Ageing of Al-Mn-Cu-Be Alloys for Stimulating Precipitation of Icosahedral Quasicrystals

In this work, the ageing of some Al-Mn-Cu-Be alloys was investigated in the temperature range in which predominantly icosahedral quasicrystalline (IQC) precipitates can form. The alloys were cast into a copper mould, directly aged (T5 heat treatment) between 300 and 440 °C for different times. After...

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Main Authors: Tonica Bončina, Mihaela Albu, Franc Zupanič
Format: Article
Language:English
Published: MDPI AG 2020-07-01
Series:Metals
Subjects:
Online Access:https://www.mdpi.com/2075-4701/10/7/937
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author Tonica Bončina
Mihaela Albu
Franc Zupanič
author_facet Tonica Bončina
Mihaela Albu
Franc Zupanič
author_sort Tonica Bončina
collection DOAJ
description In this work, the ageing of some Al-Mn-Cu-Be alloys was investigated in the temperature range in which predominantly icosahedral quasicrystalline (IQC) precipitates can form. The alloys were cast into a copper mould, directly aged (T5 heat treatment) between 300 and 440 °C for different times. Afterwards, they were examined using scanning and transmission electron microscopy, X-ray diffraction and hardness testing. The main aim of the work was to determine the conditions at which a high number density of spherical icosahedral quasicrystalline precipitates can form. The highest number density of IQC precipitates was obtained at 300 °C after prolonged ageing. The spheroidal precipitates had a diameter less than 20 nm. The size of IQC precipitates increased with the increasing temperature, and in addition, decagonal quasicrystalline precipitates appeared. The time to maximum hardness decreased strongly with increasing ageing temperature. The IQC precipitates can form in a fairly broad temperature range in Al-Mn-Cu-Be alloys and that by varying ageing temperature and duration, rather different distributions of precipitates can be obtained. The presence of precipitates caused rather strong aluminium alloys and fast work hardening during initial plastic deformation.
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spelling doaj.art-d1ad61341ca34c9299f64b5e41bdb6d72023-11-20T06:31:51ZengMDPI AGMetals2075-47012020-07-0110793710.3390/met10070937Ageing of Al-Mn-Cu-Be Alloys for Stimulating Precipitation of Icosahedral QuasicrystalsTonica Bončina0Mihaela Albu1Franc Zupanič2Faculty of Mechanical Engineering, University of Maribor, SI-2000 Maribor, SloveniaGraz Centre for Electron Microscopy, A-8010 Graz, AustriaFaculty of Mechanical Engineering, University of Maribor, SI-2000 Maribor, SloveniaIn this work, the ageing of some Al-Mn-Cu-Be alloys was investigated in the temperature range in which predominantly icosahedral quasicrystalline (IQC) precipitates can form. The alloys were cast into a copper mould, directly aged (T5 heat treatment) between 300 and 440 °C for different times. Afterwards, they were examined using scanning and transmission electron microscopy, X-ray diffraction and hardness testing. The main aim of the work was to determine the conditions at which a high number density of spherical icosahedral quasicrystalline precipitates can form. The highest number density of IQC precipitates was obtained at 300 °C after prolonged ageing. The spheroidal precipitates had a diameter less than 20 nm. The size of IQC precipitates increased with the increasing temperature, and in addition, decagonal quasicrystalline precipitates appeared. The time to maximum hardness decreased strongly with increasing ageing temperature. The IQC precipitates can form in a fairly broad temperature range in Al-Mn-Cu-Be alloys and that by varying ageing temperature and duration, rather different distributions of precipitates can be obtained. The presence of precipitates caused rather strong aluminium alloys and fast work hardening during initial plastic deformation.https://www.mdpi.com/2075-4701/10/7/937aluminiumageingquasicrystaltransmission electron microscopy
spellingShingle Tonica Bončina
Mihaela Albu
Franc Zupanič
Ageing of Al-Mn-Cu-Be Alloys for Stimulating Precipitation of Icosahedral Quasicrystals
Metals
aluminium
ageing
quasicrystal
transmission electron microscopy
title Ageing of Al-Mn-Cu-Be Alloys for Stimulating Precipitation of Icosahedral Quasicrystals
title_full Ageing of Al-Mn-Cu-Be Alloys for Stimulating Precipitation of Icosahedral Quasicrystals
title_fullStr Ageing of Al-Mn-Cu-Be Alloys for Stimulating Precipitation of Icosahedral Quasicrystals
title_full_unstemmed Ageing of Al-Mn-Cu-Be Alloys for Stimulating Precipitation of Icosahedral Quasicrystals
title_short Ageing of Al-Mn-Cu-Be Alloys for Stimulating Precipitation of Icosahedral Quasicrystals
title_sort ageing of al mn cu be alloys for stimulating precipitation of icosahedral quasicrystals
topic aluminium
ageing
quasicrystal
transmission electron microscopy
url https://www.mdpi.com/2075-4701/10/7/937
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AT mihaelaalbu ageingofalmncubealloysforstimulatingprecipitationoficosahedralquasicrystals
AT franczupanic ageingofalmncubealloysforstimulatingprecipitationoficosahedralquasicrystals