Kinetics of Sulfur, Vanadium and Nickel Removal from Basra Crude Oil Hydro Treating
Basra crude oil was hydro treated in trickle–bed reactor using cobalt – molybdenum alumina as a Catalyst. The reaction range temperatures was598 – 648 k, while LHSV was 0.7 – 2 hr-1. The pressure and H2/Oil for all experiments keep constant at 3Mpa and 300 L/L respectively. Desulphurization and demu...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
Tikrit University
2010-09-01
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| Series: | Tikrit Journal of Engineering Sciences |
| Online Access: | https://tj-es.com/ojs/index.php/tjes/article/view/564 |
| Summary: | Basra crude oil was hydro treated in trickle–bed reactor using cobalt – molybdenum alumina as a Catalyst. The reaction range temperatures was598 – 648 k, while LHSV was 0.7 – 2 hr-1. The pressure and H2/Oil for all experiments keep constant at 3Mpa and 300 L/L respectively. Desulphurization and demutualization kinetics were studied and found that the kinetics of sculpture removal is of first – order, and the kinetic of vanadium and nickel removal is of second – order. Activation energy were calculated and their value are 24.03, 745.86, 63.90 KJ / mole, respectively for sculpture, vanadium, and nickel.
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| ISSN: | 1813-162X 2312-7589 |