+N<sub>2</sub>(X<sup>1</sup>Σ<sub><I>g</I></sub><sup>+</sup>,
<I>v</I>=0), N<sub>2</sub>(A<sup>3</sup>Σ<sub><I>u</I></sub><sup>+</sup>)+N<sub>2</sub>(X<sup>1</sup>Σ<sub><I>g</I></sub><sup>+</sup>, <I>v</I>≥0), N<sub>2</sub>(A<sup>3</sup>Σ<sub><I>u</I></sub><sup>+</sup>)+O<sub>2</sub>(X<sup>3</sup>Σ<sub><I>g</I></sub><sup>−</sup>, <I>v</I>=0–2),
O<sub>2</sub>(a<sup>1</sup>Δ<sub><I>g</I></sub>, <I>b</I><sup>1</sup>Σ<sub><I>g</I></sub><sup>+</sup>)+O<sub>2</sub>(X<sup>3</sup>Σ<sub><I>g</I></sub><sup>−</sup>, <I>v</I>=0–2). The calculation has allowed one to
estimate the product branching ratios. It is shown that there is a
dependence of the calculated rate coefficients on the vibrational excitation of
N<sub>2</sub>(X<sup>1</sup>Σ<sub><I>g</I></sub><sup>+</sup>) and O<sub>2</sub>(X<sup>3</sup>Σ<sub><I>g</I></sub><sup>−</sup>) molecules. In many cases, the calculated rate coefficients
have a good agreement with available experimental data. |
| first_indexed | 2024-12-20T08:08:35Z |
| format | Article |
| id | doaj.art-d13edea23aec4e86b12406b58875f0fe |
| institution | Directory Open Access Journal |
| issn | 0992-7689 1432-0576 |
| language | English |
| last_indexed | 2024-12-20T08:08:35Z |
| publishDate | 2008-05-01 |
| publisher | Copernicus Publications |
| record_format | Article |
| series | Annales Geophysicae |
| spelling | doaj.art-d13edea23aec4e86b12406b58875f0fe2022-12-21T19:47:20ZengCopernicus PublicationsAnnales Geophysicae0992-76891432-05762008-05-01261149115710.5194/angeo-26-1149-2008The study of intermolecular energy transfers in electronic energy quenching for molecular collisions N<sub>2</sub>-N<sub>2</sub>, N<sub>2</sub>-O<sub>2</sub>, O<sub>2</sub>-O<sub>2</sub>A. S. Kirillov0Polar Geophysical Institute of the Kola Science Centre RAS, Apatity, 184209, RussiaContributions of intermolecular electron energy transfers in the electronic quenching are calculated for molecular collisions N<sub>2</sub>(A<sup>3</sup>Σ<sub><I>u</I></sub><sup>+</sup>, W<sup>3</sup>Δ<sub><I>u</I></sub>)+N<sub>2</sub>(X<sup>1</sup>Σ<sub><I>g</I></sub><sup>+</sup>, <I>v</I>=0), N<sub>2</sub>(A<sup>3</sup>Σ<sub><I>u</I></sub><sup>+</sup>)+N<sub>2</sub>(X<sup>1</sup>Σ<sub><I>g</I></sub><sup>+</sup>, <I>v</I>≥0), N<sub>2</sub>(A<sup>3</sup>Σ<sub><I>u</I></sub><sup>+</sup>)+O<sub>2</sub>(X<sup>3</sup>Σ<sub><I>g</I></sub><sup>−</sup>, <I>v</I>=0–2), O<sub>2</sub>(a<sup>1</sup>Δ<sub><I>g</I></sub>, <I>b</I><sup>1</sup>Σ<sub><I>g</I></sub><sup>+</sup>)+O<sub>2</sub>(X<sup>3</sup>Σ<sub><I>g</I></sub><sup>−</sup>, <I>v</I>=0–2). The calculation has allowed one to estimate the product branching ratios. It is shown that there is a dependence of the calculated rate coefficients on the vibrational excitation of N<sub>2</sub>(X<sup>1</sup>Σ<sub><I>g</I></sub><sup>+</sup>) and O<sub>2</sub>(X<sup>3</sup>Σ<sub><I>g</I></sub><sup>−</sup>) molecules. In many cases, the calculated rate coefficients have a good agreement with available experimental data.https://www.ann-geophys.net/26/1149/2008/angeo-26-1149-2008.pdf |
| spellingShingle | A. S. Kirillov The study of intermolecular energy transfers in electronic energy quenching for molecular collisions N<sub>2</sub>-N<sub>2</sub>, N<sub>2</sub>-O<sub>2</sub>, O<sub>2</sub>-O<sub>2</sub> Annales Geophysicae |
| title | The study of intermolecular energy transfers in electronic energy quenching for molecular collisions N<sub>2</sub>-N<sub>2</sub>, N<sub>2</sub>-O<sub>2</sub>, O<sub>2</sub>-O<sub>2</sub> |
| title_full | The study of intermolecular energy transfers in electronic energy quenching for molecular collisions N<sub>2</sub>-N<sub>2</sub>, N<sub>2</sub>-O<sub>2</sub>, O<sub>2</sub>-O<sub>2</sub> |
| title_fullStr | The study of intermolecular energy transfers in electronic energy quenching for molecular collisions N<sub>2</sub>-N<sub>2</sub>, N<sub>2</sub>-O<sub>2</sub>, O<sub>2</sub>-O<sub>2</sub> |
| title_full_unstemmed | The study of intermolecular energy transfers in electronic energy quenching for molecular collisions N<sub>2</sub>-N<sub>2</sub>, N<sub>2</sub>-O<sub>2</sub>, O<sub>2</sub>-O<sub>2</sub> |
| title_short | The study of intermolecular energy transfers in electronic energy quenching for molecular collisions N<sub>2</sub>-N<sub>2</sub>, N<sub>2</sub>-O<sub>2</sub>, O<sub>2</sub>-O<sub>2</sub> |
| title_sort | study of intermolecular energy transfers in electronic energy quenching for molecular collisions n sub 2 sub n sub 2 sub n sub 2 sub o sub 2 sub o sub 2 sub o sub 2 sub |
| url | https://www.ann-geophys.net/26/1149/2008/angeo-26-1149-2008.pdf |
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