Adsorptive removal of heavy metals from oil well produced water using citrullus lanatus peel: Characterization and optimization

The effects of adsorbent dosage, reaction time, temperature and pH on the adsorption of Pb2+, Zn2+, Fe2+ and Cu2+ from produced water using activated carbon prepared from Citrullus lanatus peel via calcination at 681.10 °C for 2.61 h were studied. L9 orthogonal Taguchi approach was used for the para...

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Bibliographic Details
Main Authors: Lekan Taofeek Popoola, Adeyinka Sikiru Yusuff, Abel Adekanmi Adeyi, Oluwagbenga Olawale Omotara
Format: Article
Language:English
Published: Elsevier 2022-01-01
Series:South African Journal of Chemical Engineering
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Online Access:http://www.sciencedirect.com/science/article/pii/S1026918521000573
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Summary:The effects of adsorbent dosage, reaction time, temperature and pH on the adsorption of Pb2+, Zn2+, Fe2+ and Cu2+ from produced water using activated carbon prepared from Citrullus lanatus peel via calcination at 681.10 °C for 2.61 h were studied. L9 orthogonal Taguchi approach was used for the parametric optimization. Activated carbon was characterized using scanning electron microscopy, Brunauer-Emmett-Teller analysis, X-ray diffraction, X-ray fluorescence and Fourier transform infrared spectroscopy and; exhibited a porous-graphite-crystalline structure, presence of different metal oxides and active functional groups with large surface area of 1249.7 m2/g. Batch adsorption experiments revealed the efficacy of prepared activated carbon to remove heavy metals from produced water. At optimum points, predicted values were 76.31, 59.3, 69.91 and 84.08% for Pb2+, Zn2+, Fe2+ and Cu2+ removed respectively. The values of R2, Adj-R2 and pred-R2 revealed reasonable agreements between experimental and predicted data which proved developed models to be effective.
ISSN:1026-9185