Rapid, Highly-Efficient and Selective Removal of Anionic and Cationic Dyes from Wastewater Using Hollow Polyelectrolyte Microcapsules

Herein, poly (allylamine hydrochloride) (PAH)/ poly (styrene sulfonic acid) sodium salt (PSS) microcapsules of (PAH/PSS)<sub>2</sub>PAH (P2P MCs) and (PAH/PSS)<sub>2</sub> (P2 MCs) were obtained by a layer-by-layer method. The P2 MCs show high adsorption capacity for Rhodamin...

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Main Authors: Zhiqi Zhao, Hongbing Zhou, Xu Han, Lun Han, Zhenzhen Xu, Peng Wang
Format: Article
Language:English
Published: MDPI AG 2023-03-01
Series:Molecules
Subjects:
Online Access:https://www.mdpi.com/1420-3049/28/7/3010
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author Zhiqi Zhao
Hongbing Zhou
Xu Han
Lun Han
Zhenzhen Xu
Peng Wang
author_facet Zhiqi Zhao
Hongbing Zhou
Xu Han
Lun Han
Zhenzhen Xu
Peng Wang
author_sort Zhiqi Zhao
collection DOAJ
description Herein, poly (allylamine hydrochloride) (PAH)/ poly (styrene sulfonic acid) sodium salt (PSS) microcapsules of (PAH/PSS)<sub>2</sub>PAH (P2P MCs) and (PAH/PSS)<sub>2</sub> (P2 MCs) were obtained by a layer-by-layer method. The P2 MCs show high adsorption capacity for Rhodamine B (642.26 mg/g) and methylene blue (909.25 mg/g), with an extremely low equilibrium adsorption time (~20 min). The P2P MCs exhibited high adsorption capacities of reactive orange K-G (ROKG) and direct yellow 5G (DY5G) which were 404.79 and 451.56 mg/g. Adsorption processes of all dyes onto microcapsules were best described by the Langmuir isotherm model and a pseudo-second-order kinetic model. In addition, the P2P MCs loaded with reactive dyes (P2P–ROKG), could further adsorb rhodamine B (RhB) dye, and P2 MCs that had adsorbed cationic MB dyes could also be used for secondary adsorption treatment of direct dye waste-water, respectively. The present work confirmed that P2P and P2 MCs were expected to become an excellent adsorbent in the water treatment industry.
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spelling doaj.art-d14ab85d3ead425db8ad305c40db04a12023-11-17T17:12:13ZengMDPI AGMolecules1420-30492023-03-01287301010.3390/molecules28073010Rapid, Highly-Efficient and Selective Removal of Anionic and Cationic Dyes from Wastewater Using Hollow Polyelectrolyte MicrocapsulesZhiqi Zhao0Hongbing Zhou1Xu Han2Lun Han3Zhenzhen Xu4Peng Wang5School of Textile and Garment, Anhui Polytechnic University, Wuhu 241000, ChinaZhejiang Huaguang Automotive Interior Decoration Co., Ltd., Rui’an 325200, ChinaSchool of Textile and Garment, Anhui Polytechnic University, Wuhu 241000, ChinaSchool of Textile and Garment, Anhui Polytechnic University, Wuhu 241000, ChinaSchool of Textile and Garment, Anhui Polytechnic University, Wuhu 241000, ChinaSchool of Textile and Garment, Anhui Polytechnic University, Wuhu 241000, ChinaHerein, poly (allylamine hydrochloride) (PAH)/ poly (styrene sulfonic acid) sodium salt (PSS) microcapsules of (PAH/PSS)<sub>2</sub>PAH (P2P MCs) and (PAH/PSS)<sub>2</sub> (P2 MCs) were obtained by a layer-by-layer method. The P2 MCs show high adsorption capacity for Rhodamine B (642.26 mg/g) and methylene blue (909.25 mg/g), with an extremely low equilibrium adsorption time (~20 min). The P2P MCs exhibited high adsorption capacities of reactive orange K-G (ROKG) and direct yellow 5G (DY5G) which were 404.79 and 451.56 mg/g. Adsorption processes of all dyes onto microcapsules were best described by the Langmuir isotherm model and a pseudo-second-order kinetic model. In addition, the P2P MCs loaded with reactive dyes (P2P–ROKG), could further adsorb rhodamine B (RhB) dye, and P2 MCs that had adsorbed cationic MB dyes could also be used for secondary adsorption treatment of direct dye waste-water, respectively. The present work confirmed that P2P and P2 MCs were expected to become an excellent adsorbent in the water treatment industry.https://www.mdpi.com/1420-3049/28/7/3010polyelectrolyte microcapsuledyes removalwater treatmenthigh adsorption capacityfast adsorption
spellingShingle Zhiqi Zhao
Hongbing Zhou
Xu Han
Lun Han
Zhenzhen Xu
Peng Wang
Rapid, Highly-Efficient and Selective Removal of Anionic and Cationic Dyes from Wastewater Using Hollow Polyelectrolyte Microcapsules
Molecules
polyelectrolyte microcapsule
dyes removal
water treatment
high adsorption capacity
fast adsorption
title Rapid, Highly-Efficient and Selective Removal of Anionic and Cationic Dyes from Wastewater Using Hollow Polyelectrolyte Microcapsules
title_full Rapid, Highly-Efficient and Selective Removal of Anionic and Cationic Dyes from Wastewater Using Hollow Polyelectrolyte Microcapsules
title_fullStr Rapid, Highly-Efficient and Selective Removal of Anionic and Cationic Dyes from Wastewater Using Hollow Polyelectrolyte Microcapsules
title_full_unstemmed Rapid, Highly-Efficient and Selective Removal of Anionic and Cationic Dyes from Wastewater Using Hollow Polyelectrolyte Microcapsules
title_short Rapid, Highly-Efficient and Selective Removal of Anionic and Cationic Dyes from Wastewater Using Hollow Polyelectrolyte Microcapsules
title_sort rapid highly efficient and selective removal of anionic and cationic dyes from wastewater using hollow polyelectrolyte microcapsules
topic polyelectrolyte microcapsule
dyes removal
water treatment
high adsorption capacity
fast adsorption
url https://www.mdpi.com/1420-3049/28/7/3010
work_keys_str_mv AT zhiqizhao rapidhighlyefficientandselectiveremovalofanionicandcationicdyesfromwastewaterusinghollowpolyelectrolytemicrocapsules
AT hongbingzhou rapidhighlyefficientandselectiveremovalofanionicandcationicdyesfromwastewaterusinghollowpolyelectrolytemicrocapsules
AT xuhan rapidhighlyefficientandselectiveremovalofanionicandcationicdyesfromwastewaterusinghollowpolyelectrolytemicrocapsules
AT lunhan rapidhighlyefficientandselectiveremovalofanionicandcationicdyesfromwastewaterusinghollowpolyelectrolytemicrocapsules
AT zhenzhenxu rapidhighlyefficientandselectiveremovalofanionicandcationicdyesfromwastewaterusinghollowpolyelectrolytemicrocapsules
AT pengwang rapidhighlyefficientandselectiveremovalofanionicandcationicdyesfromwastewaterusinghollowpolyelectrolytemicrocapsules