3,3-Bis[(4-chlorophenyl)sulfanyl]-1-methylpiperidin-2-one
The piperidone ring in the title compound, C18H17Cl2NOS2, has a distorted half-chair conformation. The S-bound benzene rings are approximately perpendicular to and splayed out of the mean plane through the piperidone ring [dihedral angles = 71.86 (13) and 46.94 (11)&a...
| Main Authors: | , , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2010-07-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810024347 |
| _version_ | 1818999289154633728 |
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| author | Julio Zukerman-Schpector Carlos A. De Simone Paulo R. Olivato Carlos R. Cerqueira Jr Jean M. M. Santos Edward R. T. Tiekink |
| author_facet | Julio Zukerman-Schpector Carlos A. De Simone Paulo R. Olivato Carlos R. Cerqueira Jr Jean M. M. Santos Edward R. T. Tiekink |
| author_sort | Julio Zukerman-Schpector |
| collection | DOAJ |
| description | The piperidone ring in the title compound, C18H17Cl2NOS2, has a distorted half-chair conformation. The S-bound benzene rings are approximately perpendicular to and splayed out of the mean plane through the piperidone ring [dihedral angles = 71.86 (13) and 46.94 (11)°]. In the crystal, C—H...O interactions link the molecules into [010] supramolecular chains with a helical topology. C—H...Cl and C—H...π interactions are also present. |
| first_indexed | 2024-12-20T22:15:03Z |
| format | Article |
| id | doaj.art-d1a6abfbe6ba41a793e36937ba2e0ddd |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-20T22:15:03Z |
| publishDate | 2010-07-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-d1a6abfbe6ba41a793e36937ba2e0ddd2022-12-21T19:25:05ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-07-01667o1863o186310.1107/S16005368100243473,3-Bis[(4-chlorophenyl)sulfanyl]-1-methylpiperidin-2-oneJulio Zukerman-SchpectorCarlos A. De SimonePaulo R. OlivatoCarlos R. Cerqueira JrJean M. M. SantosEdward R. T. TiekinkThe piperidone ring in the title compound, C18H17Cl2NOS2, has a distorted half-chair conformation. The S-bound benzene rings are approximately perpendicular to and splayed out of the mean plane through the piperidone ring [dihedral angles = 71.86 (13) and 46.94 (11)°]. In the crystal, C—H...O interactions link the molecules into [010] supramolecular chains with a helical topology. C—H...Cl and C—H...π interactions are also present.http://scripts.iucr.org/cgi-bin/paper?S1600536810024347 |
| spellingShingle | Julio Zukerman-Schpector Carlos A. De Simone Paulo R. Olivato Carlos R. Cerqueira Jr Jean M. M. Santos Edward R. T. Tiekink 3,3-Bis[(4-chlorophenyl)sulfanyl]-1-methylpiperidin-2-one Acta Crystallographica Section E |
| title | 3,3-Bis[(4-chlorophenyl)sulfanyl]-1-methylpiperidin-2-one |
| title_full | 3,3-Bis[(4-chlorophenyl)sulfanyl]-1-methylpiperidin-2-one |
| title_fullStr | 3,3-Bis[(4-chlorophenyl)sulfanyl]-1-methylpiperidin-2-one |
| title_full_unstemmed | 3,3-Bis[(4-chlorophenyl)sulfanyl]-1-methylpiperidin-2-one |
| title_short | 3,3-Bis[(4-chlorophenyl)sulfanyl]-1-methylpiperidin-2-one |
| title_sort | 3 3 bis 4 chlorophenyl sulfanyl 1 methylpiperidin 2 one |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536810024347 |
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