Recent advances based on Mg anodes and their interfacial modulation in Mg batteries
Magnesium (Mg) batteries (MBs), as post-lithium-ion batteries, have received great attention in recent years due to their advantages of high energy density, low cost, and safety insurance. However, the formation of passivation layers on the surface of Mg metal anode and the poor compatibility betwee...
| Main Authors: | , , , , , , , , |
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| Format: | Article |
| Language: | English |
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KeAi Communications Co., Ltd.
2022-10-01
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| Series: | Journal of Magnesium and Alloys |
| Subjects: | |
| Online Access: | http://www.sciencedirect.com/science/article/pii/S2213956722002092 |
| _version_ | 1797984297788899328 |
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| author | Fanfan Liu Guoqin Cao Jinjin Ban Honghong Lei Yan Zhang Guosheng Shao Aiguo Zhou Li zhen Fan Junhua Hu |
| author_facet | Fanfan Liu Guoqin Cao Jinjin Ban Honghong Lei Yan Zhang Guosheng Shao Aiguo Zhou Li zhen Fan Junhua Hu |
| author_sort | Fanfan Liu |
| collection | DOAJ |
| description | Magnesium (Mg) batteries (MBs), as post-lithium-ion batteries, have received great attention in recent years due to their advantages of high energy density, low cost, and safety insurance. However, the formation of passivation layers on the surface of Mg metal anode and the poor compatibility between Mg metal and conventional electrolytes during charge-discharge cycles seriously affect the performance of MBs. The great possibility of generating Mg dendrites has also caused controversy among researchers. Moreover, the regulation of Mg deposition and the enhancement of battery cycle stability is largely limited by interfacial stability between Mg metal anode and electrolyte. In this review, recent advances in interfacial science and engineering of MBs are summarized and discussed. Special attention is given to interfacial chemistry including passivation layer formation, incompatibilities, ion transport, and dendrite growth. Strategies for building stable electrode/interfaces, such as anode designing and electrolyte modification, construction of artificial solid electrolyte interphase (SEI) layers, and development of solid-state electrolytes to improve interfacial contacts and inhibit Mg dendrite and passivation layer formation, are reviewed. Innovative approaches, representative examples, and challenges in developing high-performance anodes are described in detail. Based on the review of these strategies, reference is provided for future research to improve the performance of MBs, especially in terms of interface and anode design. |
| first_indexed | 2024-04-11T07:00:32Z |
| format | Article |
| id | doaj.art-d141dde072e14affbe5e24429062c8d8 |
| institution | Directory Open Access Journal |
| issn | 2213-9567 |
| language | English |
| last_indexed | 2024-04-11T07:00:32Z |
| publishDate | 2022-10-01 |
| publisher | KeAi Communications Co., Ltd. |
| record_format | Article |
| series | Journal of Magnesium and Alloys |
| spelling | doaj.art-d141dde072e14affbe5e24429062c8d82022-12-22T04:38:49ZengKeAi Communications Co., Ltd.Journal of Magnesium and Alloys2213-95672022-10-01101026992716Recent advances based on Mg anodes and their interfacial modulation in Mg batteriesFanfan Liu0Guoqin Cao1Jinjin Ban2Honghong Lei3Yan Zhang4Guosheng Shao5Aiguo Zhou6Li zhen Fan7Junhua Hu8School of Materials Science and Engineering, Industrial Technology Research Institute of Resource and Materials of Henan Province, Zhengzhou University, Zhengzhou 450001, China; State Center for International Cooperation on Designer Low-carbon and Environmental Materials (CDLCEM), Zhengzhou University, Zhengzhou 450001, ChinaSchool of Materials Science and Engineering, Industrial Technology Research Institute of Resource and Materials of Henan Province, Zhengzhou University, Zhengzhou 450001, China; State Center for International Cooperation on Designer Low-carbon and Environmental Materials (CDLCEM), Zhengzhou University, Zhengzhou 450001, ChinaSchool of Materials Science and Engineering, Industrial Technology Research Institute of Resource and Materials of Henan Province, Zhengzhou University, Zhengzhou 450001, China; State Center for International Cooperation on Designer Low-carbon and Environmental Materials (CDLCEM), Zhengzhou University, Zhengzhou 450001, ChinaHenan Provincial Key Laboratory for Metal Fuel Battery, Foguang Power Generation Equipment Co. Ltd, 50 Holly Street, Zhengzhou 450000, ChinaSchool of Materials Science and Engineering, Nanjing Institute of Technology, Nanjing 211167, ChinaSchool of Materials Science and Engineering, Industrial Technology Research Institute of Resource and Materials of Henan Province, Zhengzhou University, Zhengzhou 450001, China; State Center for International Cooperation on Designer Low-carbon and Environmental Materials (CDLCEM), Zhengzhou University, Zhengzhou 450001, ChinaHenan Key Laboratory of Materials on Deep-Earth Engineering, School of Materials Science and Engineering, Henan Polytechnic University, Jiaozuo 454000, ChinaBeijing Advanced Innovation Center for Materials Genome Engineering, Institute of Advanced Materials and Technology, University of Science and Technology Beijing, Beijing 100083, China; Corresponding author.School of Materials Science and Engineering, Industrial Technology Research Institute of Resource and Materials of Henan Province, Zhengzhou University, Zhengzhou 450001, China; State Center for International Cooperation on Designer Low-carbon and Environmental Materials (CDLCEM), Zhengzhou University, Zhengzhou 450001, China; Corresponding author at: School of Materials Science and Engineering, Industrial Technology Research Institute of Resource and Materials of Henan Province, Zhengzhou University, Zhengzhou 450001, China.Magnesium (Mg) batteries (MBs), as post-lithium-ion batteries, have received great attention in recent years due to their advantages of high energy density, low cost, and safety insurance. However, the formation of passivation layers on the surface of Mg metal anode and the poor compatibility between Mg metal and conventional electrolytes during charge-discharge cycles seriously affect the performance of MBs. The great possibility of generating Mg dendrites has also caused controversy among researchers. Moreover, the regulation of Mg deposition and the enhancement of battery cycle stability is largely limited by interfacial stability between Mg metal anode and electrolyte. In this review, recent advances in interfacial science and engineering of MBs are summarized and discussed. Special attention is given to interfacial chemistry including passivation layer formation, incompatibilities, ion transport, and dendrite growth. Strategies for building stable electrode/interfaces, such as anode designing and electrolyte modification, construction of artificial solid electrolyte interphase (SEI) layers, and development of solid-state electrolytes to improve interfacial contacts and inhibit Mg dendrite and passivation layer formation, are reviewed. Innovative approaches, representative examples, and challenges in developing high-performance anodes are described in detail. Based on the review of these strategies, reference is provided for future research to improve the performance of MBs, especially in terms of interface and anode design.http://www.sciencedirect.com/science/article/pii/S2213956722002092Magnesium anodeDendritePassivation layersInterfacial engineeringSolid electrolyte interphase |
| spellingShingle | Fanfan Liu Guoqin Cao Jinjin Ban Honghong Lei Yan Zhang Guosheng Shao Aiguo Zhou Li zhen Fan Junhua Hu Recent advances based on Mg anodes and their interfacial modulation in Mg batteries Journal of Magnesium and Alloys Magnesium anode Dendrite Passivation layers Interfacial engineering Solid electrolyte interphase |
| title | Recent advances based on Mg anodes and their interfacial modulation in Mg batteries |
| title_full | Recent advances based on Mg anodes and their interfacial modulation in Mg batteries |
| title_fullStr | Recent advances based on Mg anodes and their interfacial modulation in Mg batteries |
| title_full_unstemmed | Recent advances based on Mg anodes and their interfacial modulation in Mg batteries |
| title_short | Recent advances based on Mg anodes and their interfacial modulation in Mg batteries |
| title_sort | recent advances based on mg anodes and their interfacial modulation in mg batteries |
| topic | Magnesium anode Dendrite Passivation layers Interfacial engineering Solid electrolyte interphase |
| url | http://www.sciencedirect.com/science/article/pii/S2213956722002092 |
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